2,9-二-2-萘-4,7-二苯基-1,10-菲咯啉 | 1174006-43-9

• 物质功能分类: 化学试剂 - 有机试剂 - 多环化合物
• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 中文名称: 2,9-二-2-萘-4,7-二苯基-1,10-菲咯啉
• 英文名称: NBphen
• 英文别名: (2,9-bis(naphthalen-2-yl)-4,7-diphenyl-1,10-phenanthroline)；2,9-di(naphthalen-2-yl)-4,7-diphenyl-1,10-phenanthroline；2,9-Bis(naphthalen-2-YL)-4,7-diphenyl-1,10-phenanthroline；2,9-dinaphthalen-2-yl-4,7-diphenyl-1,10-phenanthroline
• CAS: 1174006-43-9
• 化学式: C₄₄H₂₈N₂
• 分子量: 584.72
• InChiKey: XESMNQMWRSEIET-UHFFFAOYSA-N

物化性质

• 密度：
  1.234
• 熔点：
  TGA: >340 °C (0.5% weight loss)

计算性质

• 辛醇/水分配系数(LogP)：
  11.5
• 重原子数：
  46
• 可旋转键数：
  4
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 危险性防范说明：
  P261,P264,P270,P271,P280,P301+P312,P302+P352,P304+P340,P305+P351+P338,P330,P332+P313,P337+P313,P362,P403+P233,P405,P501
• 危险性描述：
  H302,H315,H319,H335

反应信息

• 作为产物：
  描述：

  在 manganese(IV) oxide 作用下， 以 二氯甲烷 为溶剂， 反应 10.0h， 以5.39 g的产率得到2,9-二-2-萘-4,7-二苯基-1,10-菲咯啉
  参考文献：
  名称：

  一种OLED电子传输材料NBphen的制备方法

  摘要：

  本发明公开了一种OLED电子传输材料NBphen的制备方法。该制备方法包括：(1)在保护气体和第一有机溶剂的存在下，将2‑溴萘和金属锂进行接触反应，得到2‑锂萘有机溶液；(2)在保护气体存在下，将Bphen有机溶液和2‑锂萘有机溶液进行接触反应，得到反应混合物；(3)将反应混合物与水进行水解反应，得到油水混合物；(4)萃取油水混合物的水层中的有机相，然后将有机相与氧化剂进行接触反应，得到所述NBphen。本发明的方法无需冷却到‑78℃，反应更加方便且节约能源；反应的安全性高，便于进行大批量制备。

  公开号：

  CN110183441B

文献信息

• [EN] BISIMIDAZOLODIAZOCINES<br/>[FR] BIS-IMIDAZOLO-DIAZOCINES
  申请人：IDEMITSU KOSAN CO

  公开号：WO2016125110A1

  公开（公告）日：2016-08-11

  The present invention relates to an organic electronic device, preferably an OLED, comprising a Bisimidazolodiazocine of formula (I) charge transport layer, a charge/exciton blocker layer, or an emitting layer comprising the Bisimidazolodiazocine; an apparatus selected from the group consisting of stationary visual display units; mobile visual display units; illumination units; keyboards; items of clothing; furniture; wallpaper, comprising the inventive organic electronic device, or the inventive charge transport layer, the charge/exciton blocker layer, or the emitting layer; the use of the Bisimidazolodiazocines for electrophotographic photoreceptors, photoelectric converters, organic solar cells, switching elements, organic light emitting field effect transistors, image sensors, dye lasers and electroluminescent devices; a process for the production of the Bisimidazolodiazocines and specific Bisimidazolodiazocines..

  本发明涉及一种有机电子器件，优选为OLED，包括式(I)的双咪唑二唑啉的电荷传输层，电荷/激子阻挡层，或包括双咪唑二唑啉的发射层；选自固定视觉显示单元组、移动视觉显示单元、照明单元、键盘、服装、家具、墙纸的装置，包括所述创新的有机电子器件，或创新的电荷传输层、电荷/激子阻挡层或发射层；双咪唑二唑啉用于电子照相感光鼓、光电转换器、有机太阳能电池、开关元件、有机发光场效应晶体管、图像传感器、染料激光器和电致发光器件的用途；一种生产双咪唑二唑啉和特定双咪唑二唑啉的方法。
• Light-Emitting Element, Lighting Device, Light-Emitting Device, and Electronic Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20160343968A1

