2-chloro-6-allyloxy-s-tetrazine

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-chloro-6-allyloxy-s-tetrazine
• 英文别名: 3-Chloro-6-prop-2-enoxy-1,2,4,5-tetrazine；3-chloro-6-prop-2-enoxy-1,2,4,5-tetrazine
• 化学式: C₅H₅ClN₄O
• 分子量: 172.574
• InChiKey: MHPYHTMOCNBCFU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  11
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  60.8
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  3,3,4,4,5,5,6,6,7,7,8,8,8-十三氟-1-辛醇 、 2-chloro-6-allyloxy-s-tetrazine 在 2,4,6-三甲基吡啶 作用下， 以 二氯甲烷 为溶剂， 反应 24.0h， 以53%的产率得到2-(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctan-1-oxy)-6-allyloxy-s-tetrazine
  参考文献：
  名称：

  Synthesis and characterization of new fluorinated tetrazines displaying a high fluorescence yield

  摘要：

  New tetrazines substituted with perfluorinated alkyl chains have been synthesized and their electrochemical and photophysical properties investigated under various conditions. Their fluorescence quantum yields in dichloromethane appear to be interestingly slightly higher than with classical tetrazines, placing these new derivatives among the most fluorescent tetrazines characterized to date. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2014.03.031
• 作为产物：
  描述：

  二氯均四嗪 、 烯丙醇 在 2,4,6-三甲基吡啶 作用下， 以 二氯甲烷 为溶剂， 反应 1.5h， 以82%的产率得到2-chloro-6-allyloxy-s-tetrazine
  参考文献：
  名称：

  Synthesis and characterization of new fluorinated tetrazines displaying a high fluorescence yield

  摘要：

  New tetrazines substituted with perfluorinated alkyl chains have been synthesized and their electrochemical and photophysical properties investigated under various conditions. Their fluorescence quantum yields in dichloromethane appear to be interestingly slightly higher than with classical tetrazines, placing these new derivatives among the most fluorescent tetrazines characterized to date. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2014.03.031

文献信息

• TROUSSE DE REVELATION COMPRENANT UN AGENT FLUORESCENT ET UN CYANOACRYLATE, PROCEDE DE CO-FUMIGATION D'UN AGENT FLUORESCENT ET D'UN CYANOACRYLATE
  申请人：Crime Scene Technology

  公开号：EP2683297A1

  公开（公告）日：2014-01-15
• VISUALIZATION KIT COMPRISING A FLUORESCENT AGENT AND A CYANOACRYLATE, AND METHOD OF COFUMIGATION OF A FLUORESCENT AGENT AND A CYANOACRYLATE
  申请人：Prete Cosimo

  公开号：US20140004620A1

  公开（公告）日：2014-01-02

  The present invention relates to a visualization kit including (A) a cyanoacrylate and (B) a fluorescent agent having a molecular weight of less than 400 g·mol −1 , a sublimation temperature of less than 200° C., and an extinction coefficient of less than 2950 L·mol −1 ·cm −1 ; to a method including the cofumigation of a cyanoacrylate (A) and a fluorescent agent (B); and to a method for visualizing traces on a substrate, employing the method of cofumigation.
• US9791369B2
  申请人：——

  公开号：US9791369B2

  公开（公告）日：2017-10-17
• [EN] EXPOSURE KIT INCLUDING A FLUORESCENT AGENT AND A CYANOACRYLATE, AND METHOD FOR THE CO-FUMIGATION OF A FLUORESCENT AGENT AND A CYANOACRYLATE<br/>[FR] TROUSSE DE REVELATION COMPRENANT UN AGENT FLUORESCENT ET UN CYANOACRYLATE, PROCEDE DE CO-FUMIGATION D'UN AGENT FLUORESCENT ET D'UN CYANOACRYLATE
  申请人：CRIME SCENE TECHNOLOGY

  公开号：WO2012120234A1

  公开（公告）日：2012-09-13

  La présente invention porte sur une trousse de révélation comprenant (A) un cyanoacrylate et (B) un agent fluorescent présentant un poids moléculaire inférieur à 400 g. mol-1, une température de sublimation inférieure à 200 °C, et un coefficient d'extinction inférieur à 2950 L. mol-1.cm-1; sur un procédé comprenant la co-fumigation d'un cyanoacrylate (A) et d'un agent fluorescent (B); ainsi que sur un procédé de révélation de traces sur un support mettant en œuvre le procédé de co-fumigation.
• Synthesis and characterization of new fluorinated tetrazines displaying a high fluorescence yield
  作者：Radhia Ben Châabane、Refka Guermazi、Gilles Clavier、Pierre Audebert、Ahmed Hedhli

  DOI：10.1016/j.dyepig.2014.03.031

  日期：2014.9

  New tetrazines substituted with perfluorinated alkyl chains have been synthesized and their electrochemical and photophysical properties investigated under various conditions. Their fluorescence quantum yields in dichloromethane appear to be interestingly slightly higher than with classical tetrazines, placing these new derivatives among the most fluorescent tetrazines characterized to date. (C) 2014 Elsevier Ltd. All rights reserved.