tert-butyl 3-(methoxycarbonyl)cyclohexanecarboxylate | 122699-77-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: tert-butyl 3-(methoxycarbonyl)cyclohexanecarboxylate
• 英文别名: 1-O-tert-butyl 3-O-methyl cyclohexane-1,3-dicarboxylate
• CAS: 122699-77-8
• 化学式: C₁₃H₂₂O₄
• 分子量: 242.315
• InChiKey: SPOVBXLKSQJVTF-UHFFFAOYSA-N

物化性质

• 沸点：
  299.8±15.0 °C(Predicted)
• 密度：
  1.047±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  17
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.85
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  tert-butyl 3-(methoxycarbonyl)cyclohexanecarboxylate 在 吡啶 、 lithium aluminium tetrahydride 、 sodium iodide 作用下， 以 四氢呋喃 、 二氯甲烷 、 丙酮 为溶剂， 反应 1.5h， 生成 tert-butyl 3-(iodomethyl)cyclohexanecarboxylate
  参考文献：
  名称：

  Reaction pathways of 3-(3'-methylenecyclobutyl)propyl and 2-(3'-methylenecyclobutyl)ethyl radicals

  摘要：

  DOI：

  10.1021/jo00281a043
• 作为产物：
  描述：

  1-羧酸-3-甲酸甲酯环己烷 在 氯化亚砜 、 N,N-二甲基苯胺 作用下， 生成 tert-butyl 3-(methoxycarbonyl)cyclohexanecarboxylate
  参考文献：
  名称：

  Reaction pathways of 3-(3'-methylenecyclobutyl)propyl and 2-(3'-methylenecyclobutyl)ethyl radicals

  摘要：

  DOI：

  10.1021/jo00281a043

文献信息

• PROCESS FOR PRODUCING EXPANDABLE STYRENE POLYMER COMPOSITIONS
  申请人：Husemann Wolfram

  公开号：US20110291040A1

  公开（公告）日：2011-12-01

  A composition comprising at least one expandable styrene polymer component and at least one cyclohexanecarboxylic ester and also optionally further components can be processed to mechanically robust foam materials.

  本发明涉及一种组合物，包括至少一种可膨胀苯乙烯聚合物组分和至少一种环己烷羧酸酯，还可以选择性地加入其他组分，可加工成具有机械强度的泡沫材料。
• CYCLOHEXANE POLYCARBOXYLIC ACID DERIVATIVES AS PLASTICIZERS FOR ADHESIVES AND SEALANTS
  申请人：Mack Helmut

  公开号：US20110232825A1

  公开（公告）日：2011-09-29

  The invention provides an adhesive or sealant comprising at least (A) one compound selected from the group consisting of silylated polyurethanes, silylated polyureas, silylated polyethers, silylated polysulfides and silyl-terminated acrylates, and at least (B) one cyclohexane polycarboxylic acid derivative. The composition has enhanced extensibility with good adhesion properties and high tensile strength. A process is disclosed for preparing the adhesive or sealant, and also disclosed is the use thereof for producing material bonds between parts to be joined.

  本发明提供了一种粘合剂或密封剂，包括至少（A）从包括硅化聚氨酯、硅化聚氨基甲酸酯、硅化聚醚、硅化聚硫化物和硅基终止丙烯酸酯的群组中选择的一种化合物，以及至少（B）一种环己烷聚羧酸衍生物。该组合物具有良好的粘附性和高拉伸强度的增强延展性。还公开了制备粘合剂或密封剂的过程，并公开了将其用于在要连接的零件之间产生材料粘结的用途。
• PIGOU, PAUL E., J. ORG. CHEM., 54,(1989) N0, C. 4943-4950
  作者：PIGOU, PAUL E.

  DOI：——

  日期：——
• Single piece closure device made of pvc
  申请人：Breitscheidel Boris

  公开号：US20050106405A1

  公开（公告）日：2005-05-19

  The present invention relates to one-part closure devices encompassing at least polyvinyl chloride and at least one plasticizer, in particular at least one substituted or unsubstituted cyclohexanedicarboxylic acid or a derivative thereof, to a process for producing a closure device of this type, and also to the use of a closure device of the invention as a closure for containers, in particular for wine bottles or other bottles.
• Use of Cyclohexane Polycarboxylic Acid Derivatives For Removing Dust From Chemical Construction Products
  申请人：Weichmann Josef

  公开号：US20110209644A1

  公开（公告）日：2011-09-01

  The use of cyclohexanepolycarboxylic acid derivatives for reducing or minimizing the dust emission when handling pulverulent construction chemistry products, processes for the preparation of the pulverulent construction chemistry products and hydraulically setting materials containing the cyclohexanepolycarboxylic acid derivatives according to the invention are proposed.