  公开（公告）日：2016-11-24

  A light-emitting element includes a first electrode; a first light-emitting layer over the first electrode, containing a first phosphorescent compound and a first host material; a second light-emitting layer over the first light-emitting layer, containing a second phosphorescent compound and a second host material; a third light-emitting layer over the second light-emitting layer, containing a third phosphorescent compound and a third host material; and a second electrode over the third light-emitting layer. Between peaks of emission spectra of the first, second, and third phosphorescent compounds, the peak of the emission spectrum of the second phosphorescent compound is on the longest wavelength side and that of the emission spectrum of the third phosphorescent compound is on the shortest wavelength side. The third host material has higher triplet excitation energy than the first host material and the second host material.

  一个发光元件包括：第一电极；设置在第一电极上的第一发光层，包含第一磷光化合物和第一主体材料；设置在第一发光层上的第二发光层，包含第二磷光化合物和第二主体材料；设置在第二发光层上的第三发光层，包含第三磷光化合物和第三主体材料；以及设置在第三发光层上的第二电极。在第一、第二和第三磷光化合物的发射光谱的峰值之间，第二磷光化合物的发射光谱峰值位于最长波长侧，而第三磷光化合物的发射光谱峰值位于最短波长侧。第三主体材料具有高于第一主体材料和第二主体材料的三重态激发能。
• [EN] SUBSTITUTED CARBAZOLE DERIVATIVES AND USE THEREOF IN ORGANIC ELECTRONICS<br/>[FR] DÉRIVÉS DE CARBAZOLE SUBSTITUÉS ET LEUR UTILISATION EN ÉLECTRONIQUE ORGANIQUE
  申请人：BASF SE

  公开号：WO2011125020A1

  公开（公告）日：2011-10-13

  An organic light-emitting diode, organic solar cell or switching element comprising at least one substituted carbazole derivative of the general formula (I), (II) or (III) in which X is NR4, O, S or PR4; Y is NR5, O, S or PR5; where at least one of the symbols X and Y is NR4 or NR5; R1 and R3 are each independently substituted or unsubstituted C1-C20-alkyl, substituted or unsubstituted C6-C30-aryl, substituted or unsubstituted heteroaryl having 5 to 30 ring atoms or a substituent with donor or acceptor action selected from the group consisting of C1-C20-alkoxy, C6-C30-aryloxy, C1-C20-alkylthio, C6-C30-arylthio, SiR6R7R8, halogen radicals, halogenated C1-C20-alkyl radicals, carbonyl (-CO(R6)), carbonylthio (- C = O (SR6)), carbonyloxy (- C = O(OR6)), oxycarbonyl (- OC = O(R6)), thiocarbonyl (- SC = O(R6)), amino (-NR6R7), OH, pseudohalogen radicals, amido (- C = O (NR6)), -NR6C = O (R7), phosphonate (- P(O) (OR6)2), phosphate (-OP(O) (OR6)2), phosphine (-PR6R7), phosphine oxide (-P(0)R62), sulfate (-OS(0)2OR6), sulfoxide (-S(O)R6), sulfonate (-S(O)2OR6), sulfonyl (-S(O)2R6), sulfonamide (-S(O)2NR6R7), N02, boronic esters (-OB(OR6)2), imino (-C = NR6R7), borane radicals, stannane radicals, hydrazine radicals, hydrazone radicals, oxime radicals, nitroso groups, diazo groups, vinyl groups, sulfoximines, alanes, germanes, boroximes and borazines;

