5-butoxy-pent-1-ene | 54004-24-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 5-butoxy-pent-1-ene
• 英文别名: Pent-4-enyl-n-butyl-aether；5-Butoxy-1-pentene；5-butoxypent-1-ene
• CAS: 54004-24-9
• 化学式: C₉H₁₈O
• mdl: MFCD11553691
• 分子量: 142.241
• InChiKey: CPBCAWGRKAFJKP-UHFFFAOYSA-N

物化性质

• 沸点：
  167.0±19.0 °C(Predicted)
• 密度：
  0.796±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  10
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.777
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  频哪醇 、 B-氯-1,2-苯二酚硼烷 、 5-butoxy-pent-1-ene 在 N-甲基二环己基胺 、 (JessePhos)₂PdCl₂ 、 lithium trifluoromethanesulfonate 作用下， 反应 24.0h， 以74%的产率得到
  参考文献：
  名称：

  由未官能化烯烃直接合成烯基硼酸酯：硼基-赫克反应

  摘要：

  我们报告了使用亲电子硼试剂进行硼基-赫克反应的第一个例子。这种钯催化的过程允许使用市售的儿茶酚氯硼烷 (catBCl) 将末端烯烃转化为反式烯基硼酸酯。原位酯交换可以快速获得各种硼酸酯、酰胺和其他烯基硼加合物。

  DOI：

  10.1021/jacs.6b02914
• 作为产物：
  描述：

  正溴丁烷 、 4-戊烯-1-醇 在 sodium hydride 作用下， 以 四氢呋喃 、 mineral oil 为溶剂， 反应 3.0h， 以70%的产率得到5-butoxy-pent-1-ene
  参考文献：
  名称：

  由未官能化烯烃直接合成烯基硼酸酯：硼基-赫克反应

  摘要：

  我们报告了使用亲电子硼试剂进行硼基-赫克反应的第一个例子。这种钯催化的过程允许使用市售的儿茶酚氯硼烷 (catBCl) 将末端烯烃转化为反式烯基硼酸酯。原位酯交换可以快速获得各种硼酸酯、酰胺和其他烯基硼加合物。

  DOI：

  10.1021/jacs.6b02914

文献信息

• A method for the preparation of optically active 2-aryl alkyl aldehydes and formation of 2-aryl-alkanoic acids therefrom
  申请人：MEDICE Chem.-Pharm. Fabrik Pütter GmbH & Co. KG

  公开号：EP0668259A1

  公开（公告）日：1995-08-23

  The present process is directed to preparing optically active 2-aryl alkyl aldehydes by various processes through the use of an optically active amine, (-)-2'-amino-3-phenyl propane. The aldehyde formed can then be oxidized to produce the corresponding acid.

  本发明的目的是通过使用具有光学活性的胺--(-)-2'-氨基-3-苯基丙烷，以各种工艺制备具有光学活性的 2-芳基烷基醛。然后，形成的醛可以被氧化，生成相应的酸。
• Polar group-containing olefin copolymer, process for preparing the same, thermoplastic resin composition contaning the copolymer, and uses thereof
  申请人：MITSUI CHEMICALS, INC.

  公开号：EP1186619A2

  公开（公告）日：2002-03-13

  The present invention is intended to provide a polar group-containing olefin copolymer having excellent adhesion properties to metals or polar resins and excellent compatibility therewith, a process for preparing the copolymer, a thermoplastic resin composition containing the copolymer, and uses thereof. The polar group-containing olefin copolymer comprises a constituent unit derived from an α-olefin of 2 to 20 carbon atoms, and a constituent unit derived from a straight-chain, branched or cyclic polar group-containing monomer having at the end a polar group such as a hydroxyl group or an epoxy group and/or a constituent unit derived from a macromonomer having at the end a polymer segment obtained by anionic polymerization, ring-opening polymerization or polycondensation. The polar group-containing olefin copolymer can be prepared by polymerizing the α-olefin with the polar group-containing monomer and/or the macromonomer in the presence of a metallocene catalyst. The polar group-containing olefin copolymer and the thermoplastic resin composition containing the copolymer are used for films, sheets, modifiers, building/civil engineering materials, automobile exterior trim, electric/electronic parts, coating bases, compatibilizing agents, etc.

