ethyl tricyclo[5.2.1.02,6 ]decane-2-carboxylate | 129520-41-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: ethyl tricyclo[5.2.1.02,6 ]decane-2-carboxylate
• 英文别名: Fruitate；ethyl tricyclo[5.2.1.0^2.6]decan-2-carboxylate；4,7-Methano-3aH-indene-3a-carboxylic acid, octahydro-, ethyl ester；ethyl tricyclo[5.2.1.02,6]decane-2-carboxylate
• CAS: 129520-41-8
• 化学式: C₁₃H₂₀O₂
• 分子量: 208.301
• InChiKey: MGQPKOBPXHENPO-UHFFFAOYSA-N

物化性质

• 物理描述：
  Liquid

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  Tricyclo<5.2.1.0^2,6>decane-2-carboxylic acid 在 sodium hydroxide 作用下， 以 硫酸二乙酯 为溶剂， 以90%的产率得到ethyl tricyclo[5.2.1.02,6 ]decane-2-carboxylate
  参考文献：
  名称：

  Fragrant tricyclic carboxylates

  摘要：

  三环羧酸酯具有以下化学式：##STR1## 其中R是2或3个碳原子的烷基。这些化合物具有木质香味，并且作为香水配方的组分非常有用。

  公开号：

  US04411828A1

文献信息

• [EN] WOODY ODORANTS<br/>[FR] MATIÈRES ODORANTES BOISÉES
  申请人：FIRMENICH & CIE

  公开号：WO2013092781A1

  公开（公告）日：2013-06-27

  The present invention concerns compounds of formula (I) in the form of any one of its stereoisomers or a mixture thereof, and wherein one dotted line represents a carbon-carbon single or double bond and the others a carbon-carbon single bond; each R, independently from each other, represents a hydrogen atom or a methyl or ethyl group provided that at least one of said R groups represents a methyl or ethyl group; and R1 represents a methyl or ethyl group; and their use in perfumery to impart odor notes of the woody type having cedar, ambery, patchouli and/or rooty aspect.

  本发明涉及公式（I）的化合物，其为其立体异构体之一或其混合物的形式，其中一个点线代表碳-碳单键或双键，其他代表碳-碳单键；每个R，彼此独立，代表氢原子或甲基或乙基基团，前提是至少其中一个R基团代表甲基或乙基基团；R1代表甲基或乙基基团；以及它们在香水中的使用，用于赋予具有雪松、琥珀、广藿香和/或根茎特征的木质气味。
• UNSATURATED MACROCYCLIC EPOXIDE AS PERFUMING INGREDIENT
  申请人：Firmenich SA

  公开号：US20170058236A1

  公开（公告）日：2017-03-02

  The present invention relates to a compound of formula (I) in the form of any one of its stereoisomers or a mixture thereof which is useful as perfuming ingredients.

  本发明涉及一种化合物，其化学式为(I)，其立体异构体或其混合物形式，可用作香料成分。
• ANTIMICROBIAL GEL FORMULATIONS
  申请人：Wang Lu

  公开号：US20100076089A1

  公开（公告）日：2010-03-25

  Disclosed herein are formulations comprising an N-halogenated or N,N-dihalogenated amine compound dispersed in a water-swellable polymer, wherein the compound is 90% stable for at least 30 days at about 25° C. Also disclosed are methods of treating or preventing infections caused by a bacterial, a microbial, a sporal, a fungal or a viral activity using such formulations.

  本文揭示了一种配方，其中包含一种N-卤代或N,N-二卤代胺化合物分散在可水肿胀的聚合物中，其中该化合物在大约25°C下稳定90％，至少30天。还揭示了使用这种配方治疗或预防由细菌、微生物、孢子、真菌或病毒活性引起的感染的方法。
• MODIFIED NAPHTHALENE FORMALDEHYDE RESIN, TRICYCLODECANE SKELETON-CONTAINING NAPHTHOL COMPOUND AND ESTER COMPOUND
  申请人：Kita Seiji

  公开号：US20120238775A1

  公开（公告）日：2012-09-20

  A modified dimethylnaphthalene formaldehyde resin obtained by modifying a polyfunctional dimethylnaphthalene formaldehyde resin having a constituent unit represented by the following general formula [1] in a molecule thereof with at least one member selected from the group consisting of a phenol represented by the following general formula [2], a naphthol represented by the following general formula [3] and a naphthol represented by the following general formula [4] provided that at least any of the naphthol represented by the general formula [3] or the naphthol represented by the general formula [4] must be included.

  通过使用下列通式[1]所代表的单元作为分子单元，将多官能团二甲基萘醛树脂改性，至少使用下列通式[2]所代表的酚、下列通式[3]所代表的萘酚或下列通式[4]所代表的萘酚中的一种对其进行改性，其中至少包含下列通式[3]所代表的萘酚或下列通式[4]所代表的萘酚中的任意一种。
• Production of carboxylic acids or carboxylic acid esters
  申请人：Kitamura Mitsuharu

  公开号：US20060205970A1

  公开（公告）日：2006-09-14

  In the production of carboxylic acid or carboxylic acid ester, a reaction product containing the carboxylic acid or carboxylic acid ester which has been produced by the reaction of an olefin, carbon monoxide, and water or an alcohol in the presence of HF is heat-treated in the presence of an acid catalyst and an acid adsorbent. By the heat treatment, the contamination of the carboxylic acid or carboxylic acid ester with HF and/or fluorine compounds such as acyl fluorides can be prevented, to enable the stable production of a high quality and high purity carboxylic acid or carboxylic acid ester without causing troubles such as corrosion of apparatus.

  在制备羧酸或羧酸酯时，将烯烃、一氧化碳和水或醇在HF存在下反应产生的含有羧酸或羧酸酯的反应产物，在存在酸催化剂和酸吸附剂的情况下进行热处理。通过热处理，可以防止羧酸或羧酸酯受到HF和/或酰基氟化物等氟化合物的污染，从而实现稳定生产高质量、高纯度的羧酸或羧酸酯，同时避免设备腐蚀等问题的发生。