(3Z,6Z,9Z,12Z)-octadeca-3,6,9,12-tetraene | 327064-38-0

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: (3Z,6Z,9Z,12Z)-octadeca-3,6,9,12-tetraene
• CAS: 327064-38-0
• 化学式: C₁₈H₃₀
• 分子量: 246.436
• InChiKey: WQVZOSJSTFXESJ-JLKQYBQHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7
• 重原子数：
  18
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  all-(Z)-3,6,9,12-pentadecatetraenal 在 lithium aluminium tetrahydride 、 三乙胺 作用下， 以 乙醚 、 二氯甲烷 为溶剂， 反应 7.0h， 生成 (3Z,6Z,9Z,12Z)-octadeca-3,6,9,12-tetraene
  参考文献：
  名称：

  A practical synthesis of (all-Z)-eicosa-3,6,9,12-tetraene, a pheromone component isolated from emerald moths

  摘要：

  A short and practical synthesis of (all-Z)-eicosa-3,6,9,12-tetraene, a component of the emerald moth pheromone is reported. Two different methodologies are used both starting with the natural polyunsaturated fatty acid (all-Z)-eicosa-5,8,11,14,17-pentaenoic acid (EPA). The methodology can be used for the syntheses of a homologous series of analogues of the pheromone that may be practical for analytical purposes of similar natural products. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.12.039

文献信息

• A nine carbon homologating system for skip-conjugated polyenes
  作者：Hussein H. Mustafa、Mark S. Baird、Juma’a R. Al Dulayymi、Viacheslav V. Tverezovskiy

  DOI：10.1016/j.chemphyslip.2014.04.005

  日期：2014.10

  Ozonolysis of Z,Z,Z-cylonona-1,4,7-triene leads to a 1,9-difunctionalised Z,Z-3,6-nonadiene which is readily converted into a range of polyunsaturated pheromones and fatty acids. (C) 2014 Elsevier Ireland Ltd. All rights reserved.