1,3-dioxa-5,5,6,6,7,7-hexafluorocyclooctane | 36301-46-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,3-dioxa-5,5,6,6,7,7-hexafluorocyclooctane
• 英文别名: 5,5,6,6,7,7-Hexafluoro-1,3-dioxa-cyclooctan；5,5,6,6,7,7-Hexafluoro-1,3-dioxocane
• CAS: 36301-46-9
• 化学式: C₆H₆F₆O₂
• 分子量: 224.103
• InChiKey: CMXKJHAIDVVKGY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  三聚甲醛 生成 1,3-dioxa-5,5,6,6,7,7-hexafluorocyclooctane
  参考文献：
  名称：

  GOLDWASSER, J. M.;ADOLPH, H. G.;EBNER, C. L.

  摘要：

  DOI：

文献信息

• Preparation of 1,3-dioxa-5,5,6,6,7,7-hexafluorocyclooctane
  申请人：The United States of America as represented by the Secretary of the Navy

  公开号：US04593110A1

  公开（公告）日：1986-06-03

  One mole of 2,2,3,3,4,4-hexafluoropentane-1,5-diol is reacted with one mole f formaldehyde in the presence of an excess of trifluoromethanesulfonic acid to produce 1,3-dioxa-5,5,6,6,7,7-hexafluorocyclooctane.

  一摩尔的2,2,3,3,4,4-六氟戊烷-1,5-二醇在过量三氟甲磺酸存在下与一摩尔甲醛反应，生成1,3-二氧杂-5,5,6,6,7,7-六氟环辛烷。
• Fluorinated ether compound, fluorinated ether composition, coating liquid, article and its production method
  申请人：AGC Inc.

  公开号：US11155508B2

  公开（公告）日：2021-10-26

  To provide a fluorinated ether compound capable of forming a surface layer excellent in initial water/oil repellency, fingerprint stain removability, abrasion resistance and light resistance; a fluorinated ether composition and a coating liquid containing the fluorinated ether compound; an article having a surface layer excellent in initial water/oil repellency, fingerprint stain removability, abrasion resistance and light resistance and a method for producing it. A fluorinated ether compound having a poly(oxyperfluoroalkylene) chain having a unit (α) which is an oxyperfluoroalkylene unit having 5 or 6 carbon atoms, and a unit (β) which is an oxyperfluoroalkylene unit having at most 4 carbon atoms, and having at least one of a hydrolysable silyl group and a silanol group on at least one terminal of the poly(oxyperfluoroalkylene) chain via a linking group.

  提供一种能够形成初始拒水/拒油性、指纹污渍去除性、耐磨性和耐光性优异的表面层的含氟醚化合物；一种含氟醚组合物和一种含有该含氟醚化合物的涂布液；一种具有初始拒水/拒油性、指纹污渍去除性、耐磨性和耐光性优异的表面层的物品及其生产方法。一种氟化醚化合物，具有聚（全氟烷基）链，其单元（α）是具有 5 或 6 个碳原子的全氟烷基单元，单元（β）是最多具有 4 个碳原子的全氟烷基单元，并通过连接基团在聚（全氟烷基）链的至少一个末端上具有可水解硅基和硅烷醇基中的至少一个。
• Patel Nimesh R., Chen Jianguo, Zhang Yuan F., Kirchmeier Robert L., Shree+, Inorg. Chem, 33 (1994) N 24, S 5463-5470
  作者：Patel Nimesh R., Chen Jianguo, Zhang Yuan F., Kirchmeier Robert L., Shree+

  DOI：——

  日期：——
• GOLDWASSER, J. M.;ADOLPH, H. G.;EBNER, C. L.
  作者：GOLDWASSER, J. M.、ADOLPH, H. G.、EBNER, C. L.

  DOI：——

  日期：——
• FLUORINATED ETHER COMPOUND, FLUORINATED ETHER COMPOSITION, COATING LIQUID, ARTICLE AND ITS PRODUCTION METHOD
  申请人：AGC Inc.

  公开号：US20200071251A1

  公开（公告）日：2020-03-05

  To provide a fluorinated ether compound capable of forming a surface layer excellent in initial water/oil repellency, fingerprint stain removability, abrasion resistance and light resistance; a fluorinated ether composition and a coating liquid containing the fluorinated ether compound; an article having a surface layer excellent in initial water/oil repellency, fingerprint stain removability, abrasion resistance and light resistance and a method for producing it. A fluorinated ether compound having a poly(oxyperfluoroalkylene) chain having a unit (α) which is an oxyperfluoroalkylene unit having 5 or 6 carbon atoms, and a unit (β) which is an oxyperfluoroalkylene unit having at most 4 carbon atoms, and having at least one of a hydrolysable silyl group and a silanol group on at least one terminal of the poly(oxyperfluoroalkylene) chain via a linking group.