四丙二醇 | 30242-05-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 四丙二醇
• 英文名称: 2-(2-[2-(2-hydroxypropoxy)-propoxy]propoxy)propan-1-ol
• 英文别名: tetrapropylene glycol；tetrapropyleneglycol；1,3-propanediol tetramer；TePG；3,3'-(4-oxa-heptane-1,7-diyldioxy)-bis-propan-1-ol；4,8,12-trioxa-pentadecane-1,15-diol；3-[3-[3-(3-Hydroxypropoxy)propoxy]propoxy]propan-1-ol
• CAS: 30242-05-8
• 化学式: C₁₂H₂₆O₅
• 分子量: 250.335
• InChiKey: SSQYDJBBYFFAOG-UHFFFAOYSA-N

物化性质

• 沸点：
  145 °C(Press: 2 Torr)
• 密度：
  1.0153 g/cm3
• 溶解度：
  可溶于氯仿（少许）、甲醇（少许）

计算性质

• 辛醇/水分配系数(LogP)：
  -0.2
• 重原子数：
  17
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  68.2
• 氢给体数：
  2
• 氢受体数：
  5

安全信息

• 海关编码：
  2909499000

反应信息

• 作为反应物：
  描述：

  四丙二醇 在 palladium on activated charcoal sodium hydroxide 、 氢气 、 四丁基硫酸氢铵 作用下， 以 甲醇 、 水 、 苯 为溶剂， 65.0 ℃ 、101.33 kPa 条件下， 反应 41.0h， 生成 hexapropyleneglycol
  参考文献：
  名称：

  Preparation of Discrete Oligoethers:  Synthesis of Pentabutylene Glycol and Hexapropylene Glycol by Two Complementary Methods

  摘要：

  Two experimentally facile methods for the preparation of discrete oligoethers are reported. The first involves an iterative sequence of oxidation, acetal formation, and reductive ring opening for the synthesis of penta-1,4-butylene glycol. The second method is also iterative, comprising phase-transfer etherification and end-group deprotection to form hexa-1,3-propylene glycol. These methods offer significantly improved yields and purification protocols over previously reported syntheses.

  DOI：

  10.1021/jo034728k
• 作为产物：
  描述：

  dibenzyl tetrapropyleneglycol 在 palladium on activated charcoal 氢气 作用下， 以 甲醇 为溶剂， 反应 5.0h， 以89%的产率得到四丙二醇
  参考文献：
  名称：

  Preparation of Discrete Oligoethers:  Synthesis of Pentabutylene Glycol and Hexapropylene Glycol by Two Complementary Methods

  摘要：

  Two experimentally facile methods for the preparation of discrete oligoethers are reported. The first involves an iterative sequence of oxidation, acetal formation, and reductive ring opening for the synthesis of penta-1,4-butylene glycol. The second method is also iterative, comprising phase-transfer etherification and end-group deprotection to form hexa-1,3-propylene glycol. These methods offer significantly improved yields and purification protocols over previously reported syntheses.

  DOI：

  10.1021/jo034728k

文献信息

• ANTIMICROBIAL COMPOSITIONS COMPRISING TRIMETHYLENE GLYCOL OLIGOMER AND METHODS OF USING THE COMPOSITIONS
  申请人：Fenyvesi Gyorgyi

  公开号：US20110224307A1

  公开（公告）日：2011-09-15

  Disclosed are antimicrobial compositions, and methods for killing, inhibiting, or preventing the growth of microbes, using trimethylene glycol oligomers or dimers. The trimethylene glycol oligomers and dimers have the formula R(CH 2 CH 2 CH 2 —O—CH 2 CH 2 CH 2 ) n R 1 where R and R 1 are hydroxyl, amine, or ester functionalitiess, and n is 2 or higher. The antimicrobial compositions are useful in personal care and cosmetic compositions

  本发明涉及抗微生物组合物，以及使用三亚甲基二醇低聚物或二聚物杀灭、抑制或防止微生物生长的方法。所述三亚甲基二醇低聚物和二聚物的化学式为R(CH2CH2CH2—O—CH2CH2CH2)nR1，其中R和R1是羟基、胺基或酯基官能团，n为2或更高。所述抗微生物组合物适用于个人护理和化妆品组合物。
• Photosensitive lithographic printing plate
  申请人：——

  公开号：US20020136987A1

  公开（公告）日：2002-09-26

  A photosensitive lithographic printing plate comprising: a support; and a photosensitive layer, wherein the photosensitive layer comprises: a polyurethane resin binder comprising an aliphatic cyclic structure which has a carboxyl group as a substituent directly or indirectly attached to the structure; or a polyvinyl alcohol resin binder modified with an acetal skeleton comprising an aliphatic cyclic structure.

