1-[2-[2-[2-(2-氯乙氧基)乙氧基]乙氧基]乙基]咪唑 | 825650-63-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 中文名称: 1-[2-[2-[2-(2-氯乙氧基)乙氧基]乙氧基]乙基]咪唑
• 英文名称: 1-(1-chloro-4,7,10-trioxadodecyl)-imidazole
• 英文别名: 1-(2-{2-[2-(2-Chloroethoxy)ethoxy]ethoxy}ethyl)-1H-imidazole；1-[2-[2-[2-(2-chloroethoxy)ethoxy]ethoxy]ethyl]imidazole
• CAS: 825650-63-3
• 化学式: C₁₁H₁₉ClN₂O₃
• 分子量: 262.736
• InChiKey: VJQMGBCFNZMCHB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.1
• 重原子数：
  17
• 可旋转键数：
  11
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  45.5
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1-[2-[2-[2-(2-氯乙氧基)乙氧基]乙氧基]乙基]咪唑 以 乙腈 为溶剂， 以82%的产率得到
  参考文献：
  名称：

  Design and synthesis of novel imidazolium-based ionic liquids with a pseudo crown-ether moiety: diastereomeric interaction of a racemic ionic liquid with enantiopure europium complexes

  摘要：

  A planar-chiral imidazolium salt with a tris(oxoethylene) bridge was synthesized, and its potential application as a room temperature ionic liquid with a molecular-recognition ability was demonstrated. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.10.073
• 作为产物：
  描述：

  咪唑 、 双[2-(2-氯化乙氧基)乙基]醚 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 以91%的产率得到1-[2-[2-[2-(2-氯乙氧基)乙氧基]乙氧基]乙基]咪唑
  参考文献：
  名称：

  Design and synthesis of novel imidazolium-based ionic liquids with a pseudo crown-ether moiety: diastereomeric interaction of a racemic ionic liquid with enantiopure europium complexes

  摘要：

  A planar-chiral imidazolium salt with a tris(oxoethylene) bridge was synthesized, and its potential application as a room temperature ionic liquid with a molecular-recognition ability was demonstrated. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.10.073

文献信息

• Design and synthesis of novel imidazolium-based ionic liquids with a pseudo crown-ether moiety: diastereomeric interaction of a racemic ionic liquid with enantiopure europium complexes
  作者：Yasuhiro Ishida、Daisuke Sasaki、Hiroyuki Miyauchi、Kazuhiko Saigo

  DOI：10.1016/j.tetlet.2004.10.073

  日期：2004.12

  A planar-chiral imidazolium salt with a tris(oxoethylene) bridge was synthesized, and its potential application as a room temperature ionic liquid with a molecular-recognition ability was demonstrated. (C) 2004 Elsevier Ltd. All rights reserved.