potassium 11-hydroxydodecyltrifluoroborate | 906007-43-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: potassium 11-hydroxydodecyltrifluoroborate
• CAS: 906007-43-0
• 化学式: C₁₂H₂₅BF₃O*K
• 分子量: 292.234
• InChiKey: RBTAWSSFPPJFOA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.73
• 重原子数：
  18.0
• 可旋转键数：
  11.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.23
• 氢给体数：
  1.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  potassium 11-hydroxydodecyltrifluoroborate 在 2-碘苯甲酸 作用下， 以 丙酮 为溶剂， 生成
  参考文献：
  名称：

  Oxidation of Hydroxyl-Substituted Organotrifluoroborates

  摘要：

  Potassium- and tetra-n-butylammonium organotrifluoroborates containing hydroxyl groups have been prepared and oxidized using several common oxidants. Aryl-, alkenyl-, and alkyltrifluoroborates containing both primary and secondary hydroxyl groups were oxidized in moderate to excellent yields with complete retention of the trifluoroborate moiety. The utility of these oxidized products was demonstrated in a Suzuki-Miyaura cross-coupling reaction.

  DOI：

  10.1021/ja062974i
• 作为产物：
  描述：

  dodec-11-en-2-ol 在 potassium hydrogen bifluoride 、 吡啶硼烷 、 碘 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 反应 20.0h， 生成 potassium 11-hydroxydodecyltrifluoroborate
  参考文献：
  名称：

  Oxidation of Hydroxyl-Substituted Organotrifluoroborates

  摘要：

  Potassium- and tetra-n-butylammonium organotrifluoroborates containing hydroxyl groups have been prepared and oxidized using several common oxidants. Aryl-, alkenyl-, and alkyltrifluoroborates containing both primary and secondary hydroxyl groups were oxidized in moderate to excellent yields with complete retention of the trifluoroborate moiety. The utility of these oxidized products was demonstrated in a Suzuki-Miyaura cross-coupling reaction.

  DOI：

  10.1021/ja062974i