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三乙基乙二醇二丁基醚 | 63512-36-7

中文名称
三乙基乙二醇二丁基醚
中文别名
三乙二醇醚二丁酯
英文名称
α-butyl-ω-butoxymono-tris-oxyethylene
英文别名
triethylene glycol dibutyl ether;5,8,11,14-tetraoxaoctadecane;triethyleneglycol dibutylether;1-[2-[2-(2-butoxyethoxy)ethoxy]ethoxy]butane
三乙基乙二醇二丁基醚化学式
CAS
63512-36-7
化学式
C14H30O4
mdl
——
分子量
262.39
InChiKey
KTSVVTQTKRGWGU-UHFFFAOYSA-N
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

物化性质

  • 沸点:
    125-127°C/2mmHg
  • 密度:
    0.9609 (rough estimate)
  • 稳定性/保质期:
    遵照规定使用和储存,则不会发生分解。

计算性质

  • 辛醇/水分配系数(LogP):
    1.8
  • 重原子数:
    18
  • 可旋转键数:
    15
  • 环数:
    0.0
  • sp3杂化的碳原子比例:
    1.0
  • 拓扑面积:
    36.9
  • 氢给体数:
    0
  • 氢受体数:
    4

ADMET

毒理性
  • 副作用
神经毒素 - 急性溶剂综合征
Neurotoxin - Acute solvent syndrome
来源:Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

SDS

SDS:bdd5550e8841b45d3e30b59436ce09bb
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Name: Triethyleneglycol dibutylether 97% Material Safety Data Sheet
Synonym: None
CAS: 63512-36-7
Section 1 - Chemical Product MSDS Name:Triethyleneglycol dibutylether 97% Material Safety Data Sheet
Synonym:None

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
63512-36-7 Triethyleneglycol dibutylether 97 unlisted
Hazard Symbols: XI
Risk Phrases: 19 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
May form explosive peroxides. Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. May form explosive peroxides.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 63512-36-7: Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: clear, colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 125-127 deg C @ 2 mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C14H30O4
Molecular Weight: 262.39

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Under normal storage conditions, peroxidizable compounds can form and accumulate peroxides which may explode when subjected to heat or shock. This material is most hazardous when peroxide levels are concentrated by distillation or evaporation.
Conditions to Avoid:
Prolonged exposure to air.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 63512-36-7 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Triethyleneglycol dibutylether - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 19 May form explosive peroxides.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 63512-36-7: No information available.
Canada
CAS# 63512-36-7 is listed on Canada's NDSL List.
CAS# 63512-36-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 63512-36-7 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

