1-methoxy-1-hydroxymethylcyclohexane | 117637-11-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-methoxy-1-hydroxymethylcyclohexane
• 英文别名: Methyl-(1-hydroxymethyl-cyclohexyl)-aether；1-Methoxy-1-hydroxymethyl-cyclohexan；(1-Methoxy-cyclohexyl)-methanol；(1-Methoxycyclohexyl)methanol
• CAS: 117637-11-3
• 化学式: C₈H₁₆O₂
• mdl: MFCD28023713
• 分子量: 144.214
• InChiKey: ZZOCIZAHEZVEQG-UHFFFAOYSA-N

物化性质

• 沸点：
  206.8±8.0 °C(Predicted)
• 密度：
  0.98±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  硫酸 、 1-methoxy-1-hydroxymethylcyclohexane 生成 环己烷基甲醛
  参考文献：
  名称：

  Mousseron; Granger, Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1938, vol. 206, p. 922

  摘要：

  DOI：
• 作为产物：
  描述：

  1-chloro-1-hydroxymethylcyclohexane 在 甲醇 、 sodium methylate 作用下， 生成 1-methoxy-1-hydroxymethylcyclohexane
  参考文献：
  名称：

  Mousseron; Granger, Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1938, vol. 206, p. 922

  摘要：

  DOI：

文献信息

• Metallized mesoporous silicate and method of oxidation with the same
  申请人：Hagiya Koji

  公开号：US20050090688A1

  公开（公告）日：2005-04-28

  A metallized mesoporous silicate which is obtained by (i) reacting (a) either a metal peroxide obtained by the reaction of an aqueous hydrogen peroxide solution with at least one metal or metal compound selected from the group consisting of the following 1) to 4) 1) tungsten 2) molybdenum 3) vanadium 4) compounds comprising 4 a ) any of tungsten, molybdenum, and vanadium and 4 b ) at least one element selected from Groups 13 to 16 (excluding oxygen) or a solution of the metal peroxide with (b) a silicon compound in the presence of an alkylamine or a quaternary ammonium salt and separating the resultant silicate; and a process for producing the metallized mesoporous silicate. Also provided is a method of organic synthesis with the silicate.

  一种金属化介孔硅酸盐，其通过以下步骤获得：(i)在烷基胺或季铵盐存在下，将(a)氢氧化物和至少选择自以下1)至4)中的一种金属或金属化合物反应得到的金属过氧化物1)钨2)钼3)钒4)包含4a)钨、钼和钒和4b)至少选择自第13至16组(不包括氧)的元素的化合物或金属过氧化物的溶液与(b)硅化合物反应，并分离所得的硅酸盐；以及生产金属化介孔硅酸盐的方法。同时提供一种使用该硅酸盐进行有机合成的方法。
• METALLIZED MESOPOROUS SILICATE AND METHOD OF OXIDATION WITH THE SAME
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP1473275A1

  公开（公告）日：2004-11-03

  A metallized mesoporous silicate which is obtained by (i) reacting (a) either a metal peroxide obtained by the reaction of an aqueous hydrogen peroxide solution with at least one metal or metal compound selected from the group consisting of the following 1) to 4) 1) tungsten 2) molybdenum 3) vanadium 4) compounds comprising 4a) any of tungsten, molybdenum, and vanadium and 4b) at least one element selected from Groups 13 to 16 (excluding oxygen) or a solution of the metal peroxide with (b) a silicon compound in the presence of an alkylamine or a quaternary ammonium salt and separating the resultant silicate; and a process for producing the metallized mesoporous silicate. Also provided is a method of organic synthesis with the silicate.

  一种金属化介孔硅酸盐，它是通过(i)使(a)过氧化氢水溶液与至少一种选自以下组别的金属或金属化合物反应而得到的过氧化金属1)至4)1)钨2)钼3)钒4)包括4a)钨、钼和钒中的任何一种和4b)至少一种选自第13至16组的元素(不包括氧)的化合物或过氧化金属的溶液与(b)硅化合物反应而得到的、钼和钒以及 4b) 至少一种选自第 13 组至第 16 组的元素（不包括氧）的化合物，或在烷基胺或季铵盐存在下，过氧化金属与 (b) 硅化合物的溶液，并分离得到的硅酸盐；以及生产金属化介孔硅酸盐的工艺。此外，还提供了一种用硅酸盐进行有机合成的方法。
• Kas'yan, L.I.; Gorb, L.G.; Galafeeva, M.F., Journal of Organic Chemistry USSR (English Translation), 1988, vol. 24, # 2, p. 320 - 326
  作者：Kas'yan, L.I.、Gorb, L.G.、Galafeeva, M.F.、Stepanova, N.V.、Minaev, E.N.、Dryuk, V.G.

  DOI：——

  日期：——
• POLYIMIDE DRY FILM AND APPLICATION THEREOF
  申请人：ETERNAL MATERIALS CO., LTD.

  公开号：US20180002567A1

  公开（公告）日：2018-01-04

  A polyimide dry film including a carrier and a polyimide layer and a method of using the same are provided. The polyimide layer contains (a) a polyimide precursor or soluble polyimide and (b) a solvent. The solvent includes a hydrophilic solvent and a hydrophobic solvent and a weight ratio of the hydrophilic solvent to the hydrophobic solvent is in the range of about 0.05 to about 2. The polyimide dry film of the present invention has water absorbability, is relatively stable even in the presence of water, and has a non-sticky surface. The resulting polyimide has excellent physical properties and can be used in a process in which water or an aqueous solution is involved to form a coverlay with excellent physical properties.
• US7132092B2
  申请人：——

  公开号：US7132092B2

  公开（公告）日：2006-11-07