dilauroyl peroxide | 56038-98-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: dilauroyl peroxide
• 英文别名: DLP；ditridecanoyl peroxide；Ditridecanoyl-peroxid；Tridecanoyl tridecaneperoxoate
• CAS: 56038-98-3
• 化学式: C₂₆H₅₀O₄
• 分子量: 426.681
• InChiKey: FZERQTXIYIJFIF-UHFFFAOYSA-N

物化性质

• 沸点：
  493.0±28.0 °C(Predicted)
• 密度：
  0.918±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  11.6
• 重原子数：
  30
• 可旋转键数：
  25
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-羟基-1,4-萘醌 、 dilauroyl peroxide 在 溶剂黄146 、 Petroleum ether 作用下， 生成 2-Dodecyl-3-hydroxy-1,4-naphthoquinone
  参考文献：
  名称：

  Fieser et al., Journal of the American Chemical Society, 1948, vol. 70, p. 3177

  摘要：

  DOI：
• 作为产物：
  描述：

  十三酸 在 吡啶 、 氯化亚砜 、 双氧水 作用下， 以 乙醚 为溶剂， 反应 1.0h， 生成 dilauroyl peroxide
  参考文献：
  名称：

  McBride, J. Michael; Bertman, Steven B.; Cioffi, Donna Z., Molecular Crystals and Liquid Crystals (1969-1991), 1988, vol. 161, p. 1 - 24

  摘要：

  DOI：
• 作为试剂：
  描述：

  4-乙烯基-1-环己烯 、 O-ethyl-1-fluoro-2,2,2-trifluoroethyl xanthate 在 dilauroyl peroxide 作用下， 以 乙酸乙酯 为溶剂， 以58%的产率得到S-(1-(cyclohex-3-en-1-yl)-3,4,4,4-tetrafluorobutyl) O-ethyl carbonodithioate
  参考文献：
  名称：

  O-Ethyl-S-(1,2,2,2-Tetrafluoroethyl)-Dithiocarbonate: A Convenient Reagent for the Generation and Capture of 1,2,2,2-Tetra­fluoroethyl Radicals

  摘要：

  The synthesis of a new fluorinated reagent O-ethyl S-(1,2,2,2-tetrafluoroethyl) carbonodithioate (xanthate) and its use for the generation and capture of the hitherto unexplored 1,2,2,2-tetrafluoroethyl radicals is described. This reagent allows the convenient introduction of the rare CF3CHF motif onto various olefinic substrates with a high functional-group tolerance.

  DOI：

  10.1055/s-0035-1560539

文献信息

• Siosomal formulation for intracellular delivery and targeting of therapeutic agents
  申请人：Salama, Zoser B.

  公开号：EP2384743A1

  公开（公告）日：2011-11-09

  The invention relates to a carrier and targeting system for the intracellular delivery and triggered release of a siosome- and/or siosome-liposome-entrapped or encapsulated active substance or therapeutic agent. The invention further relates to the targeted release and delivery of doxorubicin, cis-platin, carbo-platin and/or oxali-platin, characterized in that one or more anionic lipids, such as cholesteryl hemisuccinate residues, cardiolipin and/or their derivatives and/or other anionic groups, are covalently linked to the silicone central atom of the silanes, sugar silanes and/or amino-sugar silanes. The invention further relates to the use of cationic lipids that are covalently attached to the silicone central atom of the silanes. The invention also relates to a method for preparing such carrier and targeting systems and methods for their administration.

  该发明涉及一种用于细胞内递送和触发释放siosome和/或siosome-脂质体包埋或封装活性物质或治疗剂的载体和靶向系统。该发明还涉及对阿霉素、顺铂、卡铂和/或奥沙利铂的靶向释放和递送，其特征在于将一个或多个阴离子脂质，如胆固醇半琥珀酸酯残基、心磷脂和/或它们的衍生物和/或其他阴离子基团，共价连接到硅烷、糖硅烷和/或氨基糖硅烷的硅中心原子上。该发明还涉及将阳离子脂质共价连接到硅烷的中心原子的使用。该发明还涉及一种制备这种载体和靶向系统的方法以及它们的给药方法。
• Fieser; Chamberlin, Journal of the American Chemical Society, 1948, vol. 70, p. 74
  作者：Fieser、Chamberlin

  DOI：——

  日期：——
• Peroxides. VI.² Preparation of t-Butyl Peresters and Diacyl Peroxides of Aliphatic Monobasic Acids³
  作者：Leonard S. Silbert、Daniel Swern

  DOI：10.1021/ja01519a023

  日期：1959.5
• Electrolyte for lithium battery and lithium battery comprising same
  申请人：Kim Jun-Ho

  公开号：US20070212614A1

  公开（公告）日：2007-09-13

  An electrolyte for a lithium battery includes a non-aqueous organic solvent, a lithium salt, and an additive comprising a) a compound represented by the following Formula (1), and b) a compound selected from the group consisting of a sulfone-based compound, a poly(ester)(metha)acrylate, a polymer of poly(ester)(metha)acrylate, and a mixture thereof: wherein R 1 is a C 1 to C 10 alkyl, a C 1 to C 10 alkoxy, or a C 6 to C 10 aryl, and preferably a methyl, ethyl, or methoxy, X is a halogen, and m and n are integers ranging from 1 to 5, where m+n is less than or equal to 6.
• ELECTROLYTE FOR LITHIUM BATTERY AND LITHIUM BATTERY COMPRISING SAME
  申请人：KIM Jun-Ho

  公开号：US20090269674A1

  公开（公告）日：2009-10-29

  An electrolyte for a lithium battery includes a non-aqueous organic solvent, a lithium salt, and an additive comprising a) a compound represented by the following Formula (1), and b) a compound selected from the group consisting of a sulfone-based compound, a poly(ester)(metha)acrylate, a polymer of poly(ester)(metha)acrylate, and a mixture thereof: wherein R 1 is a C 1 to C 10 alkyl, a C 1 to C 10 alkoxy, or a C 6 to C 10 aryl, and preferably a methyl, ethyl, or methoxy, X is a halogen, and m and n are integers ranging from 1 to 5, where m+n is less than or equal to 6.