上下游信息

  • 上游原料
    中文名称 英文名称 CAS号 化学式 分子量

反应信息

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文献信息

  • Process for the preparation of cyclic esters and method for purification of the same
    申请人:——
    公开号:US20030191326A1
    公开(公告)日:2003-10-09
    The present invention provides a process for production of a cyclic ester by depolymerization of an aliphatic polyester. In the process, a mixture containing the aliphatic polyester and a specific polyalkylene glycol ether, which has a boiling point of 230-450° C. and a molecular weight of 150-450, is heated under normal or reduced pressure to a temperature at which depolymerization of the aliphatic polyester takes place. Then, a substantially homogeneous solution phase, consisting of the melt phase of the aliphatic polyester and the liquid phase of the polyalkylene glycol ether, is formed. Heating of the solution phase is continued to form the cyclic ester by depolymerization and distil out the cyclic ester together with the polyalkylene glycol ether, and then the cyclic ester is recovered from the distillate. The present invention also provides a process for purification of a crude cyclic ester by use of the specific polyalkylene glycol ether described above.
    本发明提供了一种通过脂肪族聚酯的降解来生产环酯的方法。在该过程中,将含有脂肪族聚酯和具有沸点在230-450°C和分子量在150-450之间的特定聚烷基乙二醇醚的混合物,在常压或减压下加热至脂肪族聚酯发生降解的温度。然后,形成由脂肪族聚酯的熔融相和聚烷基乙二醇醚的液相组成的基本均相溶液相。继续加热溶液相以通过降解形成环酯并与聚烷基乙二醇醚一起蒸馏出环酯,然后从馏出物中回收环酯。本发明还提供了一种利用上述特定聚烷基乙二醇醚对粗环酯进行纯化的方法。
  • [EN] METHOD FOR PREPARING ALIZARIN DERIVATIVE COMPOUND, NOVEL ALIZARIN DERIVATIVE COMPOUND, SURFACE MODIFICATION METHOD, PHOTOELECTRIC CONVERSION FILM, PHOTOELECTRIC CONVERSION ELEMENT, AND ELECTROPHOTOGRAPHIC PHOTORECEPTOR<br/>[FR] PROCÉDÉ DE PRÉPARATION D'UN COMPOSÉ DÉRIVÉ D'ALIZARINE, NOUVEAU COMPOSÉ DÉRIVÉ D'ALIZARINE, PROCÉDÉ DE MODIFICATION DE SURFACE, FILM DE CONVERSION PHOTOÉLECTRIQUE, ÉLÉMENT DE CONVERSION PHOTOÉLECTRIQUE ET PHOTORÉCEPTEUR ÉLECTROPHOTOGRAPHIQUE
    申请人:FUJIFILM CORP
    公开号:WO2011071130A1
    公开(公告)日:2011-06-16
    The present invention provides a novel alizarin derivative compound and a simplified and low cost method for preparing an alizarin derivative compound including: obtaining a compound represented by Formula (2) using a compound represented by Formula (3); and obtaining an alizarin derivative compound represented by Formula (1) using the compound represented by Formula (2); in Formulae (1) to (3), R1 represents a hydrogen atom or a substituent; n represents an integer of 1 to 3, L represents a specific alkyl group; Q represents an atomic group needed to form an aromatic ring or a heteroaromatic ring with adjacent carbon atoms; and P represents an atomic group which includes an atom(s) selected from a hydrogen atom, a carbon atom, an oxygen atom, a sulfur atom, a silicon atom and a boron atom, and which is needed to form a ring structure group with adjacent two oxygen atoms and two carbon atoms; Formula (1) Formula (2) Formula (3).
    本发明提供了一种新型茜素衍生物化合物以及一种简化且低成本的制备茜素衍生物化合物的方法,包括:使用表示为Formula (3)的化合物获得表示为Formula (2)的化合物;并使用表示为Formula (2)的化合物获得表示为Formula (1)的茜素衍生物化合物;在Formulae (1)到(3)中,R1代表氢原子或取代基;n代表1至3的整数,L代表特定的烷基团;Q代表需要与相邻碳原子形成芳香环或杂芳环的原子团;P代表包括从氢原子、碳原子、氧原子、硫原子、硅原子和硼原子中选择的原子的原子团,并且需要与相邻的两个氧原子和两个碳原子形成环结构团;Formula (1) Formula (2) Formula (3)。
  • METHOD FOR PRODUCING CARBONATE COMPOUND
    申请人:Asahi Glass Company, Limited
    公开号:US20150284314A1
    公开(公告)日:2015-10-08
    The present invention relates to a production process capable of selectively producing various kinds of carbonate compounds without restraint in high yields without using toxic compounds such as phosgene and crown ethers, without producing corrosive gases such as hydrogen chloride as a by-product, and without necessity of removing the chloroform as a by-product by distillation, and to a method for producing a carbonate compound, containing reacting compound (1) with a compound having an OH group in the presence of a metal salt and 0.2 to 4.0 mol of compound (2) per mol of the metal salt to obtain a carbonate compound, in which m is an integer of 1-10, Q is an alkylene group having 1 to 4 carbon atoms, etc, and R 10 and R 11 are alkyl groups having 1 to 5 carbon atoms, etc.
    本发明涉及一种生产过程,能够在高产率下有选择地生产各种碳酸盐化合物,而不使用像光气和冠醚这样的有毒化合物,也不产生像氯化氢这样的腐蚀性气体作为副产品,也不需要通过蒸馏去除氯仿作为副产品,以及一种制备碳酸盐化合物的方法,其中包括在金属盐和化合物(1)的存在下,将化合物(1)与具有羟基的化合物反应,每摩尔金属盐添加0.2到4.0摩尔的化合物(2),以获得碳酸盐化合物,其中m是1-10的整数,Q是具有1到4个碳原子的烷基基团,R10和R11是具有1到5个碳原子的烷基基团等。
  • METHOD FOR PRODUCING ESTER-FUNCTIONAL SILANES
    申请人:Daiss Juergen Oliver
    公开号:US20130060057A1
    公开(公告)日:2013-03-07
    Silanes containing an ester group are produced in high yield and purity by reacting a salt of a carboxylic acid with a silane containing a carboxylate substitutable leaving group following by distilling the product mixture to obtain a distillate containing the ester group containing silane product, wherein a solvent having a boiling point higher than the product is contained in the product mixture during at least a terminal portion of the distillation.
    含酯基的硅烷通过将羧酸盐与含有可替代羧酸基团的硅烷反应,然后蒸馏产物混合物以获得含有酯基的硅烷产物的蒸馏物,从而以高收率和高纯度生产,在至少蒸馏过程的末端期间,产物混合物中含有一种沸点高于产物的溶剂。
  • Method for the Production of Optically Active 3-Alkyl Carboxylic Acids and the Intermediate Products Thereof
    申请人:Sorger Klas
    公开号:US20070225519A1
    公开(公告)日:2007-09-27
    An enantioselective method for producing optically active 3-alkyl carboxylic acids comprises transforming an optically active secondary alcohol into an optically active, activated compound by introducing a leaving group; reacting the activated compound with a malonic acid derivative to obtain an optically active, alkylated malonic acid compound, the reaction taking place exclusively in ether and/or carboxylic acid ester solvents and one or more aprotic polar solvents or alcohols as a cosolvent in a maximum proportion of 30 volume percent of total solvent, wherein the added cosolvent is not hexamethyl phosphoric acid triamide; the malonic acid compound is hydrolyzed if necessary to obtain the corresponding acid; and the corresponding acid is decarboxylated.
    一种产生光学活性3-烷基羧酸的对映选择性方法包括将光学活性的次级醇转化为光学活性的活化化合物,方法是引入一个离去基;将活化的化合物与丙二酸衍生物反应,以获得光学活性的烷基化丙二酸化合物,反应仅在醚和/或羧酸酯溶剂中进行,并且添加一种或多种无水极性溶剂或醇作为共溶剂,最大比例为总溶剂的30体积百分比,其中添加的共溶剂不是六甲基膦酰胺;必要时,对丙二酸化合物进行水解以获得相应的酸;并且通过脱羧反应获得相应的酸。
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