2,12-bis[trans-Pt(PEt3)2NO3]-[7-(3,5-di-tert-butylphenyl)-5,6,8,9-tetrahydro-dibenzo[c,h]acridine] | 869641-37-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 2,12-bis[trans-Pt(PEt3)2NO3]-[7-(3,5-di-tert-butylphenyl)-5,6,8,9-tetrahydro-dibenzo[c,h]acridine]
• 英文别名: 2,12-bis[trans-Pt(PEt3)2NO3]-7-(3,5-di-tert-butyl-phenyl)-5,6,8,9-tetrahydrodibenzo[c,h]acridine；2,12-bis[trans-Pt(PEt3)2NO3]DTDA
• CAS: 869641-37-2
• 化学式: C₅₉H₉₅N₃O₆P₄Pt₂
• 分子量: 1456.47
• InChiKey: RJKIMPOATCMFQI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  2,12-bis[trans-Pt(PEt3)2NO3]-[7-(3,5-di-tert-butylphenyl)-5,6,8,9-tetrahydro-dibenzo[c,h]acridine] 、 1,3,5-tris((4-isocyano-3,5-diisopropylphenyl)ethynyl)benzene 以 水 、 丙酮 为溶剂， 以99%的产率得到bicyclo(tris[2,12-bis(trans-Pt(PEt3)2)-7-(3,5-di-tert-butylphenyl)-5,6,8,9-tetrahydrodibenzo[c,h]acridine]bis[1,3,5-tris(2-(4-isocyano-3,5-diisopropylphenyl)ethynyl)benzene])(NO3)6
  参考文献：
  名称：

  Self-Assembly of Rectangles and Prisms via a Molecular “Clip”

  摘要：

  Aromatic molecular "clips" bearing two symmetrically bound platinum moieties have been prepared. The molecular "clip" 4 readily self-assembled with linear linkers such as 4,4'-bipyridyl, 1,4-bis[2-(4-isocyano-3,5-diisopropylphenyl)ethynyl]benzene, and nicotinic acid to form molecular rectangles. The overall dimensions of the rectangle 7 were 7.3 angstrom x 15.3 angstrom. The molecular "clip" also self-assembled with tritopic pyridyl and isocyanide ligands to form trigonal prismatic frameworks. The characterization of the supramolecules by multinuclear NMR, electrospray mass spectrometry, and X-ray crystal structures is also reported.

  DOI：

  10.1021/ic0508369
• 作为产物：
  描述：

  铂(三乙基膦)4 以 二氯甲烷 、 甲苯 为溶剂， 生成 2,12-bis[trans-Pt(PEt3)2NO3]-[7-(3,5-di-tert-butylphenyl)-5,6,8,9-tetrahydro-dibenzo[c,h]acridine]
  参考文献：
  名称：

  Self-Assembly of Rectangles and Prisms via a Molecular “Clip”

  摘要：

  Aromatic molecular "clips" bearing two symmetrically bound platinum moieties have been prepared. The molecular "clip" 4 readily self-assembled with linear linkers such as 4,4'-bipyridyl, 1,4-bis[2-(4-isocyano-3,5-diisopropylphenyl)ethynyl]benzene, and nicotinic acid to form molecular rectangles. The overall dimensions of the rectangle 7 were 7.3 angstrom x 15.3 angstrom. The molecular "clip" also self-assembled with tritopic pyridyl and isocyanide ligands to form trigonal prismatic frameworks. The characterization of the supramolecules by multinuclear NMR, electrospray mass spectrometry, and X-ray crystal structures is also reported.

  DOI：

  10.1021/ic0508369

文献信息

• A molecular-clip-based approach to cofacial zinc–porphyrin complexes
  作者：Duckhyun Kim、Sewon Lee、Guohua Gao、Hong Seok Kang、Jaejung Ko

  DOI：10.1016/j.jorganchem.2009.09.035

  日期：2010.1

  We have synthesized molecular-clip-based cofacial zinc-porphyrin complexes. The complexes are shown to be new efficient receptors for the complexation of 1,4-diazabicyclo[2,2,2] octane, acridinium ions, 1,4,5,8-naphthalene tetracarboxylic dianhydride (NTDA) and 1,2,4,5-benzenetetracarboxylic dianhydride (BTDA). Large binding constants (K-asso) in the range of 2.0 x 10(4)-1.1 x 10(8) M (1) were obtained for the 1:1 complexes of molecular tweezers (3) and rectangle (8) by inserting the hosts between the two porphyrin rings. The values of K and the spectroscopic results suggest that 3 and 8 serve as effective building blocks to capture the hosts. Semi-empirical calculations show that the guests position themselves within the cleft of the bis-porphyrins. (C) 2009 Elsevier B. V. All rights reserved.