申请人:Voskoboynikov Z. Alexander
公开号:US20070135595A1
公开(公告)日:2007-06-14
A metallocene compound is represented by the formula (1):
wherein: M is a Group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom, preferably a Group 4 transition metal atom selected from titanium, zirconium or hafnium; E is a substituted or unsubstituted monocyclic or polycyclic arenyl ligand pi-bonded to M; A is a substituted or unsubstituted polycyclic arenyl ligand that is pi-bonded to M and has a different ring structure than the E ligand; at least one of the A and E ligands includes at least one halogen substituent directly bonded to an sp
2
carbon at a bondable ring position; Y is a bridging group containing at least one Group 13, 14, 15, or 16 element and any single position of the ring structure of A and to any single position of the ring structure of E; and y is zero or 1, indicating the absence (y=0) or presence (y=1) of Y; and each X is a univalent anionic ligand, or two X are joined and bound to the metal atom to form a metallocycle ring, or two X are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand; provided that when E is an unsubstituted cyclopentadienyl ligand, either y is one or A is not 2-bromofluorenyl or 2,7-dibromofluorenyl.
一个茂金属化合物的化学式如下(1):其中:M是3、4、5或6族过渡金属原子,或镧系金属原子,或锕系金属原子,最好是从钛、锆或铪中选择的4族过渡金属原子;E是与M形成π键的取代或未取代的单环或多环芳基配体;A是与M形成π键且具有不同环结构于E配体的取代或未取代的多环芳基配体;A和E中至少一个包括至少一个卤素取代基,直接连接到可成键环位置的sp2碳上;Y是一个含有至少一个13、14、15或16族元素的桥联基,连接到A和E的环结构的任意单位置;y为0或1,表示Y的存在(y=0)或不存在(y=1);每个X是一个一价阴离子配体,或两个X连接并与金属原子结合形成一个茂环,或两个X连接形成螯合配体、二烯配体或烷基亚甲基配体;但当E是未取代的环戊二烯基配体时,y为1或A不是2-溴萘基或2,7-二溴萘基。