  本发明旨在提供一种对金属或极性树脂具有极佳粘附性和相容性的含极性基团的烯烃共聚物、制备该共聚物的工艺、含有该共聚物的热塑性树脂组合物及其用途。含极性基团的烯烃共聚物包括一个由 2 至 20 个碳原子的 α-烯烃衍生的组成单元和一个由直链、支链或环状含极性基团单体衍生的组成单元，直链、支链或环状含极性基团单体的末端具有极性基团，如羟基或环氧基，和/或一个由大单体衍生的组成单元，大单体的末端具有通过阴离子聚合、开环聚合或缩聚反应获得的聚合物段。含极性基团的烯烃共聚物可通过在茂金属催化剂存在下使α-烯烃与含极性基团的单体和/或大单体聚合来制备。含极性基团的烯烃共聚物和含有该共聚物的热塑性树脂组合物可用于薄膜、板材、改性剂、建筑/土木工程材料、汽车外饰、电气/电子零件、涂层基料、相容剂等。
• Polar group-containing olefin copolymer, process for preparing the same, thermoplastic resin composition containing the copolymer, and uses thereof
  申请人：——

  公开号：US20020156207A1

  公开（公告）日：2002-10-24

  The present invention is intended to provide a polar group-containing olefin copolymer having excellent adhesion properties to metals or polar resins and excellent compatibility therewith, a process for preparing the copolymer, a thermoplastic resin composition containing the copolymer, and uses thereof. The polar group-containing olefin copolymer comprises a constituent unit derived from an &agr;-olefin of 2 to 20 carbon atoms, and a constituent unit derived from a straight-chain, branched or cyclic polar group-containing monomer having at the end a polar group such as a hydroxyl group or an epoxy group and/or a constituent unit derived from a macromonomer having at the end a polymer segment obtained by anionic polymerization, ring-opening polymerization or polycondensation. The polar group-containing olefin copolymer can be prepared by polymerizing the &agr;-olefin with the polar group-containing monomer and/or the macromonomer in the presence of a metallocene catalyst. The polar group-containing olefin copolymer and the thermoplastic resin composition containing the copolymer are used for films, sheets, modifiers, building/civil engineering materials, automobile exterior trim, electric/electronic parts, coating bases, compatibilizing agents, etc.

  本发明旨在提供一种对金属或极性树脂具有极佳粘附性能和极佳相容性的含极性基团的烯烃共聚物、制备该共聚物的工艺、含有该共聚物的热塑性树脂组合物及其用途。含极性基团的烯烃共聚物包括一个由 2 至 20 个碳原子的&agr;-烯烃衍生的组成单元，以及一个由直链、支链或环状含极性基团单体衍生的组成单元，该单体末端具有极性基团，如羟基或环氧基，和/或一个由大单体衍生的组成单元，该大单体末端具有通过阴离子聚合、开环聚合或缩聚反应获得的聚合物段。含极性基团的烯烃共聚物可通过在茂金属催化剂存在下，将&agr;-烯烃与含极性基团的单体和/或大单体进行聚合来制备。含极性基团的烯烃共聚物和含有该共聚物的热塑性树脂组合物可用于薄膜、板材、改性剂、建筑/土木工程材料、汽车外饰、电气/电子零件、涂层基料、相容剂等。
• Polar group-containing olefin copolymer, process for preparing the same, thermoplastic resin composition containing the copolymer and uses thereof
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1734061B1

  公开（公告）日：2010-04-07
• THERMOSETTING RESIN COMPOSITION AND METHOD FOR MANUFACTURING SAME
  申请人：SAKAI CHEMICAL INDUSTRY CO., LTD.

  公开号：US20210395459A1

  公开（公告）日：2021-12-23

  The present invention provides a resin composition which has excellent handleability and which provides a cured product having excellent toughness and heat resistance. The present invention relates to a thermosetting resin composition including an allyl compound (A) containing at least two or more allyl groups and one or more benzene rings in a molecule, a maleimide compound (B) containing at least two or more maleimide groups in a molecule, a thiol compound (C) containing at least two or more thiol groups in a molecule, and a cyclic compound (D) containing at least two or more hydroxyl groups in a molecule.