7,11,15,28-tetrakis[(acetylaceton-3-yl)methyl]-1,21,23,25-tetrapentyl-2,20:3,19-dimetheno-1H,21H,23H,25H-bis[1,3]dioxocino[5,4-i:5',4'-i']benzo(l,2-d:5,4-d')bis[1,3]benzodioxocin

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 7,11,15,28-tetrakis[(acetylaceton-3-yl)methyl]-1,21,23,25-tetrapentyl-2,20:3,19-dimetheno-1H,21H,23H,25H-bis[1,3]dioxocino[5,4-i:5',4'-i']benzo(l,2-d:5,4-d')bis[1,3]benzodioxocin
• 英文别名: 3-[[12,18,39-Tris(2-acetyl-3-oxobutyl)-25,29,33,37-tetrapentyl-2,4,8,10,14,16,20,22-octaoxanonacyclo[21.15.1.124,38.05,36.07,34.011,32.013,30.017,28.019,26]tetraconta-1(39),5,7(34),11,13(30),17(28),18,23,26,31,35,38(40)-dodecaen-6-yl]methyl]pentane-2,4-dione；3-[[12,18,39-tris(2-acetyl-3-oxobutyl)-25,29,33,37-tetrapentyl-2,4,8,10,14,16,20,22-octaoxanonacyclo[21.15.1.124,38.05,36.07,34.011,32.013,30.017,28.019,26]tetraconta-1(39),5,7(34),11,13(30),17(28),18,23,26,31,35,38(40)-dodecaen-6-yl]methyl]pentane-2,4-dione
• 化学式: C₇₆H₉₆O₁₆
• 分子量: 1265.59
• InChiKey: ZBHSJDQKDDBKCC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.4
• 重原子数：
  92
• 可旋转键数：
  32
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.58
• 拓扑面积：
  210
• 氢给体数：
  0
• 氢受体数：
  16

反应信息

• 作为产物：
  描述：

  乙酰丙酮化钠 、 7,11,15,28-tetrakis(bromomethyl)-1,21,23,25-tetrapentyl-2,20:3,19-dimetheno-1H,21H,23H,25H-bis[1,3]dioxocino[5,4-i:5',4'-i']benzo[1,2-d:5,4-d']bis[1,3]benzodioxocin 以 1,4-二氧六环 为溶剂， 反应 17.0h， 以63%的产率得到7,11,15,28-tetrakis[(acetylaceton-3-yl)methyl]-1,21,23,25-tetrapentyl-2,20:3,19-dimetheno-1H,21H,23H,25H-bis[1,3]dioxocino[5,4-i:5',4'-i']benzo(l,2-d:5,4-d')bis[1,3]benzodioxocin
  参考文献：
  名称：

  A facile synthetic route to convert Tb(iii) complexes of novel tetra-1,3-diketone calix[4]resorcinarene into hydrophilic luminescent colloids

  摘要：

  通过重新沉淀和聚电解质沉积技术，利用Tb(iii)配合物合成了发光亲水性核壳纳米颗粒。

  DOI：

  10.1039/c4nj00637b

文献信息

• A facile synthetic route to convert Tb(<scp>iii</scp>) complexes of novel tetra-1,3-diketone calix[4]resorcinarene into hydrophilic luminescent colloids
  作者：Nataliya A. Shamsutdinova、Sergey N. Podyachev、Svetlana N. Sudakova、Asiya R. Mustafina、Rustem R. Zairov、Vladimir A. Burilov、Irek R. Nizameev、Ildar Kh. Rizvanov、Victor V. Syakaev、Bulat M. Gabidullin、Sergey A. Katsuba、Aidar T. Gubaidullin、Georgy M. Safiullin、Wim Dehaen

  DOI：10.1039/c4nj00637b

  日期：——

  Luminescent hydrophilic core–shell nanoparticles are synthesized through reprecipitation and polyelectrolyte deposition techniques from Tb(iii) complexes.

  通过重新沉淀和聚电解质沉积技术，利用Tb(iii)配合物合成了发光亲水性核壳纳米颗粒。