2-tert-butyl-perylene | 108318-07-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 2-tert-butyl-perylene
• 英文别名: 2-(1,1-Dimethylethyl)perylene；2-tert-butylperylene
• CAS: 108318-07-6
• 化学式: C₂₄H₂₀
• 分子量: 308.423
• InChiKey: UTBOSRSDKQCULX-UHFFFAOYSA-N

物化性质

• 沸点：
  492.2±12.0 °C(Predicted)
• 密度：
  1.173±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  24
• 可旋转键数：
  1
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  2-tert-butyl-perylene 在 (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride 、 N-溴代丁二酰亚胺(NBS) 、 四(三苯基膦)钯 、 potassium acetate 、 potassium carbonate 作用下， 以 1,4-二氧六环 为溶剂， 反应 66.0h， 生成 8-[4-[5-Tert-butyl-10-[4-(2,2-difluoro-4,6,10,12-tetramethyl-3-aza-1-azonia-2-boranuidatricyclo[7.3.0.03,7]dodeca-1(12),4,6,8,10-pentaen-8-yl)-3,5-dimethylphenyl]perylen-3-yl]-2,6-dimethylphenyl]-2,2-difluoro-4,6,10,12-tetramethyl-3-aza-1-azonia-2-boranuidatricyclo[7.3.0.03,7]dodeca-1(12),4,6,8,10-pentaene
  参考文献：
  名称：

  [EN] BORON-CONTAINING CYCLIC EMISSIVE COMPOUNDS AND COLOR CONVERSION FILM CONTAINING THE SAME
  [FR] COMPOSÉS ÉMISSIFS CYCLIQUES CONTENANT DU BORE ET FILM DE COLORISATION CONTENANT CEUX-CI

  摘要：

  本公开涉及新型的光致发光配合物，该配合物包括与蓝色光吸收基团共价键结合的BODIPY部分，包含该光致发光配合物的色转换膜，以及使用该配合物的背光单元。

  公开号：

  WO2020210761A1
• 作为产物：
  描述：

  1-bromo-8-(5-tert-butyl-2,3-bis(trimethylsilylethynyl)phenyl)naphthalene 在 偶氮二异丁腈 、 potassium carbonate 作用下， 以 四氢呋喃 、 甲醇 、 苯 为溶剂， 反应 10.0h， 生成 2-tert-butyl-perylene
  参考文献：
  名称：

  伯格曼反应作为一种综合工具：优点和局限性

  摘要：

  Bergman环芳烃化反应可有效地将易于制备的无环烯二炔转化为芳环。为了使用该反应制备更大的官能化稠合芳族体系，必须全面了解官能化如何影响环芳构化。在这里，我们介绍了三个不同功能化位点上取代基对环芳构化的影响以及如何对这些官能团进行定制以制备更复杂的系统的研究。

  DOI：

  10.1016/s0040-4020(01)00247-2

文献信息

• Lund, Torben; Lund, Henning, Acta chemica Scandinavica. Series B: Organic chemistry and biochemistry, 1986, vol. 40, # 6, p. 470 - 485
  作者：Lund, Torben、Lund, Henning

  DOI：——

  日期：——
• Experimental Fingerprints of Vibrational Wave-Packet Motion during Ultrafast Heterogeneous Electron Transfer
  作者：C. Zimmermann、F. Willig、S. Ramakrishna、B. Burfeindt、B. Pettinger、R. Eichberger、W. Storck

  DOI：10.1021/jp011106z

  日期：2001.9.1

  By application of 20 fs laser pulses, vibrational wave packets of low-energy modes (mainly 357 and 421 cm(-1)) were generated in the perylene chromophore that gave rise to periodic beats that lasted longer than I ps in transient absorption signals. Electron transfer from the excited singlet state of the perylene chromophore, attached as molecule DTB-Pe via the -CH2-phosphonic acid group to anatase TiO2, was measured in ultrahigh vacuum with a time constant of 75 fs. The vibrational wave packet that was generated in the donor state continued its motion for several hundred femtoseconds in the product state of the reaction, i.e., in the ionized chromophore. This is direct proof for electron transfer occurring from a nonrelaxed vibrational population that was created by the short laser pulse in the donor molecule. The rise of the product state showed a staircase-like time dependence. The steps are attributed to electron transfer that occurs preferentially each time the vibrational wave packet (frequency 480 cm(-1)) reaches a crossing point for the potential curves of reactant and product state. Such wave-packet modulation of heterogeneous electron transfer can arise if the density of electronic acceptor states in the electrode is changing strongly over an energy range on the order of the reorganization energy below the excited molecular donor orbital.
• [EN] BORON-CONTAINING CYCLIC EMISSIVE COMPOUNDS AND COLOR CONVERSION FILM CONTAINING THE SAME<br/>[FR] COMPOSÉS ÉMISSIFS CYCLIQUES CONTENANT DU BORE ET FILM DE COLORISATION CONTENANT CEUX-CI
  申请人：NITTO DENKO CORP

  公开号：WO2020210761A1

  公开（公告）日：2020-10-15

  The present disclosure relates to novel photoluminescent complexes comprising a BODIPY moiety covalently bonded to a blue light absorbing moiety, a color conversion film comprising the photoluminescent complex, and a back-light unit using the same.

  本公开涉及新型的光致发光配合物，该配合物包括与蓝色光吸收基团共价键结合的BODIPY部分，包含该光致发光配合物的色转换膜，以及使用该配合物的背光单元。
• The Bergman reaction as a synthetic tool: advantages and restrictions
  作者：Daniel M Bowles、Grant J Palmer、Chad A Landis、John L Scott、John E Anthony

  DOI：10.1016/s0040-4020(01)00247-2

  日期：2001.4

  The Bergman cycloaromatization reaction efficiently converts easily prepared acyclic enediynes into aromatic rings. In order to prepare larger, functionalized fused aromatic systems using this reaction, a thorough understanding of how functionalization affects cycloaromatization is necessary. We present here our studies on the influence of substituents at three different functionalization sites on

  Bergman环芳烃化反应可有效地将易于制备的无环烯二炔转化为芳环。为了使用该反应制备更大的官能化稠合芳族体系，必须全面了解官能化如何影响环芳构化。在这里，我们介绍了三个不同功能化位点上取代基对环芳构化的影响以及如何对这些官能团进行定制以制备更复杂的系统的研究。