3-氯-1,1,3,3-四氟-1-丙烯 | 406-46-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 3-氯-1,1,3,3-四氟-1-丙烯
• 英文名称: 3-chloro-1,1,3,3-tetrafluoropropene
• 英文别名: 3-chloro-1,1,3,3-tetrafluoro-propene；3-chloro-1,1,3,3-tetrafluoro-1-propene；3-Chlor-1,1,3,3-tetrafluor-prop-1-en；3-Chloro-1,1,3,3-tetrafluoropropen；3-Chlor-1,1,3,3-tetrafluor-propen；Propene, 3-chloro-1,1,3,3-tetrafluoro-；3-chloro-1,1,3,3-tetrafluoroprop-1-ene
• CAS: 406-46-2
• 化学式: C₃HClF₄
• 分子量: 148.488
• InChiKey: AYXCWSNLDUYPCX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  8
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3-氯-1,1,3,3-四氟-1-丙烯 在 三氯化铝 作用下， 生成 trans-1-chloro-1,3,3,3-tetrafluoropropene 、 cis-1-chloro-1,3,3,3-tetrafluoropropene
  参考文献：
  名称：

  Perfluoro-4-methyl-1,3-dioxole: a new monomer for high-Tg amorphous fluoropolymers

  摘要：

  A 4-Chloro-5-trifluoromethyl-2,2,4-trifluoro-1,3-dioxolane (1) was synthesised by reaction of CF2(OF)(2) with CF3-CH=CFCl; the elimination of HCl from (1) in basic conditions led to the formation of dioxole perfluoro-4-methyl-1,3-dioxole (2). Both these synthetic steps gave the corresponding product in high yield.A new synthetic route for the preparation of CF3-CH=CFCl, starting from CF2ClBr and CH2=CF2, together with some examples of polymerisation products obtained by reaction of dioxole (2) with fluoroolefins are also reported. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jfluchem.2003.10.009
• 作为产物：
  描述：

  全氟丙二烯 在 盐酸 作用下， 生成 3-氯-1,1,3,3-四氟-1-丙烯
  参考文献：
  名称：

  176.聚卤代丙二烯。第一部分：四氟丙二烯及其二聚体，以及二聚体与三氟亚硝基甲烷的反应

  摘要：

  DOI：

  10.1039/jr9650000978

文献信息

• Banks,R.E. et al., Proceedings of the Chemical Society, London, 1964, p. 121
  作者：Banks,R.E. et al.

  DOI：——

  日期：——
• 176. Polyhalogeno-allenes. Part I. Tetrafluoroallene, its dimer, and the reaction of the dimer with trifluoronitrosomethane
  作者：R. E. Banks、R. N. Haszeldine、D. R. Taylor

  DOI：10.1039/jr9650000978

  日期：——
• Perfluoro-4-methyl-1,3-dioxole: a new monomer for high-Tg amorphous fluoropolymers
  作者：Antonio Russo、Walter Navarrini

  DOI：10.1016/j.jfluchem.2003.10.009

  日期：2004.1

  A 4-Chloro-5-trifluoromethyl-2,2,4-trifluoro-1,3-dioxolane (1) was synthesised by reaction of CF2(OF)(2) with CF3-CH=CFCl; the elimination of HCl from (1) in basic conditions led to the formation of dioxole perfluoro-4-methyl-1,3-dioxole (2). Both these synthetic steps gave the corresponding product in high yield.A new synthetic route for the preparation of CF3-CH=CFCl, starting from CF2ClBr and CH2=CF2, together with some examples of polymerisation products obtained by reaction of dioxole (2) with fluoroolefins are also reported. (C) 2003 Elsevier B.V. All rights reserved.

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