7,14-Bis[4-dodecylphenyl]acenaphtho[1,2-k]-fluoranthene | 352532-72-0

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物
• 英文名称: 7,14-Bis[4-dodecylphenyl]acenaphtho[1,2-k]-fluoranthene
• 英文别名: 3,15-Bis(4-dodecylphenyl)heptacyclo[15.7.1.15,9.02,16.04,14.021,25.013,26]hexacosa-1(24),2(16),3,5,7,9(26),10,12,14,17,19,21(25),22-tridecaene
• CAS: 352532-72-0
• 化学式: C₆₂H₇₀
• 分子量: 815.238
• InChiKey: QNBCXUXAJZGMGD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  22.8
• 重原子数：
  62
• 可旋转键数：
  24
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.39
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  7,14-Bis[4-dodecylphenyl]acenaphtho[1,2-k]-fluoranthene 在 三氯化铁 作用下， 以 硝基甲烷 、 二氯甲烷 为溶剂， 反应 0.17h， 以87%的产率得到4,4'7,7'-Tetrakis(4-dodecylphenyl)diacenaphtho[1,2-k:1',2',k']diindeno[1,2,3-cd:1',2',3'-lm]perylene
  参考文献：
  名称：

  Novel Perylene Chromophores Obtained by a Facile Oxidative Cyclodehydrogenation Route

  摘要：

  New perylene chromophores, phenyl-substituted diindeno[1.2.3-cd: 1',2',3'-lm]perylenes 5 a,b and 4.4'.7,7'-tetraphenyldiacenaphtho[1.2-k:1',2',k']diindeno[1,2,3-cd :1'.2'.3'-me]perylenes 22 a,b, have been synthesized from substituted fluoranthene derivatives 3a,b and 4a,b by means of a surprisingly simple oxidative cyclodehydrogenation reaction. The resulting chromophores, when substituted with alkyl chains at the periphery, show good solubility in organic solvents, and a full characterization of the novel red, green, and blue dyes by field-desorption mass spectrometry, UV/Vis and H-1 and C-13 NMR spectroscopy becomes possible.

  DOI：

  10.1002/1521-3765(20010518)7:10<2197::aid-chem2197>3.0.co;2-g
• 作为产物：
  描述：

  1,3-bis(4-dodecylphenyl)-propan-2-one 在 氢氧化钾 作用下， 以 乙醇 、 甲苯 、 xylene 为溶剂， 反应 16.08h， 生成 7,14-Bis[4-dodecylphenyl]acenaphtho[1,2-k]-fluoranthene
  参考文献：
  名称：

  Novel Perylene Chromophores Obtained by a Facile Oxidative Cyclodehydrogenation Route

  摘要：

  New perylene chromophores, phenyl-substituted diindeno[1.2.3-cd: 1',2',3'-lm]perylenes 5 a,b and 4.4'.7,7'-tetraphenyldiacenaphtho[1.2-k:1',2',k']diindeno[1,2,3-cd :1'.2'.3'-me]perylenes 22 a,b, have been synthesized from substituted fluoranthene derivatives 3a,b and 4a,b by means of a surprisingly simple oxidative cyclodehydrogenation reaction. The resulting chromophores, when substituted with alkyl chains at the periphery, show good solubility in organic solvents, and a full characterization of the novel red, green, and blue dyes by field-desorption mass spectrometry, UV/Vis and H-1 and C-13 NMR spectroscopy becomes possible.

  DOI：

  10.1002/1521-3765(20010518)7:10<2197::aid-chem2197>3.0.co;2-g