  一种有机发光二极管、有机太阳能电池或开关元件，包括至少一种取代咔唑衍生物，其通用公式为(I)、(II)或(III)，其中X是NR4、O、S或PR4；Y是NR5、O、S或PR5；其中符号X和Y中至少一个是NR4或NR5；R1和R3各自独立地是取代或未取代的C1-C20-烷基，取代或未取代的C6-C30-芳基，取代或未取代的含有5到30个环原子的杂芳基，或选自C1-C20-烷氧基、C6-C30-芳氧基、C1-C20-烷硫基、C6-C30-芳硫基、SiR6R7R8、卤素自由基、卤代C1-C20-烷基自由基、羰基(-CO(R6))、硫羰基(-C=S(R6))、羰氧基(-C=O(OR6))、氧羰基(-OC=O(R6))、硫羰基(-SC=O(R6))、氨基(-NR6R7)、OH、拟卤素自由基、酰胺(-C=O(NR6))、-NR6C=O(R7)、磷酰基(-P(O)(OR6)2)、磷酸酯(-OP(O)(OR6)2)、膦(-PR6R7)、氧化膦(-P(O)R62)、硫酸酯(-OS(O)2OR6)、亚磺酰基(-S(O)R6)、磺酸酯(-S(O)2OR6)、磺酰基(-S(O)2R6)、磺酰胺(-S(O)2NR6R7)、N02、硼酸酯(-OB(OR6)2)、亚胺(-C=NR6R7)、硼烷自由基、锡烷自由基、肼自由基、腙自由基、肟自由基、亚硝基团、重氮基团、乙烯基团、亚磺酰亚胺、铝烷、锗烷、硼氧基和硼唑的取代基。
• MATERIAL FOR HOLE-TRANSPORT LAYER, MATERIAL FOR HOLE-INJECTION LAYER, ORGANIC COMPOUND, LIGHT-EMITTING DEVICE, LIGHT-EMITTING APPARATUS, ELECTRONIC DEVICE, AND LIGHTING DEVICE
  申请人：SEMICONDUCTOR ENERGY LABORATORY CO., LTD.

  公开号：US20210005814A1

  公开（公告）日：2021-01-07

  A material for a hole-transport layer includes a monoamine compound. The first aromatic group, the second aromatic group, and the third aromatic group are bonded to the nitrogen atom of the monoamine compound. The first and second aromatic groups each independently include 1 to 3 benzene rings. One or both of the first and second aromatic groups have one or more hydrocarbon groups each having 1 to 12 carbon atoms each forming a bond only by the sp 3 hybrid orbitals. The total number of the carbon atoms in the hydrocarbon group in the first or second aromatic group is 6 or more. The total number of the carbon atoms in all of the hydrocarbon groups in the first and second aromatic groups is 8 or more. The third aromatic group is a substituted or unsubstituted monocyclic condensed ring or a substituted or unsubstituted bicyclic or tricyclic condensed ring.

  一种用于空穴传输层的材料包括单胺化合物。第一个芳基团、第二个芳基团和第三个芳基团均连接到单胺化合物的氮原子上。第一个和第二个芳基团每个独立地包括1到3个苯环。第一个和第二个芳基团中的一个或两个具有一个或多个各自具有1到12个碳原子的烃基团，这些烃基团仅通过sp3杂化轨道形成键。第一或第二芳基团中的烃基团中的碳原子总数为6个或更多。第一和第二芳基团中的所有烃基团中的碳原子总数为8个或更多。第三个芳基团是取代的或未取代的单环稠环，或是取代的或未取代的双环或三环稠环。
• ARYLAMINE COMPOUND, HOLE-TRANSPORT LAYER MATERIAL, HOLE-INJECTION LAYER MATERIAL, LIGHT-EMITTING DEVICE, LIGHT-EMITTING APPARATUS, ELECTRONIC APPARATUS, AND LIGHTING DEVICE
  申请人：SEMICONDUCTOR ENERGY LABORATORY CO., LTD.

  公开号：US20210317069A1

  公开（公告）日：2021-10-14

  To provide a novel arylamine compound with a low refractive index. The provided arylamine compound includes at least one aromatic group. The aromatic group includes a first benzene ring, a second benzene ring, a third benzene ring, and at least three alkyl groups. The first benzene ring, the second benzene ring, and the third benzene ring are directly bonded in this order. The first benzene ring is bonded to nitrogen of amine. The first benzene ring may further include a substituted or unsubstituted phenyl group. The second benzene ring or the third benzene ring may further include an alkylated phenyl group. Each of first positions and third positions of two or more of the first to third benzene rings is independently bonded to another benzene ring, a benzene ring of the alkylated phenyl group, any of the at least three alkyl groups, or the nitrogen of the amine.

  提供一种低折射率的新型芳胺化合物。所提供的芳胺化合物包括至少一个芳香族基团。该芳香族基团包括第一苯环、第二苯环、第三苯环和至少三个烷基团。第一苯环、第二苯环和第三苯环按此顺序直接键合。第一苯环与胺的氮原子键合。第一苯环可进一步包括取代的或未取代的苯基团。第二苯环或第三苯环可进一步包括烷基化的苯基团。第一至第三苯环中的两个或多个第一位置和第三位置独立地键合到另一个苯环、烷基化苯基团的苯环、至少三个烷基团中的任一个或胺的氮原子。