(3E)-4-cyclohexyl-3-butenal | 58474-82-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (3E)-4-cyclohexyl-3-butenal
• 英文别名: (E)-4-cyclohexylbut-3-enal
• CAS: 58474-82-1
• 化学式: C₁₀H₁₆O
• 分子量: 152.236
• InChiKey: AHVQIRJTRGHRBR-XBXARRHUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  Carbonic acid 1-cyclohexyl-4-(tetrahydro-pyran-2-yloxy)-but-2-ynyl ester methyl ester 在 palladium on barium sulfate 四(三苯基膦)钯 、 氢气 、 4-甲基苯磺酸吡啶 作用下， 以 四氢呋喃 、 甲醇 、 水 为溶剂， 反应 3.0h， 生成 (3E)-4-cyclohexyl-3-butenal
  参考文献：
  名称：

  钯催化的区域选择性氢迁移合成α，β-不饱和醛

  摘要：

  在THF或AcOH水溶液中用催化量的Pd（PPh 3）4处理3-烯烃-1,2-二醇的环状碳酸酯或2-烯烃-1,4-二醇的4-甲基碳酸酯，得到α，β-不饱和醛收率高。该反应可以通过π-烯丙基铝中间体的区域选择性1，4-氢迁移来解释。

  DOI：

  10.1016/s0040-4039(00)78560-1

文献信息

• POLYVINYL ALCOHOL BLOCK COPOLYMER AND AQUEOUS PIGMENT DISPERSIONS AND RECORDING FLUIDS MADE BY USING THE SAME
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：EP1609807A1

  公开（公告）日：2005-12-28

  A problem of the invention is to provide a recording liquid capable of giving a printed matter which is high in printing density, is suppressed in blur, has high printing quality, and has good fastness of a recorded matter including light fastness, water fastness and the like and having a low viscosity, good discharge properties and excellent storage stability. The invention is concerned with a polyvinyl alcohol based block copolymer represented by the following general formula (1), a pigment dispersion aqueous liquid containing this polyvinyl alcohol based block copolymer and a pigment in an aqueous medium, and a recording liquid containing this pigment dispersion aqueous liquid. (In the foregoing general formula (1), A represents a polyvinyl alcohol based block; B represents a block containing a hydrophobic segment B' and a hydrophilic or hydrophobic segment B" other than A and B'; X1, X2, X3, and X4 each independently represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group, or an aralkyl group (provided that such an organic group has from 1 to 20 carbon atoms and may be linear, branched or cyclic), and X1, X2, X3, and X4 may be different from each other; m1 represents an integer of from 1 to 5; m2 represents an integer of from 0 to 4; and (m1 + m2) represents an integer of from 1 to 5.)

  本发明的一个问题是提供一种记录液，该记录液能够得到印刷密度高、抑制模糊、印刷质量高、记录物牢度（包括耐光牢度、耐水色牢度等）好、粘度低、放电性能好和储存稳定性好的印刷品。 本发明涉及一种由以下通式（1）表示的聚乙烯醇基嵌段共聚物，一种在水介质中含有这种聚乙烯醇基嵌段共聚物和颜料的颜料分散水基液，以及一种含有这种颜料分散水基液的记录液。 (在前述通式（1）中，A 代表聚乙烯醇基嵌段；B 代表含有疏水段 B'和除 A 和 B' 以外的亲水或疏水段 B "的嵌段；X1、X2、X3 和 X4 各自独立地代表氢原子、卤素原子、烷基、芳基或芳烷基（条件是此类有机基团具有 1 至 20 个碳原子，并且可以是直链、支链或环链），并且 X1、X2、X3 和 X4 可以彼此不同；m1 代表 1 至 5 的整数；m2 代表 0 至 4 的整数；以及 (m1 + m2) 代表 1 至 5 的整数。)
• Polyvinyl alcohol based block copolymer and pigment dispersion aqueous liquid using the same and recording liquid
  申请人：Ueno Nobuhiko

  公开号：US20060089423A1

  公开（公告）日：2006-04-27

  A recording liquid capable of giving a printed matter which is high in printing density, is suppressed in blur, has high printing quality, and has good fastness of a recorded matter including light fastness, water fastness and the like and having a low viscosity, good discharge properties and excellent storage stability. The invention is concerned with a polyvinyl alcohol based block copolymer represented by the following general formula (1), a pigment dispersion aqueous liquid containing this polyvinyl alcohol based block copolymer and a pigment in an aqueous medium, and a recording liquid containing this pigment dispersion aqueous liquid. wherein A, B, X 1 , X 2 , X 3 , X 4 , m1, and m2 have the same meanings as defined in the specification.

  一种记录液，能够得到印刷密度高、抑制模糊、印刷质量高、记录物牢度（包括耐光牢度、耐水牢度等）好、粘度低、放电性能好、储存稳定性好的印刷品。本发明涉及一种由以下通式（1）表示的聚乙烯醇基嵌段共聚物，一种在水介质中含有该聚乙烯醇基嵌段共聚物和颜料的颜料分散水基液，以及一种含有该颜料分散水基液的记录液。 其中 A、B、X 1 , X 2 , X 3 , X 4 m1 和 m2 的含义与规范中的定义相同。
• - and -2-methoxycyclopropyllithium: novel reagents for the stereoselective syntheses of -βγ-unsaturated aldehydes
  作者：E.J. Corey、Peter Ulrich

  DOI：10.1016/s0040-4039(00)91308-x

  日期：1975.1
• US7348382B2
  申请人：——

  公开号：US7348382B2

  公开（公告）日：2008-03-25
• Synthesis of α,β-unsaturated aldehydes through palladium catalyzed regioselective hydrogen migration
  作者：Tatsuya Minami、Miyoji Hanaoka

  DOI：10.1016/s0040-4039(00)78560-1

  日期：1994.12

  Treatment of cyclic carbonate of 3-alkene-1,2-diols or 4-methylcarbonate of 2-alkene-1,4-diols with a catalytic amount of Pd(PPh3)4 in aqueous THF or AcOH gave α,β-unsaturated aldehydes in good yields. The reaction can be interpreted by the regioselective 1,4-hydrogen migration of π-allylpalladium intermediate.

  在THF或AcOH水溶液中用催化量的Pd（PPh 3）4处理3-烯烃-1,2-二醇的环状碳酸酯或2-烯烃-1,4-二醇的4-甲基碳酸酯，得到α，β-不饱和醛收率高。该反应可以通过π-烯丙基铝中间体的区域选择性1，4-氢迁移来解释。