3,4,5,6,7,8,9,10,11,12-decahydro-2H-triphenylen-1-one | 29509-01-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 3,4,5,6,7,8,9,10,11,12-decahydro-2H-triphenylen-1-one
• 英文别名: 1-Keto-1,2,3,4,5,6,7,8,9,10,11,12-dodecahydro-triphenylen；Dodecahydrotriphenylen-1-on；3,4,5,6,7,8,9,10,11,12-decahydro-2H-triphenylen-1-one；3,4,5,6,7,8,9,10,11,12-Decahydro-2H-triphenylen-1-on
• CAS: 29509-01-1
• 化学式: C₁₈H₂₂O
• 分子量: 254.372
• InChiKey: LKAHUFUNQPCZKJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.96
• 重原子数：
  19.0
• 可旋转键数：
  0.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.61
• 拓扑面积：
  17.07
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  3,4,5,6,7,8,9,10,11,12-decahydro-2H-triphenylen-1-one 在 palladium on activated charcoal lithium aluminium tetrahydride 、 氢气 作用下， 以 四氢呋喃 、 正庚烷 为溶剂， 生成 Perhydrotriphenylen-2-carbonsaeuremethylester
  参考文献：
  名称：

  过氢三亚苯基的立体化学-Ⅰ：关于结构和反应性的一些评论

  摘要：

  讨论了过氢三亚苯基的立体化学，并与肌醇的立体化学进行了比较，无论是异构体的数量还是手性。在十种异构体（其中六种是手性）中，特别关注反-反-反-反-反-反-异构体（I），详细描述了其合成，结构，物理性质和反应性。讨论了羧基处于赤道位置的全氢三苯-2-羧酸（XV）的合成和结构。还提到了获得具有相同结构的其他化合物的尝试。

  DOI：

  10.1016/s0040-4020(01)92759-0
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 硫酸 作用下， 生成 3,4,5,6,7,8,9,10,11,12-decahydro-2H-triphenylen-1-one
  参考文献：
  名称：

  Personality disorders and psychoses form two distinct subgroups of homicide among female offenders

  摘要：

  This study examined circumstances of homicide by women in relation to their subsequent diagnoses. We investigated the written reports of forensic psychiatric examinations on 125 Finnish women who committed murder, attempted murder, manslaughter, or attempted manslaughter during 1982-92. In 86% of the cases the victims were adults, in 15% children. Intimate partners were the victims in 54% of the cases. Stabbing was the most frequent method and a quarrel the most frequent motive. The diagnoses of personality disorders and psychoses formed distinct subgroups. Psychotic women attacked proportionally more children than the personality disordered, who mainly attacked adults. Personality disordered women were more likely to have been intoxicated with alcohol at the time. Future treatment programmes and studies are suggested.

  DOI：

  10.1080/09585180122116

文献信息

• Site-selective unidirectional benzylic sp³ C–H oxidation of dodecahydrotriphenylene with RuCl₃–NaIO₄: formation of benzylic ketones
  作者：Gaurang J. Bhatt、Pradeep T. Deota、Deepak Upadhyay、Prafulla K. Jha

  DOI：10.1039/d1ra06897k

  日期：——

  Dodecahydrotriphenylene, a higher homologue of trindane chemoselectively undergoes unidirectional benzylic sp³ C–H oxidation and the central benzene ring remains intact unlike that in trindane under similar reaction conditions.

  十二氢三苯基乙烷是三苯基乙烷的高级同系物，在化学选择性上经历了一向单向的苄基sp3 C-H氧化反应，而中心苯环保持完整，这与三苯基乙烷在类似反应条件下的情况不同。
• 437. Isomerisation reactions. Part II
  作者：G. M. Badger、W. Carruthers、J. W. Cook

  DOI：10.1039/jr9490002044

  日期：——
• 434. Preparation and isomerisation of aromatic ketones and keto-acids
  作者：G. Baddeley、R. Williamson

  DOI：10.1039/jr9530002120

  日期：——
• Benzologues of perylene, coronene and anthanthrene
  作者：E. Clar、A. McCallum

  DOI：10.1016/s0040-4020(01)98612-0

  日期：1964.1