1-ethoxy-1-methoxy-butane | 127248-85-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-ethoxy-1-methoxy-butane
• 英文别名: Butyraldehyd-methylaethylacetal；1-Aethoxy-1-methoxy-butan；1-Ethoxy-1-methoxybutane
• CAS: 127248-85-5
• 化学式: C₇H₁₆O₂
• 分子量: 132.203
• InChiKey: MHLUISRWIURWAQ-UHFFFAOYSA-N

物化性质

• 沸点：
  132.8±8.0 °C(Predicted)
• 密度：
  0.841±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  9
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  甲醇 、 1-ethoxy-1-methoxy-butane 在 盐酸 作用下， 生成 1,1-二甲氧基丁烷 、 乙醇
  参考文献：
  名称：

  Claus, P.; Berndt, T.; Scherzer, K., Zeitschrift fur Physikalische Chemie (Leipzig), 1989, vol. 270, # 6, p. 1205 - 1216

  摘要：

  DOI：
• 作为产物：
  描述：

  1-chloro-1-methoxy-butane 、 sodium ethanolate 生成 1-ethoxy-1-methoxy-butane
  参考文献：
  名称：

  Straus; Weber, Justus Liebigs Annalen der Chemie, 1932, vol. 498, p. 101,107

  摘要：

  DOI：

文献信息

• Methods for Producing Fluorine-Containing Hydroxyaldehyde, Fluorine-Containing Propanediol, and Fluorine-Containing Alcohol Monomer
  申请人：Central Glass Company, Limited

  公开号：US20150361026A1

  公开（公告）日：2015-12-17

  As shown by the following reaction formula, disclosed is a fluorine-containing hydroxyaldehyde production method, including the step of obtaining a fluorine-containing hydroxyaldehyde represented by the general formula (1) by reacting a fluorine-containing ketone represented by the general formula (4) and an aldehyde represented by the general formula (5) in the presence of an organic base selected from a heterocyclic compound which contains a nitrogen atom in its ring or a tertiary amine. By this production method, it is possible to obtain the fluorine-containing hydroxyaldehyde in a high yield. Furthermore, it is possible to easily obtain in high yields a fluorine-containing propanediol, which is a derivative of this fluorine-containing hydroxyaldehyde, and a fluorine-containing alcohol monomer by using the same.

  根据以下反应方程式，揭示了一种含氟羟基醛的生产方法，包括通过在选择的含氟酮（通式（4）表示）和醛（通式（5）表示）在含有从含有氮原子的杂环化合物或三级胺中选择的有机碱的情况下反应，获得由通式（1）表示的含氟羟基醛的步骤。通过这种生产方法，可以高产率地获得含氟羟基醛。此外，可以通过使用相同方法轻松高产率地获得含氟丙二醇（这是这种含氟羟基醛的衍生物）和含氟醇单体。
• Polymerizable Fluoromonomer, Fluoropolymer, Resist Material, and Method of Pattern Formation
  申请人：Komoriya Haruhiko

  公开号：US20110244188A1

  公开（公告）日：2011-10-06

  Disclosed is a polymerizable fluoromonomer represented by the following general formula (1). In the formula, R 1 represents a hydrogen atom, methyl group, fluorine atom, or trifluoromethyl group. n is an integer of 0 or 1, and m is that of from 1 to (3+n). R 2 and R 3 each independently represents a hydrogen atom or a protective group. A resist containing a fluoropolymer obtained by polymerizing or copolymerizing the monomer is suitable for use in microfabrication by immersion exposure or by a double patterning process based on immersion exposure.

