1,5-bis(4-fluorophenyl)-1,3,5-pentanetrione | 667886-89-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,5-bis(4-fluorophenyl)-1,3,5-pentanetrione
• 英文别名: 1,5-Bis(4-fluorophenyl)pentane-1,3,5-trione
• CAS: 667886-89-7
• 化学式: C₁₇H₁₂F₂O₃
• 分子量: 302.277
• InChiKey: QCEIXTYPISTPKW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  22
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  51.2
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  1,5-bis(4-fluorophenyl)-1,3,5-pentanetrione 在 potassium carbonate 、 三氯氧磷 作用下， 以 N-甲基吡咯烷酮 、 甲苯 为溶剂， 生成 4-(10H-phenothiazin-10-yl)-2,6-bis(4-(p-tolyloxy)phenyl)pyrylium perchlorate
  参考文献：
  名称：

  Functional Aromatic Polyethers: Polymers with Tunable Chromogenic and Fluorogenic Properties

  摘要：

  This paper describes the preparation and chemical modification of pyranone-based aromatic polyethers to yield polymers that contain pyrylium rings, which permit the design of high performance materials with "a la carte" chromogenic and fluorescence behavior. These materials can be used for innovative applications such as luminescent converter (LUCO) materials for hybrid light-emitting diodes (LEDs) or the preparation of selective chromogenic and fluorogenic sensing materials for the preparation of sensing devices. The fluorescence emission maxima of polyether films ranged from 514 to 561 nm, allowing the future development of LUCO-LED devices. Moreover, the interaction of polyether films with different amines leads to color changes and variations in the intensity and emission maxima of fluorescence, which permits the development of amine sensing materials.

  DOI：

  10.1021/ma101106a
• 作为产物：
  描述：

  4-氟苯乙酮 在 sodium 、 sodium hydride 作用下， 以 乙二醇二甲醚 为溶剂， 生成 1,5-bis(4-fluorophenyl)-1,3,5-pentanetrione
  参考文献：
  名称：

  Functional Aromatic Polyethers: Polymers with Tunable Chromogenic and Fluorogenic Properties

  摘要：

  This paper describes the preparation and chemical modification of pyranone-based aromatic polyethers to yield polymers that contain pyrylium rings, which permit the design of high performance materials with "a la carte" chromogenic and fluorescence behavior. These materials can be used for innovative applications such as luminescent converter (LUCO) materials for hybrid light-emitting diodes (LEDs) or the preparation of selective chromogenic and fluorogenic sensing materials for the preparation of sensing devices. The fluorescence emission maxima of polyether films ranged from 514 to 561 nm, allowing the future development of LUCO-LED devices. Moreover, the interaction of polyether films with different amines leads to color changes and variations in the intensity and emission maxima of fluorescence, which permits the development of amine sensing materials.

  DOI：

  10.1021/ma101106a

文献信息

• New Strong Base Synthesis of Symmetrical 1,5-Diaryl-1,3,5-pentanetriones from Acetone and Benzoate Esters
  作者：John D. Knight、Clyde R. Metz、Charles F. Beam、William T. Pennington、Donald G. VanDerveer

  DOI：10.1080/00397910802138488

  日期：2008.6.27

  Lithium hexamethyldisilazide (LiHMDS) was used to condense substituted benzoate esters with acetone to afford symmetrical 1,5-diaryl-1,3,5-pentanetriones that were isolated, characterized (including a representative X-ray crystallographic analysis), and acid cyclized to the respective 2,6-diaryl-4H-pyran-4-ones.
• Functional Aromatic Polyethers: Polymers with Tunable Chromogenic and Fluorogenic Properties
  作者：Ana Gómez-Valdemoro、Ramón Martínez-Máñez、Félix Sancenón、Félix Clemente García、José Miguel García

  DOI：10.1021/ma101106a

  日期：2010.9.14

  This paper describes the preparation and chemical modification of pyranone-based aromatic polyethers to yield polymers that contain pyrylium rings, which permit the design of high performance materials with "a la carte" chromogenic and fluorescence behavior. These materials can be used for innovative applications such as luminescent converter (LUCO) materials for hybrid light-emitting diodes (LEDs) or the preparation of selective chromogenic and fluorogenic sensing materials for the preparation of sensing devices. The fluorescence emission maxima of polyether films ranged from 514 to 561 nm, allowing the future development of LUCO-LED devices. Moreover, the interaction of polyether films with different amines leads to color changes and variations in the intensity and emission maxima of fluorescence, which permits the development of amine sensing materials.