1-propylsulfanyl-2-hexanol | 1159011-19-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-propylsulfanyl-2-hexanol
• 英文别名: 1-propylthiohexan-2-ol；1-propylsulfanylhexan-2-ol
• CAS: 1159011-19-4
• 化学式: C₉H₂₀OS
• 分子量: 176.323
• InChiKey: PEHSPHIZOABTMF-UHFFFAOYSA-N

物化性质

• 沸点：
  99-101 °C(Press: 1 Torr)
• 密度：
  0.9334 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  11
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  45.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  环己亚胺 、 聚合甲醛 、 1-propylsulfanyl-2-hexanol 以 苯 为溶剂， 反应 5.0h， 以74%的产率得到1-(1-propylsulfanylmethylpentyloxymethyl)azepane
  参考文献：
  名称：

  Synthesis of 1-propylsulfanylhexane aminomethoxy derivatives

  摘要：

  Synthesis was performed of new aminomethoxy derivatives of 1-propylsulfanyl hexane by Mannich condensation of 1-propanethiol, secondary amines, and formaldehyde. The structure of compounds synthesized was established by elemental analysis, mass spectrometry, IR and H-1 NMR spectroscopy. Some compounds obtained were tested as antimicrobial additives to lubricating oils, and also as antiseptics against bacteria and fungi. It was established that these compounds are more efficient antimicrobial substances than the preparations currently used.

  DOI：

  10.1134/s1070428010020053
• 作为产物：
  描述：

  丙烷-1-硫醇 、 1-溴己烷-2-醇 在 sodium hydroxide 作用下， 以 水 为溶剂， 反应 4.0h， 以67%的产率得到1-propylsulfanyl-2-hexanol
  参考文献：
  名称：

  Synthesis of 1-propylsulfanylhexane aminomethoxy derivatives

  摘要：

  Synthesis was performed of new aminomethoxy derivatives of 1-propylsulfanyl hexane by Mannich condensation of 1-propanethiol, secondary amines, and formaldehyde. The structure of compounds synthesized was established by elemental analysis, mass spectrometry, IR and H-1 NMR spectroscopy. Some compounds obtained were tested as antimicrobial additives to lubricating oils, and also as antiseptics against bacteria and fungi. It was established that these compounds are more efficient antimicrobial substances than the preparations currently used.

  DOI：

  10.1134/s1070428010020053

文献信息

• Synthesis of 1-propylsulfanylhexane aminomethoxy derivatives
  作者：E. G. Mamedbeili、I. A. Dzhafarov、K. A. Kochetkov、Kh. I. Gasanov、S. T. Alieva

  DOI：10.1134/s1070428010020053

  日期：2010.2

  Synthesis was performed of new aminomethoxy derivatives of 1-propylsulfanyl hexane by Mannich condensation of 1-propanethiol, secondary amines, and formaldehyde. The structure of compounds synthesized was established by elemental analysis, mass spectrometry, IR and H-1 NMR spectroscopy. Some compounds obtained were tested as antimicrobial additives to lubricating oils, and also as antiseptics against bacteria and fungi. It was established that these compounds are more efficient antimicrobial substances than the preparations currently used.