3-propylamino-2-butanone | 95641-24-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-propylamino-2-butanone
• 英文别名: 2-Butanone, 3-(propylamino)-；3-(propylamino)butan-2-one
• CAS: 95641-24-0
• 化学式: C₇H₁₅NO
• mdl: MFCD18813339
• 分子量: 129.202
• InChiKey: JFKBIQPBUBKNGD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  9
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.857
• 拓扑面积：
  29.1
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-propylamino-2-butanone 生成 3-[Ethyl(propyl)amino]butan-2-one
  参考文献：
  名称：

  FRIARY, R.;KIRBY, G. W., J. CHEM. SOC. CHEM. COMMUN., 1984, N 20, 1383

  摘要：

  DOI：
• 作为产物：
  描述：

  正丙胺 、 3-羟基-2-丁酮 以 环己烷 、 水 为溶剂， 反应 0.5h， 生成 3-propylamino-2-butanone
  参考文献：
  名称：

  Synthesis ofN-1-Substituted 2-Amino-3-t-butoxycarbonyl-4,5- dimethylpyrroles

  摘要：

  DOI：

  10.1055/s-1985-31182

文献信息

• Reactions of a Platinum(III) Dimeric Complex with Alkynes in Water:  Novel Approach to α-Aminoketone, α-Iminoketone, and α,β-Diimine via Ketonyl−Pt(III) Dinuclear Complexes
  作者：Masahiko Ochiai、Yong-Shou Lin、Jun Yamada、Hanae Misawa、Saiko Arai、Kazuko Matsumoto

  DOI：10.1021/ja0302634

  日期：2004.3.3

  of the platinum(III) dimeric complex [Pt2(NH3)4((CH3)3CCONH)2(NO3)2](NO3)2 (1), prepared in situ by the oxidation of the platinum blue complex [Pt4(NH3)8((CH3)3CCONH)4](NO3)5 (2) with Na2S2O8, with terminal alkynes CH⋮CR (R = (CH2)nCH3 (n = 2−5), (CH2)nCH2OH (n = 0−2), CH2OCH3, and Ph), in water gave a series of ketonyl−Pt(III) dinuclear complexes [Pt2(NH3)4((CH3)3CCONH)2(CH2COR)](NO3)3 (3, R = (CH2)2CH3;

  铂 (III) 二聚配合物 [Pt2(NH3)4((CH3)3CCONH)2(NO3)2](NO3)2 (1) 的反应，通过氧化铂蓝配合物 [Pt4(NH3) 原位制备)8((CH3)3CCONH)4](NO3)5 (2) 与 Na2S2O8，末端炔烃 CH⋮CR (R = (CH2)nCH3 (n = 2−5), (CH2)nCH2OH (n = 0−) 2)、CH2OCH3 和 Ph)，在水中得到一系列酮基-Pt(III) 双核配合物 [Pt2(NH3)4((CH3)3CCONH)2(CH2COR)](NO3)3 (3, R = ( CH2)2CH3; 4, R = (CH2)3CH3; 5, R = (CH2)4CH3; 6, R = (CH2)5CH3; 7, R = CH2OH; 8, R = CH2CH2OH; 9, R = (CH2) 2CH2OH；10，R = CH2OCH3；11，R
• Method for Producing Aromatic Compound Polymer
  申请人：Higashimura Hideyuki

  公开号：US20090018309A1

  公开（公告）日：2009-01-15

  A method for producing an aromatic compound polymer comprising oxidatively polymerizing one or more of aromatic compound(s) having two or more hydrogen atoms directly connected to aromatic ring(s), in the presence of an oxidizing agent, wherein the method employs a catalyst composed of a transition metal complex or a catalyst prepared from a transition metal complex and an activating agent, and said catalyst has a parameter P defined by the following formula (A) of 0.50 or more, and a parameter Eo defined by the following formula (B) of 0.50 [V] or more: P=Af/Ai (A) and Eo =( Epa+Epc )/2[V]  (B).

  一种生产芳香族化合物聚合物的方法，包括在氧化剂存在下氧化聚合具有两个或更多氢原子直接连接到芳香环的一个或多个芳香族化合物，其中该方法采用由过渡金属配合物或由过渡金属配合物和活化剂制备的催化剂，所述催化剂具有以下公式（A）定义的参数P，P的值为0.50或更高，并且具有以下公式（B）定义的参数Eo，Eo的值为0.50 [V]或更高：P=Af/Ai（A）和Eo=(Epa+Epc)/2[V]（B）。
• USE OF PEPTIDE DERIVATIVES FOR INDUCING CELL DIFFERENTIATION
  申请人：Obschestvo S Ogranichennoi Otvetstennostiyu "Pharmenterprises"

  公开号：EP1491206B1

  公开（公告）日：2010-11-17
• ISOBARIC MASS LABELS
  申请人：Electrophoretics Limited

  公开号：US20170146549A1

  公开（公告）日：2017-05-25

  The present invention relates to a set of two or more mass labels, wherein each mass label comprises the formula: X-L-M-Re wherein X is a reporter moiety having an exact mass, L is a bond cleavable by collision in a mass spectrometer, M is a mass modifier, and Re is a) a reactive functionality for attaching the mass label to an analyte or b) the analyte, wherein each mass label in the set has an integer mass, wherein each mass label in the set has the same integer mass, and wherein the set comprises two or more subsets of mass labels, each subset comprising one, two or more mass labels, and wherein, when the subset comprises two or more mass labels, the exact mass of the reporter moiety X of each mass label in the subset is different from the exact mass of the reporter moiety X of the mass labels in the same subset and in all other subsets, and wherein each mass label is distinguishable by mass spectrometry.
• US8048982B2
  申请人：——

  公开号：US8048982B2

  公开（公告）日：2011-11-01