trans,trans-Trideca-5,8-dien-7-one | 73838-79-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: trans,trans-Trideca-5,8-dien-7-one
• 英文别名: (5E,8E)-trideca-5,8-dien-7-one
• CAS: 73838-79-6
• 化学式: C₁₃H₂₂O
• 分子量: 194.317
• InChiKey: HYEQQVNCVQQUMQ-WGDLNXRISA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  14
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  trans,trans-Trideca-5,8-dien-7-one 在 Schwartz's reagent 、 四氯化钛 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 3.5h， 生成 (3R,5R)-3,5-Dibutyl-4-vinyl-cyclohexanone
  参考文献：
  名称：

  Novel CuBr·SMe₂Catalyzed Conjugate Addition of 3-Trimethylsilyl-1-propenylzirconocene to Divinylketones. Stereoselective Synthesis of Poly­substituted Cyclohexanones

  摘要：

  催化量的CuBr·SMe2存在下，(E)-3-三甲基硅基-1-丙烯基锆杂环戊二烯与(E,E)-二乙烯基酮在温和条件下进行共轭加成，以良好产率得到含(E)-α,β-不饱和羰基部分的(E)-烯丙基硅烷。这些化合物经TiCl4处理后可发生高度立体控制性的硅辅助分子内环化反应，生成多取代环己酮。

  DOI：

  10.1055/s-2003-37525
• 作为产物：
  描述：

  一氧化碳 、 trans-1-Hexenylmercuric chloride 在 di(rhodium)tetracarbonyl dichloride lithium chloride 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 以78%的产率得到trans,trans-Trideca-5,8-dien-7-one
  参考文献：
  名称：

  Mercury in organic chemistry. 18. Synthesis of symmetrical divinyl and diaryl ketones via rhodium-catalyzed carbonylation of vinyl- and arylmercurials

  摘要：

  DOI：

  10.1021/jo01307a022

文献信息

• [EN] TRANSITION METAL COMPLEXES, ESPECIALLY IRON COMPLEXES, USED AS A CATALYST COMPONENT IN THE POLYMERISATION OF OLEFINS<br/>[FR] COMPLEXES DE METAUX DE TRANSITION, EN PARTICULIER COMPLEXES DE FER, UTILISES EN TANT QUE CONSTITUANTS CATALYTIQUES DE POLYMERISATION D'OLEFINES
  申请人：IC INNOVATIONS LTD

  公开号：WO2004081020A1

  公开（公告）日：2004-09-23

  The present invention relates to compounds of formula (I) wherein each of X, Y, Z is independently selected from 0, S, NR1, CR2R3, N and CR4, and where optionally X-Y, Y-Z, Z-E1 and X-E2 each independently form part of a saturated or unsaturated ring system which may be substituted or unsubstituted; m is 0 or 1; M is a metal selected from Ti[III], Ti[IV], Fe[II], Fe[III], Co[I], Co[II], Co[III], Ni[II], Cr[III], Mn[II], Mn[III], Mn[IV], Ru[II], Ru[III], Ru[IV], Pd[II], V[II], V[III], V[IV], V[V], Cu[I], Cu[II], Rh[I], Rh[III], Mo[III], Mo[V], Re[I] and Re[II]; each of E1 and E2 is independently selected from O, S, NR5, N, P, PR6, where at least one of either E1 or E2 carries a formal negative charge; L2 is a one electron donor ligand; n is zero or an integer such that the compound has an overall charge of zero or +1; L1 is NR7RB, PR7RB, OR7, SR7, O, S or NR16, imidazolyl, pyridinyl, benzimidazolyl or quinolinyl; each of R1-8 and R16 is independently H or a hydrocarbyl group; Q is a linker group; and r is 0 or 1. Further aspects of the invention relate to catalyst compositions comprising compounds of formula (I), and their use in the polymerisation of olefinically unsaturated monomers.

  本发明涉及具有以下结构的化合物（I）：其中X、Y、Z中的每一个独立选择自0、S、NR1、CR2R3、N和CR4，其中可选地X-Y、Y-Z、Z-E1和X-E2中的每一个独立地形成饱和或不饱和环系统的一部分，该环系统可以被取代或未取代；m为0或1；M为从Ti[III]、Ti[IV]、Fe[II]、Fe[III]、Co[I]、Co[II]、Co[III]、Ni[II]、Cr[III]、Mn[II]、Mn[III]、Mn[IV]、Ru[II]、Ru[III]、Ru[IV]、Pd[II]、V[II]、V[III]、V[IV]、V[V]、Cu[I]、Cu[II]、Rh[I]、Rh[III]、Mo[III]、Mo[V]、Re[I]和Re[II]中选择的金属；E1和E2中的每一个独立选择自O、S、NR5、N、P、PR6，其中E1或E2中的至少一个带有正式负电荷；L2是一个单电子供体配体；n为零或整数，使得化合物的总电荷为零或+1；L1为NR7RB、PR7RB、OR7、SR7、O、S或NR16、咪唑基、吡啶基、苯并咪唑基或喹啉基；R1-8和R16中的每一个独立地为H或烃基；Q为连接基团；r为0或1。本发明的其他方面涉及包含化合物（I）的催化剂组合物，以及它们在烯烃不饱和单体的聚合中的使用。
• Palladium Complexes and Polymerization and Coupling Processes Thereof
  申请人：Goodson, III Felix E.

