3-methyl-1,9-decadiene | 13151-22-9

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 3-methyl-1,9-decadiene
• 英文别名: 1,9-Decadiene, 3-methyl；3-methyldeca-1,9-diene
• CAS: 13151-22-9
• 化学式: C₁₁H₂₀
• 分子量: 152.28
• InChiKey: XIKRZIYEDRNBOH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  11
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1,9-癸二烯 、 碘甲烷 在 正丁基锂 、 potassium tert-butylate 作用下， 生成 3-methyl-1,9-decadiene 、 (Z)-3,10-undecadiene
  参考文献：
  名称：

  1,(ω - 1)-Dienes: solvent controlled unilateral or bilateral metalation

  摘要：

  In hexane, i.e. under heterogeneous conditions, 1,(omega-1)-dienes readily undergo double deprotonation to give bis(allylmetal) intermediates. In tetrahydrofuran at - 75 or - 50-degrees-C, however, only monometalation occurs with dienes having chains of up to 12 carbon atoms. The practical potential of such selective monosubstitution reactions is demonstrated by two novel pheromone syntheses.

  DOI：

  10.1016/0022-328x(91)86133-b

文献信息

• MORET, ETIENNE;DESPONDS, OLIVIER;SCHLOSSER, MANFRED, J. ORGANOMET. CHEM., 409,(1991) N-2, C. 83-91
  作者：MORET, ETIENNE、DESPONDS, OLIVIER、SCHLOSSER, MANFRED

  DOI：——

  日期：——
• 1,(ω - 1)-Dienes: solvent controlled unilateral or bilateral metalation
  作者：Etienne Moret、Olivier Desponds、Manfred Schlosser

  DOI：10.1016/0022-328x(91)86133-b

  日期：1991.5

  In hexane, i.e. under heterogeneous conditions, 1,(omega-1)-dienes readily undergo double deprotonation to give bis(allylmetal) intermediates. In tetrahydrofuran at - 75 or - 50-degrees-C, however, only monometalation occurs with dienes having chains of up to 12 carbon atoms. The practical potential of such selective monosubstitution reactions is demonstrated by two novel pheromone syntheses.