1-[3-(1-hydroxycyclohexyl)propyl]cyclohexanol | 101083-14-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-[3-(1-hydroxycyclohexyl)propyl]cyclohexanol
• 英文别名: 1,1'-propanediyl-bis-cyclohexanol；1,1'-Propandiyl-bis-cyclohexanol；1.3-Bis-(1-hydroxy-cyclohexyl)-propan；1,1'-(Propane-1,3-diyl)di(cyclohexan-1-ol)；1-[3-(1-hydroxycyclohexyl)propyl]cyclohexan-1-ol
• CAS: 101083-14-1
• 化学式: C₁₅H₂₈O₂
• 分子量: 240.386
• InChiKey: CQDOMVXWDDTXMO-UHFFFAOYSA-N

物化性质

• 熔点：
  120 °C
• 沸点：
  111-115 °C(Press: 14 Torr)
• 密度：
  1.027±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  环己酮 在 乙醚 、 乙醇 、 钯 、 锌 作用下， 生成 1-[3-(1-hydroxycyclohexyl)propyl]cyclohexanol
  参考文献：
  名称：

  Zeile; Meyer, Chemische Berichte, 1942, vol. 75, p. 356,360

  摘要：

  DOI：

文献信息

• PREPARATION AND DEHYDRATION OF DI-(1-HYDROXYCYCLOALKYL)-ALKANES
  作者：A. S. Bailey、D. G. M. Diaper、M. V. H. Schwemin

  DOI：10.1139/v61-142

  日期：1961.5.1

  not available

  不可用
• [EN] PROCESS FOR THE PREPARATION OF AN ALLY ALKYL EHTER BY CATALYTIC ALLYATION<br/>[FR] PROCÉDÉ DE PRÉPARATION D'UN ALLYL ARYL ÉTHER PAR ALLYLATION CATALYTIQUE
  申请人：RESOLUTION RES NEDERLAND BV

  公开号：WO2010086139A1

  公开（公告）日：2010-08-05

  The invention provides a process for the preparation of an allyl alkyl ether comprising the allylation of an aliphatic hydroxyl containing compound with an allyl source in the presence of a catalyst, wherein the catalyst is a transition metal complex with a phosphine ligand, wherein the allylation is carried out in the presence of an acid in an amount of at least 0.1 mol% calculated on the aliphatic hydroxyl containing compound. This invention further provides a process for the preparation of epoxy resins wherein as intermediate use is made of the allyl alkyl ethers prepared by the process of the invention.

  该发明提供了一种制备烯丙基烷基醚的过程，包括将含有脂肪族羟基的化合物与烯丙基源在催化剂存在下进行烯丙基化反应，其中催化剂是含有膦配体的过渡金属配合物，其中烯丙基化反应在存在酸的情况下进行，酸的用量至少为脂肪族羟基含有化合物的0.1 mol％。该发明还提供了一种环氧树脂的制备方法，其中利用了通过该发明的过程制备的烯丙基烷基醚作为中间体。
• 3-Chloropropyl phenyl ether as a 1,3-dilithiopropane source: sequential reaction with carbonyl compounds
  作者：Francisco Foubelo、Miguel Yus

  DOI：10.1016/s0040-4039(98)02360-0

  日期：1999.1

  The reaction of 3-chloropropyl phenyl ether (1) with lithium powder and a catalytic amount of DTBB (2.5% molar) in THF at −78°C followed by successive treatment with a carbonyl compound [E1 = ButCHO, Me2CO, (CH2)5CO] at −78 to 20°C and, after 1 h at this temperature, a second one [E2 = ButCHO, PhCHO, MeCOPrn, (CH2)5CO] at −78°C leads, after hydrolysis with water, to the formation of the corresponding

  3-氯丙基苯基醚的反应（1）与锂粉末和DTBB（2.5％摩尔）在THF中的-78℃的催化量，接着与羰基化合物连续处理[E 1 =卜吨CHO中，Me 2 CO，（CH 2）5 CO]在-78至20℃，并在此温度下ë1个小时，第二个[后2 =卜吨CHO，苯甲醛，MeCOPr ñ，（CH 2）5 CO]在-在用水水解后，78℃导致形成相应的1，5-二醇（2），其中已经引入了两个不同的亲电子片段。
• Radiation-Curable Aqueous Polyurethane Dispersions
  申请人：Heischkel Yvonne

  公开号：US20080145563A1

  公开（公告）日：2008-06-19

  The present invention relates to UV-curable polyurethane dispersions, to a process for preparing them, and to their use.

  本发明涉及紫外光固化聚氨酯分散液，以及制备它们的过程和它们的使用。
• PROCESS FOR PRODUCING EPOXY COMPOUND, EPOXY RESIN COMPOSITION AND USE THEREOF, ULTRAVIOLET-CURABLE CAN COATING COMPOSITION, AND PROCESS FOR PRODUCING COATED METAL CAN
  申请人：DAICEL CHEMICAL INDUSTRIES, Ltd.

  公开号：EP1389615A1

  公开（公告）日：2004-02-18

  The invention I provides a method of producing an alicyclic epoxy compound having a specific structure, which comprises epoxidizing an alicyclic olefin compound having a specific structure by using an aliphatic percarboxylic acid having low water content. The alicyclic epoxy compound is useful for use in coatings, inks, adhesives, sealants, encapsulants, stabilizers or the like. The invention II provides an epoxy resin composition containing the alicyclic epoxy compound as a main component, and a photosemiconductor device comprising a photosemiconductor element encapsulated with the epoxy resin composition. The epoxy resin composition can be cured by heating, thereby obtaining a cured product having excellent moisture and heat resistance and transparency. The invention III provides: an ultraviolet rays-curable can-coating composition containing the alicyclic epoxy compound as a main component, which can be cured by ultraviolet irradiation, and can form a coating film having excellent film performances such as processability, adhesion, hardness and scratch resistance, particularly film appearance and retort resistance; and a process of producing a coated metal can using the composition.

  本发明一提供了一种生产具有特定结构的脂环族环氧化合物的方法，该方法包括使用含水量低的脂肪族过羧酸对具有特定结构的脂环族烯烃化合物进行环氧化。脂环族环氧化合物可用于涂料、油墨、粘合剂、密封剂、封装剂、稳定剂等。 本发明二提供了一种含有脂环族环氧化合物作为主要成分的环氧树脂组合物，以及一种光电半导体器件，该器件包括用环氧树脂组合物封装的光电半导体元件。环氧树脂组合物可以通过加热固化，从而获得具有优异的耐湿性、耐热性和透明度的固化产品。 本发明III提供了：一种紫外线固化罐涂层组合物，该组合物以脂环族环氧化合物为主要成分，可通过紫外线照射固化，并可形成具有优异涂膜性能（如加工性、附着力、硬度和抗划伤性）的涂膜，特别是涂膜外观和耐蒸煮性；以及一种使用该组合物生产涂层金属罐的工艺。