methyl 6-hydroxy-2,2-bis(4-methoxyphenyl)-2H-naphtho[1,2-b]pyran-5-carboxylate | 169682-11-5

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 黄酮类化合物
• 英文名称: methyl 6-hydroxy-2,2-bis(4-methoxyphenyl)-2H-naphtho[1,2-b]pyran-5-carboxylate
• 英文别名: 2,2-bis(4-methoxyphenyl)-5-methoxycarbonyl-6-hydroxy-[2H]-naphtho[1,2-b]pyran；2,2-bis(4-methoxyphenyl)-5-methoxycarbonyl-6-hydroxy-2H-naphtho[1,2-b]pyran；2,2-Bis(4-methoxyphenyl)-5-(methoxycarbonyl)-6-hydroxy-[2H]-naphtho[1,2-b]pyran；methyl 6-hydroxy-2,2-bis(4-methoxyphenyl)benzo[h]chromene-5-carboxylate
• CAS: 169682-11-5
• 化学式: C₂₉H₂₄O₆
• 分子量: 468.506
• InChiKey: IRUSWXGCWKNVPY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  35
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  74.2
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  苯基氯化镁 、 methyl 6-hydroxy-2,2-bis(4-methoxyphenyl)-2H-naphtho[1,2-b]pyran-5-carboxylate 在 盐酸 作用下， 以 四氢呋喃 、 水 为溶剂， 反应 1.0h， 生成 2,2-bis(4-methoxyphenyl)-5-diphenylmethylol-6-hydroxy-2H-naphtho[1,2-b]pyran
  参考文献：
  名称：

  NOVEL SUBSTITUTED NAPHTHOPYRANS

  摘要：

  公开号：

  EP0994871B1
• 作为产物：
  描述：

  1,1-双(4-甲氧基苯基)-2-丙炔-1-醇 、 1,4-二羟基-2-萘甲酸甲酯 在 aluminum oxide 作用下， 以 甲苯 为溶剂， 反应 1.5h， 以76%的产率得到methyl 6-hydroxy-2,2-bis(4-methoxyphenyl)-2H-naphtho[1,2-b]pyran-5-carboxylate
  参考文献：
  名称：

  Gabbutt, Christopher D.; Hepworth, John D.; Heron, B. Mark, Heterocycles, 2004, vol. 63, # 3, p. 567 - 582

  摘要：

  DOI：

文献信息

• Optimizing the photochromic performance of naphthopyrans in a rigid host matrix using poly(dimethylsiloxane) conjugation
  作者：Francesca Ercole、Nino Malic、Thomas P. Davis、Richard A. Evans

  DOI：10.1039/b904345d

  日期：——

  A series of methoxy substituted 2,2-diaryl-2H-naphthopyran photochromic dyes were assembled incorporating hydroxy functionality to allow their subsequent attachment to flexible poly(dimethylsiloxane) oligomers. The photochromic performance of the generated PDMS–naphthopyran conjugates was studied in a thermoset host matrix and compared to non-conjugated, electronically equivalent control dyes. Both coloration and decoloration speeds were found to be greatly improved with critical T1/2 decoloration times reduced by 42–80%. The extent of solution-like performance provided by PDMS conjugation in the rigid host was examined with reference to the fade performance of control dyes in solution, and found to range from 20 to 90%. These measures are believed to be influenced by the electronic nature and steric interactions of the photochromic dyes.

  一系列甲氧基取代的2,2-二芳基-2H-萘并吡喃光致变色染料被合成并通过引入羟基功能性，以便随后将其固定到柔性的聚二甲基硅氧烷低聚物中。研究了生成的PDMS-萘并吡喃共轭物在热固性基质中的光致变色性能，并与非共轭、电子等效的对照染料进行了比较。发现着色和褪色的速度都大幅提高，关键的褪色半衰期T1/2减少了42-80%。PDMS共轭在刚性基质中提供的类似溶液性能的程度，参考了对照染料在溶液中的褪色性能进行了考察，发现范围从20%到90%不等。这些测量结果被认为受到光致变色染料的电子性质和立体相互作用的影响。
• Photochromic Polymer and Composition Comprising Photochromic Polymer
  申请人：Evans Richard Alexander

  公开号：US20110147681A1

  公开（公告）日：2011-06-23

  A photochromic polymer comprising at least one siloxane oligomer and at least two photochromic groups covalently linked to one or both terminuses of the siloxane oligomer and compositions containing photochromic siloxane polymers with narrow polydispersity. The photochromic polymer enhances switching speed in rigid host polymers.

  一种光致变色聚合物，包括至少一个硅氧烷寡聚物和至少两个光致变色基团，与硅氧烷寡聚物的一个或两个端点共价连接，并且含有具有狭窄聚分散度的光致变色硅氧烷聚合物的组合物。该光致变色聚合物可以提高刚性主体聚合物的切换速度。
• Photochromic materials
  申请人：Wang Feng

  公开号：US20060022176A1

  公开（公告）日：2006-02-02

  Various non-limiting embodiments disclosed herein related to photochromic materials comprising the reaction product of (a) at least one ring-opening cyclic monomer, and (b) a photochromic initiator. Other non-limiting embodiments related to photochromic materials represented by: wherein S′ comprises the at least one ring-opened cyclic monomer as set forth herein. Other non-limiting embodiments related to photochromic compositions, optical elements, and methods of inhibiting migration of a photochromic material in a polymeric material using the photochromic materials disclosed herein. Methods of making such photochromic materials, compositions, and optical elements are also disclosed.

  本文披露了各种非限制性实施例，涉及光致变色材料，其包括（a）至少一种开环环状单体的反应产物，以及（b）光致变色引发剂。其他非限制性实施例涉及光致变色材料，该材料由下式表示：其中S’包括如本文所述的至少一种开环环状单体。其他非限制性实施例涉及光致变色组合物、光学元件和使用本文所披露的光致变色材料抑制聚合物材料中光致变色材料迁移的方法。本文还披露了制备此类光致变色材料、组合物和光学元件的方法。
• Photochromic Polymer
  申请人：Evans Richard Alexander

  公开号：US20140042377A1

  公开（公告）日：2014-02-13

  A photochromic polymer comprising at least two photochromic moieties linked by a straight or branched chain polymer selected from the group consisting of poly(C2 to C4 alkylene oxide), poly[C 1 to C 10 alkoxy substituted (C 2 to C 4 alkylene oxide)] and poly[C 1 to C- 15 acyloxy substituted (C 2 to C 4 alkylene oxide)].

  一种光致变色聚合物，包括至少两个光致变色基团，这些基团通过直链或支链聚合物链接，所述聚合物选自以下组合：聚（C2到C4烷氧基）烷，聚[C1到C10烷氧基取代（C2到C4烷氧基）]和聚[C1到C-15酰氧取代（C2到C4烷氧基）]。
• Photochromic polymer and composition comprising photochromic polymer
  申请人：Evans Richard Alexander

  公开号：US08865029B2

  公开（公告）日：2014-10-21

  A photochromic polymer comprising at least one siloxane oligomer and at least two photochromic groups covalently linked to one or both terminuses of the siloxane oligomer and compositions containing photochromic siloxane polymers with narrow polydispersity. The photochromic polymer enhances switching speed in rigid host polymers.

  一种光致变色聚合物，包括至少一种硅氧烷寡聚物和至少两个光致变色基团，它们与硅氧烷寡聚物的一个或两个端点共价连接，以及含有具有狭窄分子量分布的光致变色硅氧烷聚合物的组合物。该光致变色聚合物可以提高刚性宿主聚合物的切换速度。