(diethyldiselenocarbamate)(diisopropyldithiophosphate)Cu(II) | 251320-53-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物
• 英文名称: (diethyldiselenocarbamate)(diisopropyldithiophosphate)Cu(II)
• CAS: 251320-53-3
• 化学式: C₁₁H₂₄CuNO₂PS₂Se₂
• 分子量: 518.889
• InChiKey: CMQBSGBAHGLCFA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  2.36
• 重原子数：
  20.0
• 可旋转键数：
  7.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.91
• 拓扑面积：
  21.7
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  (diethyldiselenocarbamate)(diisopropyldithiophosphate)Cu(II) 以 甲苯 为溶剂， 生成 (diethyldiselenocarbamate)(diisopropyldithiophosphate)Cu(I)
  参考文献：
  名称：

  Charge-transfer photochemistry of the ternary complex (diselenocarbamato, dithiophosphato)copper(II)

  摘要：

  Photolysis of the ternary system consisting of diethyldiselenocarbamate (Et,dsc), diisoproplidithiophosphate (i-Pr,dtp) and copper(II)(1:1:1) has been studied in toluene, CH2Cl2, CHCl3, CCl4, and chlolualkane-EtOH solutions. The results obtained bq EPR techniques and UV Vis data indicate that a homolytic Cu-S bond cleavage involving dtp ligand appears as the primary photoprocess in Cu(dsc)(dtp) photolysis. Further conversion of the primary photoproduct Cu-1(Et(2)dsc) is discussed in terms of specific interaction with the solvent. According to quantum yield data solvent efficiencies in photolysis could be related to their oxidizing power. A reaction mechanism is proposed well fitting the experimental results. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00520-9
• 作为产物：
  描述：

  bis(diethyldiselenocarbamate)copper(II) 、 (SP-4-1)-双[O,O-二(1-甲乙基)二硫代磷酸根合-S,S]铜 生成 (diethyldiselenocarbamate)(diisopropyldithiophosphate)Cu(II)
  参考文献：
  名称：

  Charge-transfer photochemistry of the ternary complex (diselenocarbamato, dithiophosphato)copper(II)

  摘要：

  Photolysis of the ternary system consisting of diethyldiselenocarbamate (Et,dsc), diisoproplidithiophosphate (i-Pr,dtp) and copper(II)(1:1:1) has been studied in toluene, CH2Cl2, CHCl3, CCl4, and chlolualkane-EtOH solutions. The results obtained bq EPR techniques and UV Vis data indicate that a homolytic Cu-S bond cleavage involving dtp ligand appears as the primary photoprocess in Cu(dsc)(dtp) photolysis. Further conversion of the primary photoproduct Cu-1(Et(2)dsc) is discussed in terms of specific interaction with the solvent. According to quantum yield data solvent efficiencies in photolysis could be related to their oxidizing power. A reaction mechanism is proposed well fitting the experimental results. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00520-9