2-hydroperfluorooct-1-ene | 103712-63-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-hydroperfluorooct-1-ene
• 英文别名: 2H-perfluoro-1-octene；1,1,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluorooct-1-ene
• CAS: 103712-63-6
• 化学式: C₈HF₁₅
• 分子量: 382.072
• InChiKey: RDUYLBKWAFOUKQ-UHFFFAOYSA-N

物化性质

• 沸点：
  107.1±8.0 °C(Predicted)
• 密度：
  1.618±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  23
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  15

反应信息

• 作为反应物：
  描述：

  2-hydroperfluorooct-1-ene 、 tris(4-bromophenyl)phosphine oxide 在 sodium acetate 作用下， 以 氯仿 、 N,N-二甲基甲酰胺 为溶剂， 以91%的产率得到Tris[4(1H,2H-perfluoro-1-octenyl)phenyl]phosphine oxide
  参考文献：
  名称：

  Method of generating a functionalised arylphosphine

  摘要：

  生成官能化芳基膦的方法，新型中间体和新型官能化芳基膦。

  公开号：

  US20030181767A1
• 作为产物：
  描述：

  1,1,1,2,2,3,3,4,4,5,5,6,6,8,8-十五氟-8-碘辛烷 在 sodium chloride 作用下， 反应 5.0h， 以98%的产率得到2-hydroperfluorooct-1-ene
  参考文献：
  名称：

  Synthesis and copolymerisation of fluorinated monomers bearing a reactive lateral group

  摘要：

  The synthesis and the radical copolymerisation of 2-hydroperfluorooct-1-ene (HPO) with vinylidene, fluoride (VDF), initiated by tertiobutyl peroxypivalate (TBPPI) at 75 degrees C, are presented. That fluorinated alkene (HPO) was synthesised in two steps starting from the thermal or redox telomerisation of VDF with C6F13I (after purification of the monoadduct compound by rectification) followed by a dehydroiodination in the presence of various alkalies. Their influences are discussed toward the yield of the reaction. The compositions of the resulting random-type copolymers were calculated by means of F-19 NMR spectroscopy and allowed one to quantify the respective amounts of each monomeric unit in the copolymer. From the Tidwell and Mortimer method, the reactivity ratios (r(i)) of both comonomers for this copolymerisation were determined showing a higher incorporation of VDF: r(VDF) = 12.0 +/- 3.0 and r(F2C=CHC6F13) = 0.9 +/- 0.4 at 74 degrees C. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jfluchem.2005.03.006

文献信息

• Polymerized cycloolefins using transition metal catalyst and end products thereof
  申请人：——

  公开号：US20030181607A1

  公开（公告）日：2003-09-25

  Methods for the addition polymerization of cycloolefins using a cationic Group 10 metal complex and a weakly coordinating anion of the formula: [(R′) z M(L′) x (L″) y ] b [WCA] d wherein [(R′) z M(L′) x (L″) y ] is a cation complex where M represents a Group 10 transition metal; R′ represents an anionic hydrocarbyl containing ligand; L′ represents a Group 15 neutral electron donor ligand; L″ represents a labile neutral electron donor ligand; x is 1 or 2; and y is 0, 1, 2, or 3; and z is 0 or 1, wherein the sum of x, y, and z is 4; and [WCA] represents a weakly coordinating counteranion complex; and b and d are numbers representing the number of times the cation complex and weakly coordinating counteranion complex are taken to balance the electronic charge on the overall catalyst complex.

  使用阳离子第10族金属配合物和公式为[(R′)zM(L′)x(L″)y]b[WCA]d的弱配位阴离子的方法进行环烯烃的加成聚合，其中[(R′)zM(L′)x(L″)y]是一个阳离子配合物，M代表第10族过渡金属；R′代表含阴离子的碳氢基配体；L′代表第15族中性电子给体配体；L″代表不稳定的中性电子给体配体；x为1或2；y为0、1、2或3；z为0或1，其中x、y和z的总和为4；[WCA]代表弱配位对阴离子配合物；b和d是表示需要多少次阳离子配合物和弱配位对阴离子配合物来平衡整个催化剂配合物的电荷的数字。
• Catalyst and methods for polymerizing cycloolefins
  申请人：The B.F.Goodrich Company

  公开号：US20030023013A1

  公开（公告）日：2003-01-30

  Methods for the addition polymerization of cycloolefins using a cationic Group 10 metal complex and a weakly coordinating anion of the formula: [(R′) z M(L′) x (L″) y ] b [WCA] d wherein [(R′) z M(L′) x (L″) y ] is a cation complex where M represents a Group 10 transition metal; R′ represents an anionic hydrocarbyl containing ligand; L′ represents a Group 15 neutral electron donor ligand; L″ represents a labile neutral electron donor ligand; x is 1 or 2; and y is 0, 1, 2, or 3; and z is 0 or 1, wherein the sum of x, y, and z is 4; and [WCA] represents a weakly coordinating counteranion complex; and b and d are numbers representing the number of times the cation complex and weakly coordinating counteranion complex are taken to balance the electronic charge on the overall catalyst complex.

