1,4-二(烯丙氧基)丁烷 | 1471-16-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 1,4-二(烯丙氧基)丁烷
• 英文名称: 1.4-Diallyloxy-butan
• 英文别名: 1,4-Bis(allyloxy)butane；1,4-bis(prop-2-enoxy)butane
• CAS: 1471-16-5
• 化学式: C₁₀H₁₈O₂
• 分子量: 170.252
• InChiKey: DOXPDQHPOSLLIL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  12
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2909199090

反应信息

• 作为反应物：
  描述：

  1,4-二(烯丙氧基)丁烷 在 1,3-bis[(diphenylphosphino)propane]dichloronickel(II) 二异丁基氢化铝 作用下， 以 乙醚 、 甲苯 为溶剂， 反应 2.0h， 以51%的产率得到1,4-丁二醇
  参考文献：
  名称：

  Extremely Facile and Selective Nickel-Catalyzed Allyl Ether Cleavage

  摘要：

  Child's play! Allyl ethers as protecting groups for hydroxyl functions can be removed readily with a combination of DIBAL and catalytic amounts of [NiCl2 (dppp)]. Propene is expelled in this remarkably selective reaction, and a nickel-catalyzed hydroalumination-elimination pathway is proposed [Eq. (a)]. dppp=propane-1,3-diylbis(diphenylphosphane).

  DOI：

  10.1002/(sici)1521-3773(19980504)37:8<1136::aid-anie1136>3.0.co;2-z
• 作为产物：
  描述：

  2-[4-(Thiiran-2-ylmethoxy)butoxymethyl]thiirane 以92%的产率得到
  参考文献：
  名称：

  Gesson J. P., Jacquesy J. C., Rambaud D., Tetrahedron, 49 (1993) N 11, S 2239-2248

  摘要：

  DOI：

文献信息

• SYSTEM FOR PROTECTING GOODS DURING TRANSPORT
  申请人：Stutz Susanne

  公开号：US20120328685A1

  公开（公告）日：2012-12-27

  A system for protecting stored goods in a container ( 10 ), comprises a cage-like structure ( 20 ) formed by at least one pesticide treated net ( 22 ), capable of enclosing the stored goods, wherein the cage like structure ( 20 ), further comprises means for suspending the pesticide treated nets ( 14, 28, 30, 32, 34 ), and means for opening and closing the cage-like structure ( 26 ) on at least one section ( 24 ) of the at least one net ( 22 ). The system is particularly useful for the transport of tobacco, coffee, dried fruits, cocoa, nuts, tea, cereals, vegetables, spices and animals.

  一个用于保护集装箱（10）中存放货物的系统，包括由至少一种经过杀虫剂处理的网（22）形成的类似笼子的结构（20），能够围住存放的货物，其中类似笼子的结构（20）进一步包括用于悬挂经过杀虫剂处理的网（14、28、30、32、34）的手段，以及用于在至少一种网（22）的至少一部分（24）上打开和关闭类似笼子结构（26）的手段。该系统特别适用于烟草、咖啡、干果、可可、坚果、茶叶、谷物、蔬菜、香料和动物的运输。
• The effectiveness of ruthenium(II) complexes and ruthenium trichloride as pre-catalysts in solvent-free isomerization of model alkyl allyl ether
  作者：Magdalena Urbala

  DOI：10.1016/j.apcata.2010.01.010

  日期：2010.4

  The isomerization of readily available allyl ethers catalyzed by soluble ruthenium complexes is an extremely versatile methodology for synthesis of O-1-propenyl systems—attractive monomers in cationic UV-radiation curing technology. From the process development perspective, the effectiveness of selected simple ruthenium catalyst precursors, mainly [RuClH(CO)(PPh3)3], [RuCl2(PPh3)3] and RuCl3·xH2O in

  可溶性钌配合物催化易得的烯丙基醚的异构化是一种非常通用的方法，可用于合成O -1-丙烯基体系-阳离子UV辐射固化技术中的有吸引力的单体。从工艺开发的角度来看，所选的简单钌催化剂前体的有效性，主要是[RuClH（CO）（PPh 3）3 ]，[RuCl 2（PPh 3）3 ]和RuCl 3 · x H 2研究了1,4-双烯丙氧基丁烷的无溶剂异构化过程中的O。基本反应参数之间的关系，例如反应温度，催化剂前体的量，非氢化物配合物（碱或醇）的促进剂，环境气体气氛和反应时间之间的关系可实现将模型双烯丙基醚定量转化为已经提出了其1-丙烯基衍生物（τ100 ％）。特别注意的是使用在合理时间内完成反应所需的较低负载的[Ru]配合物。首次完成了烯丙基氢过氧化物的存在和数量对异构化过程的影响的详细研究。
• DIENE-BASED CARBOXYLATE ANION AND SALT THEREOF, AND POLYMERIZABLE OR CURABLE COMPOSITION THEREOF
  申请人：Kaneko Tomomasa

  公开号：US20130197123A1

  公开（公告）日：2013-08-01

  The claimed invention provides a novel compound not having been studied before, that is, a diene carboxylate anion that contains a specific structure, and a salt thereof. The claimed invention further provides a diene carboxylate anion and a salt thereof, especially a metal salt thereof, which are easily soluble in general organic solvents, reactive diluents, and resins, may be in a liquid state at normal temperature depending on the structure, and have high polymerizability. Polymerization/curing of these produces a resin to which many ionic bonds and a metal are introduced, providing various properties such as hardness, scratch resistance, anti-fingerprint property, gas-barrier property, water vapor barrier property, oxygen absorption property, ultraviolet protection, infrared protection, color development and coloring, high refractive index, adhesion, various catalytic abilities, fluorescence ability and light-emitting ability, optical amplification, dispersibility, and antistatic properties. In addition, the anion and the salt can be used for raw materials for functional fine particles and for metal nanoparticle composites, and also for MOD materials. The claimed invention also provides an advantageous method for producing the diene carboxylate anion and the salt thereof.

