1,4-bis(α-D-mannopyranosyloxymethyl)benzene

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,4-bis(α-D-mannopyranosyloxymethyl)benzene
• 英文别名: (2R,3S,4S,5S,6S)-2-(hydroxymethyl)-6-[[4-[[(2S,3S,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxymethyl]phenyl]methoxy]oxane-3,4,5-triol
• 化学式: C₂₀H₃₀O₁₂
• 分子量: 462.451
• InChiKey: ZVEKXKSIMTWXKV-KTTIQVEUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -3.2
• 重原子数：
  32
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  199
• 氢给体数：
  8
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  对苯二甲醇 在 三氟甲磺酸三甲基硅酯 、 sodium methylate 作用下， 以 甲醇 、 二氯甲烷 、 乙腈 为溶剂， 反应 73.0h， 生成 1,4-bis(α-D-mannopyranosyloxymethyl)benzene
  参考文献：
  名称：

  Effect ofp-Substitution of Aryl α-D-Mannosides on Inhibiting Mannose-Sensitive Adhesion ofEscherichia coli – Syntheses and Testing

  摘要：

  DOI：

  10.1002/(sici)1099-0690(199808)1998:8<1669::aid-ejoc1669>3.0.co;2-q

文献信息

• Methods And Systems For Growing Plants Using Silicate-Based Substrates, Cultivation Of Enhanced Photosynthetic Productivity And Photosafening By Utilization Of Exogenous Glycopyranosides For Endogenous Glycopyranosyl-Protein Derivatives, And Formulations, Processes And Systems For The Same
  申请人：Innovation Hammer, LLC

  公开号：US20140331555A1

  公开（公告）日：2014-11-13

  Methods for promoting plant growth based on novel photosafening treatment regimes with glycopyranosides including glycopyranosylglycopyranosides, and aryl-a-D-glycopyranosides, and more specifically, with one or more compounds comprising terminal mannosyl-triose, optionally in the presence of light enhanced by one or more light reflecting and/or refracting members such as silicon-based substrates. Furthermore, chemical synthesis processes for the above compounds are disclosed for general application to plants. Silicate microbeads of the like are distributed over the ground or substrate in which roots of a plant are supported and planted, beneath and around a plant in a manner that light is refracted or reflected toward the phylloplane.

  基于新型光保护处理方案促进植物生长的方法，包括甘露聚糖苷类化合物，如甘露聚糖苷和芳基-a-D-甘露聚糖苷，更具体地，使用含有端基甘露三糖的一个或多个化合物，可选地在存在硅基基底等一个或多个反射和/或折射光的成员的情况下增强光线。此外，还公开了上述化合物的化学合成过程，以供普遍应用于植物。类似的硅酸盐微珠分布在植物的根部支撑和种植的地面或基质上，在植物的下方和周围，使光线以折射或反射的方式朝向叶面。
• Methods and systems for growing plants using silicate-based substrates, cultivation of enhanced photosynthetic productivity and photosafening by utilization of exogenous glycopyranosides for endogenous glycopyranosyl-protein derivatives, and formulations, processes and systems for the same
  申请人：Innovation Hammer, LLC

  公开号：US10010029B2

  公开（公告）日：2018-07-03

  Methods for promoting plant growth based on novel photosafening treatment regimes with glycopyranosides including glycopyranosylglycopyranosides, and aryl-a-D-glycopyranosides, and more specifically, with one or more compounds comprising terminal mannosyl-triose, optionally in the presence of light enhanced by one or more light reflecting and/or refracting members such as silicon-based substrates. Furthermore, chemical synthesis processes for the above compounds are disclosed for general application to plants. Silicate microbeads of the like are distributed over the ground or substrate in which roots of a plant are supported and planted, beneath and around a plant in a manner that light is refracted or reflected toward the phylloplane.

  本发明公开了基于新型光发酵处理机制的促进植物生长的方法，该机制使用的糖吡喃糖苷包括糖吡喃糖基糖吡喃糖苷和芳基-a-D-糖吡喃糖基糖吡喃糖苷，更具体地说，使用一种或多种包含末端甘露三糖的化合物，可选择在由一种或多种光反射和/或折射部件（如硅基底物）增强的光存在下进行。此外，还公开了上述化合物的化学合成工艺，可普遍应用于植物。类似的硅酸盐微珠分布在支撑和种植植物根系的地面或基质上，在植物的下方和周围，光线被折射或反射到植物体上。
• Methods and systems for growing plants using silicate-based substrates, cultivation of enhanced photosynthetic productivity and photosafening by utilization of exogenous glycopyranosides for endogenous glycopyranosyl-protein derivatives, and formulations, process and systems for the same
  申请人：Innovation Hammer, LLC

  公开号：US11147219B2

  公开（公告）日：2021-10-19

  A container for growing a plant. The container includes at least one container wall having a surface, the container wall having one or more light reflective and/or refractive members attached thereto. The one or more light reflective and/or refractive members may include one or more silicate microbeads that are buffered to neutrality. The container may contain a plant, and the one or more light reflective and/or refractive members may be positioned in the container to redistribute light toward the plant, and may be present in an amount effective to cause harmful light saturation of the plant. To safen the plant from such harmful light, the container also may contain one or more glycopyranosidic compounds, such as one or more alkyl-α-D-mannosides.

  一种用于种植植物的容器。容器包括至少一个具有表面的容器壁，容器壁上附有一个或多个光反射和/或折射部件。一个或多个光反射和/或折射部件可包括一个或多个缓冲至中性的硅酸盐微珠。容器中可装有植物，一个或多个光反射和/或折射部件可设置在容器中，以向植物重新分配光线，其存在量可有效导致植物的有害光饱和。为了使植物免受有害光的伤害，容器中还可含有一种或多种糖苷化合物，如一种或多种烷基-α-D-甘露糖苷。
• METHOD FOR GROWING PLANTS USING SILICATE MICROBEADS AND PHOTOSAFENING BY UTILIZATION OF EXOGENOUS GLYCOPYRANOSIDES
  申请人：Innovation Hammer LLC

  公开号：EP2782990B1

  公开（公告）日：2020-10-07
• Effect ofp-Substitution of Aryl α-D-Mannosides on Inhibiting Mannose-Sensitive Adhesion ofEscherichia coli – Syntheses and Testing
  作者：Thisbe K. Lindhorst、Sven Kötter、Jiří Kubisch、Ulrike Krallmann-Wenzel、Stefan Ehlers、Vladimír Křen

  DOI：10.1002/(sici)1099-0690(199808)1998:8<1669::aid-ejoc1669>3.0.co;2-q

  日期：1998.8