  使用阳离子第10族金属配合物和一个弱配位阴离子的方法进行环烯烃的加成聚合，其化学式为：[(R′)zM(L′)x(L″)y]b[WCA]d，其中 [(R′)zM(L′)x(L″)y]是一个阳离子配合物，其中M代表第10族过渡金属；R′代表含有负离荷的碳氢基配体；L′代表第15族中性电子给体配体；L″代表不稳定中性电子给体配体；x为1或2；y为0、1、2或3；z为0或1，其中x、y和z的总和为4；[WCA]代表一个弱配位的反离子配合物；b和d是代表阳离子配合物和弱配位反离子配合物被取用的次数以平衡整个催化剂复合物的电荷的数字。
• CATALYST AND METHODS FOR POLYMERIZING CYCLOOLEFINS
  申请人：——

  公开号：US20020052454A1

  公开（公告）日：2002-05-02

  Methods for the addition polymerization of cycloolefins using a cationic Group 10 metal complex and a weakly coordinating anion of the formula: [(R′) z M(L′) x (L″) y ] b [WCA] d wherein [(R′) z M(L′) x (L″) y ] is a cation complex where M represents a Group 10 transition metal; R′ represents an anionic hydrocarbyl containing ligand; L′ represents a Group 15 neutral electron donor ligand; L″ represents a labile neutral electron donor ligand; x is 1 or 2; and y is 0, 1, 2, or 3; and z is 0 or 1, wherein the sum of x, y, and z is 4; and [WCA] represents a weakly coordinating counteranion complex; and b and d are numbers representing the number of times the cation complex and weakly coordinating counteranion complex are taken to balance the electronic charge on the overall catalyst complex.

  使用阳离子第10族金属配合物和公式为[(R′)zM(L′)x(L″)y]b和[WCA]d的弱配位阴离子的方法，进行环烯烃的加成聚合。其中[(R′)zM(L′)x(L″)y]是阳离子配合物，其中M代表第10族过渡金属；R′代表含负离子的碳氢基配体；L′代表第15族中性电子给体配体；L″代表不稳定的中性电子给体配体；x为1或2；y为0、1、2或3；z为0或1，其中x、y和z的总和为4；[WCA]代表弱配位对阴离子配合物；b和d是表示需要取多少次阳离子配合物和弱配位对阴离子配合物以平衡催化剂整体电荷的数字。
• A Method of Generating A Functionalised Arylphosphine
  申请人：The University of Liverpool

  公开号：US20040059159A2

  公开（公告）日：2004-03-25

  Abstract of the Disclosure A method of generating a functionalised arylphosphine, novel intermediates and novel functinalised arylphosphines.

  本发明涉及一种生成功能化芳基膦、新型中间体和新型功能化芳基膦的方法。
• Polymer film, and polymeric compound for the production thereof
  申请人：CANON KABUSHIKI KAISHA

  公开号：EP1108761A2

  公开（公告）日：2001-06-20

  A novel polymer film is based on a principle totally different from that of the known liquid-repelling agents used with the known surface-modifying methods and can easily modify the properties of the surface of an article. More specifically, such a polymer film can be formed on the surface of an article by application to improve the liquid repellency of the surface of the article and maintain the liquid-repelling effect. A novel polymeric compound can be used to form such a polymer film and a liquid-repellency treatment solution containing such a polymeric compound. There is also provided a method of modifying the surface of an article by means of such a liquid-repellency treatment solution and articles having a modified surface. The polymer film contains fluorine atoms and has physical aggregates of polymer chains in the inside and/or on the surface.

  一种新型聚合物薄膜的原理完全不同于与已知表面改性方法一起使用的已知斥液剂，它可以很容易地改变物品表面的特性。更具体地说，这种聚合物薄膜可以通过涂抹的方式在物品表面形成，以提高物品表面的斥液性并保持斥液效果。可以使用一种新型聚合物化合物来形成这种聚合物薄膜，以及含有这种聚合物化合物的斥液处理溶液。此外，还提供了一种通过这种斥液处理液对物品表面进行改性的方法，以及具有改性表面的物品。聚合物薄膜含有氟原子，内部和/或表面有聚合物链的物理聚集。