[Ni(anthranilic acid(-1H))2(H2O)2] | 1269791-83-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [Ni(anthranilic acid(-1H))2(H2O)2]
• CAS: 1269791-83-4
• 化学式: C₁₄H₁₆N₂NiO₆
• 分子量: 366.981
• InChiKey: AYNIAQZLMJVGRP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Ni(anthranilic acid(-1H))2(H2O)2] 以 neat (no solvent) 为溶剂， 生成 nickel(II) oxide
  参考文献：
  名称：

  Synthesis, characterization and optical band gap of NiO nanoparticles derived from anthranilic acid precursors via a thermal decomposition route

  摘要：

  This study focuses on the preparation and characterization of single phase NiO nano particles. Four nickel anthranilic acid complexes were synthesized by the semi-solid phase reaction method as precursors for the preparation of NiO nanoparticles via a solid-state decomposition procedure at 700 degrees C. Thermogravimetric analysis (TGA) was applied to determine the thermal behavior of the precursors and the temperature at which the precursors decompose leaving the oxide. The crystalline structures of the products were investigated by X-ray diffraction (XRD), the morphology of particles by SEM and TEM. The particles size was determined by STM and the average particle size was found to be 8 nm. Electronic spectra were used to clarify qualitatively the change in absorption band positions on changing the particle size of NiO. The optical band gap of the NiO nanoparticles was calculated and indicated a direct transition. The values of the optical band gap of NiO nanoparticles increase as the particle size decreases. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.11.020
• 作为产物：
  描述：

  水 、 邻氨基苯甲酸 、 nickel(II) acetate tetrahydrate 以 水 为溶剂， 生成 [Ni(anthranilic acid(-1H))2(H2O)2]
  参考文献：
  名称：

  Synthesis, characterization and optical band gap of NiO nanoparticles derived from anthranilic acid precursors via a thermal decomposition route

  摘要：

  This study focuses on the preparation and characterization of single phase NiO nano particles. Four nickel anthranilic acid complexes were synthesized by the semi-solid phase reaction method as precursors for the preparation of NiO nanoparticles via a solid-state decomposition procedure at 700 degrees C. Thermogravimetric analysis (TGA) was applied to determine the thermal behavior of the precursors and the temperature at which the precursors decompose leaving the oxide. The crystalline structures of the products were investigated by X-ray diffraction (XRD), the morphology of particles by SEM and TEM. The particles size was determined by STM and the average particle size was found to be 8 nm. Electronic spectra were used to clarify qualitatively the change in absorption band positions on changing the particle size of NiO. The optical band gap of the NiO nanoparticles was calculated and indicated a direct transition. The values of the optical band gap of NiO nanoparticles increase as the particle size decreases. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.11.020