  一种光敏石版印刷版，包括：支撑体；以及光敏层，其中光敏层包括：聚氨酯树脂粘合剂，其包含有一个脂环结构，该脂环结构具有直接或间接连接到结构上的羧基取代基；或者是改性的聚乙烯醇树脂粘合剂，其具有一个脂环结构的缩醛骨架。
• POLYMERIZABLE COMPOSITION AND LITHOGRAPHIC PRINTING PLATE PRECURSOR
  申请人：Sugasaki Atsushi

  公开号：US20090053653A1

  公开（公告）日：2009-02-26

  A polymerizable composition comprising: a polyurethane resin synthesized by using a compound represented by the following formula (I) as one of starting materials; a photopolymerization or thermal polymerization initiator; and an addition-polymerizable compound having an ethylenically unsaturated bond: wherein X represents a tri- or higher valent atom; R 1 and R 2 each independently represent a single bond or an alkylene group optionally having a substituent, provided that R 1 and R 2 do not represent a single bond at a same time; A represents a straight chain linking group; and n is an integer of from 1 to 5.

  一种可聚合的组合物，包括：由使用以下式(I)所表示的化合物之一作为起始材料合成的聚氨酯树脂；光聚合或热聚合引发剂；以及具有乙烯基不饱和键的加成聚合化合物：其中，X代表三价或更高价原子；R1和R2各自独立地表示单键或具有取代基的烷基基团，但R1和R2不能同时表示单键；A表示直链连接基团；n为1到5的整数。
• PHOTOSENSITIVE COMPOSITION, PLANOGRAPHIC PRINTING PLATE PRECURSOR, POLYURETHANE, AND METHOD FOR PRODUCING POLYURETHANE
  申请人：FUJIFILM CORPORATION

  公开号：US20140134540A1

  公开（公告）日：2014-05-15

  A photosensitive composition includes (A) a polyurethane obtained by reacting a diol component including a compound represented by the following Formula (I) with a polyisocyanate component; and (B) a photosensitive component. In Formula (I), A represents a single bond, or a divalent linking group including an atom selected from the group consisting of a carbon atom, a hydrogen atom, and an oxygen atoms; B represents a monovalent organic group; each of R 1 to R 5 independently represents a hydrogen atom or an alkyl group; m represents an integer from 0 to 3; n represents an integer from 0 to 3; and m+n is not zero.

  一种光敏组合物，包括(A)聚氨酯和(B)光敏组分。聚氨酯是通过将包括以下式(I)的化合物的二元醇组分与多异氰酸酯组分反应而获得的。在式(I)中，A表示单键，或者包括从群组中选择的原子的双价连接基团，该群组包括碳原子，氢原子和氧原子；B表示单价有机基团；R1到R5中的每一个独立地表示氢原子或烷基；m表示从0到3的整数；n表示从0到3的整数；且m+n不为零。
• Dithiophosphorus/amine salts and aqueous compositions containing same
  申请人：The Lubrizol Corporation

  公开号：EP0116399A2

  公开（公告）日：1984-08-22

  Phosphorus, sulfur and nitrogen containing salts prepared from dithiophosphorus compounds and amnines are disclosed, which salts find utility in aqueous functional fluids. Compositions comprising a continuous aqueous phase, at least one of said salts prepared from dithiophosphorus compounds and amines and optionally a surface active agent are also disclosed.

  本发明公开了由二硫磷化合物和胺制备的含磷、硫和氮盐，这些盐可用于水性功能液。此外，还公开了由连续水相、至少一种由二硫磷化合物和胺制备的上述盐类以及表面活性剂组成的组合物。

表征谱图