  公开号：US20090111962A1

  公开（公告）日：2009-04-30

  The present invention is related to palladium complexes having substituted diarylideneacetone ligands and coupling and polymerization processes thereof.

  本发明涉及具有取代二芳基丙酮配体的钯配合物及其偶联和聚合过程。
• Acrylic Polymers Having Controlled Placement of Functional Groups
  申请人：Lester Christopher L.

  公开号：US20110118372A1

  公开（公告）日：2011-05-19

  Acrylic copolymers that include the controlled placement of functional groups within the polymer structure are provided. The copolymers contain a reactive segment and a non-reactive segment and are manufactured via a controlled radical polymerization process. The copolymers are useful in the manufacture of adhesives and elastomers.

  提供了包含在聚合物结构内控制放置功能基团的丙烯酸酯共聚物。该共聚物包含反应性段和非反应性段，并通过受控自由基聚合过程制造。该共聚物在制造粘合剂和弹性体中非常有用。
• Process for polymerizing acrylonitrile
  申请人：Case Western Reserve University

  公开号：EP0872493A2

  公开（公告）日：1998-10-21

  This invention relates to a process for polymerising acrylonitrile, comprising: (A) forming a polymerisable mixture comprising acrylonitrile monomer, solvent and a metal catalyst; (B) contacting said mixture with an initiator, said initiator being selected from the group consisting of sulfonyl halides, halopropionitriles, substituted halopropionitriles in the form of monoadducts derived from sulfonyl halides and acrylonitrile, monoadducts derived from substituted sulfonyl halides and monomers other than acrylonitrile; or polymers containing end groups derived from sulfonyl halides, halopropionitriles, substituted halopropionitriles in the form of monoadducts derived from sulfonyl halides and acrylonitrile, or monoadducts derived from substituted sulfonyl halides and monomers other than acrylonitrile; and (C) polymerising said acrylonitrile monomer to form a polymer comprised of acrylonitrile. In one embodiment, the polymerisable mixture in step (A) further comprises at least one polymerisable comonomer other than acrylonitrile, and the polymer formed during step (C) is a copolymer or a multicomponent copolymer comprised of acrylonitrile and said at least one other polymerisable comonomer.

  本发明涉及一种聚合丙烯腈的工艺，包括(A) 形成由丙烯腈单体、溶剂和金属催化剂组成的可聚合混合物； (B) 将所述混合物与引发剂接触，所述引发剂选自以下组别：磺酰卤、卤丙酰腈、由磺酰卤和丙烯腈衍生的单体形式的取代卤丙酰腈、由取代磺酰卤和丙烯腈以外的单体衍生的单体；(C) 聚合所述丙烯腈单体以形成由丙烯腈组成的聚合物。在一个实施方案中，步骤(A)中的可聚合混合物还包括至少一种丙烯腈以外的可聚合共聚单体，而步骤(C)中形成的聚合物是由丙烯腈和所述至少一种其他可聚合共聚单体组成的共聚物或多组分共聚物。
• POROUS FILM AND SECONDARY CELL ELECTRODE
  申请人：Zeon Corporation

  公开号：EP2282364A1

  公开（公告）日：2011-02-09

  The invention intends to provide a porous film which is formed on a surface of an electrode used for such as a secondary battery and the like, which has excellent binding property and is capable to contribute for improving a cyclic characteristic of the battery. A porous film according to the present invention comprises water soluble polymer, inorganic filler and water insoluble polymer comprising 0.5 to 40mass% of monomer unit including hydrophilic group selected from the group consisting of carboxylate group, hydroxyl group and sulfonic acid group.

  本发明旨在提供一种多孔薄膜，该薄膜形成于二次电池等所用电极的表面，具有极佳的结合性能，并有助于改善电池的循环特性。 根据本发明，多孔薄膜包括 水溶性聚合物、无机填料和水不溶性聚合物，其中水不溶性聚合物包含 0.5 至 40mass% 的单体单元，单体单元中的亲水基团选自羧酸基、羟基和磺酸基组成的组。