u/l-3-oxiranylmethoxy-6-(1,3-dioxoindan-2-ylidenemethyl)-1-phenyl-1,2,3,4-tetrahydroquinoline | 1035221-52-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: u/l-3-oxiranylmethoxy-6-(1,3-dioxoindan-2-ylidenemethyl)-1-phenyl-1,2,3,4-tetrahydroquinoline
• 英文别名: 2-[[3-(oxiran-2-ylmethoxy)-1-phenyl-3,4-dihydro-2H-quinolin-6-yl]methylidene]indene-1,3-dione
• CAS: 1035221-52-3
• 化学式: C₂₈H₂₃NO₄
• 分子量: 437.495
• InChiKey: COKRDJTXAOZNTL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  33
• 可旋转键数：
  5
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  59.1
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  u/l-3-oxiranylmethoxy-6-(1,3-dioxoindan-2-ylidenemethyl)-1-phenyl-1,2,3,4-tetrahydroquinoline 、 4'4-二巯基二苯硫醚 在 三乙胺 作用下， 以 丁酮 为溶剂， 反应 1.0h， 以52%的产率得到
  参考文献：
  名称：

  Synthesis of Aryl(hetero)methylene-1,3-indandione Based Molecular Glasses

  摘要：

  Novel glass-forming 2-(1-phenyl-1,2,3,4-tetrahydroquinoline-6-ylmethylene)-1,3-indandione derivatives were synthesized and their thermal properties were studied. The results of a preliminary investigation of the photoelectric properties of amorphous films of the title compounds are briefly reported. The ionization potential of these molecular glasses is ca. 5.6eV and the hole drift mobility exceeds 10(-8)cm(2)V(-1)s(-1) at strong electric fields.

  DOI：

  10.1007/s00706-007-0748-5
• 作为产物：
  描述：

  u/l-3-oxiranylmethoxy-1-phenyl-1,2,3,4-tetrahydroquinoline-6-carboxaldehyde 、 1,3-茚满二酮 以 甲醇 为溶剂， 反应 72.0h， 以82%的产率得到u/l-3-oxiranylmethoxy-6-(1,3-dioxoindan-2-ylidenemethyl)-1-phenyl-1,2,3,4-tetrahydroquinoline
  参考文献：
  名称：

  Synthesis of Aryl(hetero)methylene-1,3-indandione Based Molecular Glasses

  摘要：

  Novel glass-forming 2-(1-phenyl-1,2,3,4-tetrahydroquinoline-6-ylmethylene)-1,3-indandione derivatives were synthesized and their thermal properties were studied. The results of a preliminary investigation of the photoelectric properties of amorphous films of the title compounds are briefly reported. The ionization potential of these molecular glasses is ca. 5.6eV and the hole drift mobility exceeds 10(-8)cm(2)V(-1)s(-1) at strong electric fields.

  DOI：

  10.1007/s00706-007-0748-5