3-methyl-3-tert-butylperoxy-1-butyne | 52258-96-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-methyl-3-tert-butylperoxy-1-butyne
• 英文别名: 3-(tert-butylperoxy)-3-methyl-1-butyne；2-tert-butylperoxy-2-methyl-3-butyne；3-(tert-Butylperoxy)-3-methylbut-1-yne；3-tert-butylperoxy-3-methylbut-1-yne
• CAS: 52258-96-5
• 化学式: C₉H₁₆O₂
• 分子量: 156.225
• InChiKey: QVUYVULKJVINCT-UHFFFAOYSA-N

物化性质

• 沸点：
  47-48.5 °C(Press: 30 Torr)
• 密度：
  0.899±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  11
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-methyl-3-tert-butylperoxy-1-butyne 在 ammonium hydroxide 、 溴 、 silver nitrate 作用下， 生成 1-Bromo-3-methyl-3-tert-butylperoxy-1-butyne
  参考文献：
  名称：

  Moiseichuk, K. L.; Dikusar, E. A.; Yuvchenko, A. P., Journal of general chemistry of the USSR, 1989, vol. 59, # 5.2, p. 1053 - 1054

  摘要：

  DOI：

文献信息

• Polymerization of styrene initiated by acetylenic peroxides
  作者：S. G. Stepin、E. A. Dikusar

  DOI：10.1134/s1070427209010248

  日期：2009.1

  The initiating activity of acetylenic peroxides in polymerization of styrene was studied. The kinetic parameters of the polymerization and its initiation were calculated. The effect exerted by the structure of radicals on the initiating activity of peroxides was evaluated.

  研究了炔属过氧化物在苯乙烯聚合反应中的引发活性。计算了聚合反应及其引发的动力学参数。评估了自由基的结构对过氧化物引发活性的影响。
• Acetylenic Peroxides Derived from 4,4'-Biphenyldicarboxylic Acids
  作者：A. P. Yuvchenko、E. A. Dikusar、V. K. Ol'khovik

  DOI：10.1023/b:rugc.0000015990.86981.1e

  日期：2003.9

  Lithium peroxyacetylides were reacted with Paraform to obtain lithium peroxyalcoholates. The latter react with 4,4'-biphenyldicarboxylic and 2,2'-sulfonyl-4,4'-biphenyldicarboxylic dichlorides, yielding peroxy-contaming esters. Lithium peroxyacetylides react with 4,4'-biphenyldicarboxylic and 2-methoxy- and ;2.2'-sulfonyl-4,4'-biphenyldicarboxylic acids to form acetylenic biphenyldihydroxytetraperoxides.
• Dikusar; Shirokii; Yuvchenko, Russian Journal of General Chemistry, 1999, vol. 69, # 8, p. 1266 - 1272
  作者：Dikusar、Shirokii、Yuvchenko、Bazhanov、Moiseichuk、Khrustalev、Antipin

  DOI：——

  日期：——
• Dikusar; Yuvchenko; Zhukovskaya, Russian Journal of General Chemistry, 1997, vol. 67, # 9, p. 1463 - 1466
  作者：Dikusar、Yuvchenko、Zhukovskaya、Murashko、Moiseichuk

  DOI：——

  日期：——
• ——
  作者：E. A. Dikusar、N. A. Zhukovskaya、K. L. Moiseichuk、A. P. Yuvchenko

  DOI：10.1023/a:1015588911126

  日期：——

  A synthesis was developed of 2,5-dimethyl-2-tert-alkylperoxy-5-lithiumoxy-3-undecynes by treating the corresponding peroxyalkynes with butyllithium followed by reaction of the arising lithium peroxyacetylides with 2-octanone. The lithium peroxyalcoholates undergo hydrolysis with water to furnish peroxy bond containing alcohols. They also react with methyl and ethyl iodides, alkyl and benzyl bromides in the presence of hexamethylphosphoramide to afford the corresponding 2,5-dimethyl-2-tert-alkylperoxy5-alkyl(benzyl)oxy-3-undecynes, with benzoyl chloride they yield peroxy bond containing benzoates. The thermal stability of the peroxides obtained was estimated by derivatography.