  所述发明提供了一种新颖的化合物，此化合物以前未被研究过，即一种含有特定结构的二烯二酸盐阴离子及其盐。所述发明进一步提供了一种二烯二酸盐阴离子及其盐，特别是其金属盐，这些盐在一般有机溶剂、反应性稀释剂和树脂中易溶解，在常温下可能处于液态，具有高聚合性。这些的聚合/固化产生的树脂引入了许多离子键和金属，提供了硬度、抗刮擦性、防指纹性、气体屏障性、阻水汽性、氧气吸收性、紫外线保护、红外线保护、颜色开发和着色、高折射率、粘附性、各种催化能力、荧光能力和发光能力、光学放大、分散性和抗静电性等各种性能。此外，该阴离子和盐可用作功能性细颗粒和金属纳米粒子复合材料的原材料，也可用于MOD材料。所述发明还提供了一种生产二烯二酸盐阴离子及其盐的优势方法。
• [EN] MANUFACTURE OF EPOXYETHYL ETHERS OR GLYCIDYL ETHERS<br/>[FR] FABRICATION D'ÉTHERS D'ÉPOXYÉTHYLE OU D'ÉTHERS DE GLYCIDYLE
  申请人：MOMENTIVE SPECIALTY CHEMICALS RES S A

  公开号：WO2011095293A1

  公开（公告）日：2011-08-11

  Processes are provided for the formation of an epoxyethyl ether or a glycidyl ether, hi one embodiment, a process is provided for the manufacture of an epoxyethyl ether or glycidyl ether including reacting a vinyl ether or an allyl ether with an oxidant in the presence of a water-soluble manganese complex in an aqueous reaction medium, wherein the water-soluble manganese complex comprises an oxidation catalyst, characterized in that the water-soluble manganese complex is a mononuclear complex of the general formula (I): [LMnX3]Y (I), or a binuclear complex of the general formula (II): [LMn(μ-X)3MnL](Y)n (II), wherein Mn is a manganese; L or each L independently is a polydentate ligand, each X independently is a coordinating species and each μ-X independently is a bridging coordinating species, Y is a non-coordinating counter ion, and wherein the epoxidation is carried out at a pH in the range of from 1.0 to 6.0. The invention also relates to epoxyethyl ethers.

  提供了一种形成环氧乙基醚或环氧基醚的工艺。在一个实施例中，提供了一种用于制造环氧乙基醚或环氧基醚的工艺，包括在水溶性锰配合物存在的水相反应介质中，将乙烯醚或烯丙基醚与氧化剂反应，其中水溶性锰配合物包括氧化催化剂，其特征在于水溶性锰配合物是通式(I)的单核配合物：[LMnX3]Y (I)，或通式(II)的双核配合物：[LMn(μ-X)3MnL](Y)n (II)，其中Mn是锰；L或每个L独立地是多齿配体，每个X独立地是一个配位物种，每个μ-X独立地是一个桥联配位物种，Y是一个非配位的反离子，环氧化在pH值为1.0至6.0的范围内进行。该发明还涉及环氧乙基醚。
• Synthesis, characterization, thermal and computational studies of novel tetra–azido compounds as energetic plasticizers
  作者：Mohammad Hadi Baghersad、Azizollah Habibi、Akbar Heydari

  DOI：10.1016/j.molstruc.2016.09.028

  日期：2017.2

  polymer (GAP) has been investigated by viscosity measurements and thermal analysis of the prepolymer–plasticizer mixtures and plasticized binders. The plasticized mixtures were cured by a diisocyanate curing agent and the glass transition temperature and decomposition temperature of the cured polyurethane binders were measured. Thermal analysis of the prepolymer–plasticizer and cured polymer mixtures

  摘要 本文合成并表征了四种叠氮化合物是新型含能增塑剂。核磁共振 (NMR) 和红外 (IR) 光谱、元素分析、差示扫描量热法 (DSC)、热重分析 (TGA) 和差热分析 (DTA) 已用于识别和确定合成增塑剂的性能。通过对预聚物-增塑剂混合物和增塑粘合剂的粘度测量和热分析，研究了增塑剂对缩水甘油基叠氮化物聚合物 (GAP) 的增塑作用。增塑混合物通过二异氰酸酯固化剂固化，并测量固化聚氨酯粘合剂的玻璃化转变温度和分解温度。预聚物-增塑剂和固化聚合物混合物的热分析表明合成的增塑剂与 GAP 粘合剂完全相容并具有非常好的增塑效果。此外，使用波函数 Spartan 软件中提供的热化学 T1 配方获得了每种增塑剂分子的平衡几何形状和形成热。比较经验燃烧热和使用形成热计算的燃烧热表明，T1 配方建议的最佳分子结构与这些分子的真实分子结构高度相似。每个增塑剂分子的平衡几何形状和形成热是使用热化学 T1