  本发明涉及一种可聚合的含氟单体，其通式（1）如下所示。其中，R1代表氢原子、甲基基团、氟原子或三氟甲基基团。n为0或1的整数，m为1至（3+n）的整数。R2和R3各自独立地代表氢原子或保护基团。通过聚合或共聚合该单体得到的含氟聚合物的抗蚀剂适用于浸润曝光或基于浸润曝光的双重图案化工艺的微细加工。
• Fluorine-Containing Compound, Fluorine-Containing Polymer Compound, Resist Composition, Top Coat Composition And Pattern Formation Method
  申请人：Mori Kazunori

  公开号：US20120077126A1

  公开（公告）日：2012-03-29

  A fluorine-containing polymer of the present invention contains a repeating unit (a) of the general formula (2) and has a mass-average molecular weight of 1,000 to 1,000,000. This polymer is suitably used in a resist composition for pattern formation by high energy ray radiation of 300 nm or less wavelength or electron beam radiation or a top coat composition for liquid immersion lithography and is characterized as having high water repellency, notably high receding contact angle. In the formula, R 1 represents a polymerizable double bond-containing group; R 2 represents a fluorine atom or a fluorine-containing alkyl group; R 8 represents a substituted or unsubstituted alkyl group or the like; and W 1 represents a single bond, a substituted or unsubstituted methylene group or the like.

  本发明的含氟聚合物包含通式（2）的重复单元（a），其具有1,000至1,000,000的质量平均分子量。该聚合物适用于抗高能辐射（波长小于或等于300nm的高能射线辐射或电子束辐射）的光阻组合物，或用于液体浸没光刻的面涂层组合物，并具有高水珠性，尤其是高后退接触角。在公式中，R1表示可聚合的双键含有的基团；R2表示氟原子或含氟烷基；R8表示取代或未取代的烷基或类似物；W1表示单键，取代或未取代的亚甲基或类似物。
• Top Coat Composition
  申请人：Komoriya Haruhiko

  公开号：US20110245395A1

  公开（公告）日：2011-10-06

  Disclosed is a top coat composition for photoresist, which is characterized by containing a fluorinated polymer having a repeating unit represented by general formula (5). In the formula, R 1 represents a hydrogen atom, a methyl group, a fluorine atom, or a trifluoromethyl group; n represents 0 or 1; m represents an integer of 1 to (3+n); and R 2 or R 3 represents a hydrogen atom or a protecting group. The top coat composition has a proper degree of solubility in a developing solution.

  公开了一种用于光刻胶的面漆组合物，其特征在于包含有一个由通式（5）表示的重复单元的氟化聚合物。在该式中，R1表示氢原子、甲基、氟原子或三氟甲基；n表示0或1；m表示1至（3+n）的整数；而R2或R3表示氢原子或保护基。该面漆组合物在显影液中具有适当的溶解度。
• POLYVINYL ETHER COMPOUND AND LUBRICATING OIL
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0644175A1

  公开（公告）日：1995-03-22

  A polyvinyl ether compound (including one having a specified terminal group) having constitutional units each represented by general formula (I) wherein R₃, R₄ and R₅ represent each H or alkyl; R⁶ represents alkylen; R⁷ represents alkyl; and k represents 0 to 10; and a process for producing the same by polymerizing a vinyl ether monomer in the presence of a specified initiator comprising a combination of a Brönsted acid, Lewis acid or organometallic compound with an adduct of a carboxylic acid with water, alcohol, phenol, acetal or vinyl ether. The compound is useful as lubricating oil, etc. A process for producing an ether compound by the reaction of an acetal or ketal represented by general formula (II) with hydrogen in the presence of an acidic substance and a solid catalyst having a hydrogenating ability to convert the group R³³O- or R³⁴O- into a hydrogen atom.

  一种聚乙烯醇醚化合物（包括具有特定末端基团的聚乙烯醇醚化合物），其每个构 成单元均由通式(I)表示，其中 R₃、R₄ 和 R₅ 分别代表 H 或烷基；R⁶ 代表亚烷基；R⁷ 代表烷基；以及 k 代表 0 至 10；以及一种生产该化合物的工艺，其方法是在指定的引发剂存在下，使乙烯基醚单体聚合，该引发剂包括布氏酸、路易斯酸或有机金属化合物与羧酸与水、醇、苯酚、缩醛或乙烯基醚的加合物的组合。这种化合物可用作润滑油等。在酸性物质和具有氢化能力的固体催化剂存在下，通式 (II) 所代表的缩醛或缩酮与氢发生反应，将基团 R³³O- 或 R³⁴O- 转化为氢原子，从而生产醚化合物的工艺。