1,3-Diphenyl-3-(2-propylsulfanylethylamino)prop-2-en-1-one | 1005761-70-5

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 直链 1,3-二芳基丙烷
• 英文名称: 1,3-Diphenyl-3-(2-propylsulfanylethylamino)prop-2-en-1-one
• 英文别名: 1,3-diphenyl-3-(2-propylsulfanylethylamino)prop-2-en-1-one
• CAS: 1005761-70-5
• 化学式: C₂₀H₂₃NOS
• 分子量: 325.475
• InChiKey: BYLOCIKMFQBHMC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  23
• 可旋转键数：
  9
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  54.4
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1,3-Diphenyl-3-(2-propylsulfanylethylamino)prop-2-en-1-one 、 四氯化钛 在 potassium hydride 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 生成 [(1Z,3Z)-1,3-diphenyl-3-(2-(propylthio)ethylimino)prop-1-en-1-olate]Ti(IV)Cl3
  参考文献：
  名称：

  Synthesis, characterization, and catalytic behaviors of β-carbonylenamine-derived metal complexes (M = Ti, Zr) in styrene polymerization

  摘要：

  The titanium and zirconium complexes based on thioether substituted beta-carbonylenamine were prepared and characterized. In the presence of MMAO, the titanium complexes showed good activity in syndiospecific styrene polymerization with high syndioselectivity, and performed good thermal stability. Electron withdrawing group on ligands is beneficial to the styrene polymerization. [1,3-diphenyl-3-(2-(isopropylthio)ethylimino)prop-1-en-1-olate](2)ZrCl2(IV) could also polymerize styrene to give syndiotactic polymer, however in low activity and with low syndioselectivity. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2014.02.021
• 作为产物：
  描述：

  [2-(丙基硫代)乙基]胺盐酸盐 、 二苯甲酰基甲烷 生成 1,3-Diphenyl-3-(2-propylsulfanylethylamino)prop-2-en-1-one
  参考文献：
  名称：

  Copolymerization of Ethylene with Functionalized Olefins by [ONX] Titanium Complexes

  摘要：

  A series of titanium complexes bearing [ONX] tridentate ligands have been synthesized and characterized. The complexes containing sulfur or phosphine donors showed high activity in the copolymerization of ethylene with 9-decen-1-ol (up to 1.3 x 10(8) g polymer (mol Ti)(-1) h(-1)) with an incorporation ratio of up to 8.8 mol %. Moreover, they have also shown excellent capability for copolymerization of ethylene with AlBu3i (or tert-butylchlorodimethylsilane) pretreated 4-penten-1-ol, omega-alkenoic acid, and omega-alkenoic ester, as well as unprotected tertiary amine.

  DOI：

  10.1021/ma400283p