3-乙基-2-甲基-1-戊烯 | 19780-67-7

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 中文名称: 3-乙基-2-甲基-1-戊烯
• 英文名称: 3-ethyl-2-methyl-pent-2-ene
• 英文别名: 3-Aethyl-2-methyl-pent-2-en；1.1-Dimethyl-2.2-diaethyl-aethylen；3-Isopropyliden-pentan；α.α-Dimethyl-β.β-diaethyl-aethylen；γ-Isopropyliden-pentan；2-Methyl-3-ethyl-2-pentene；3-ethyl-2-methylpent-2-ene
• CAS: 19780-67-7
• 化学式: C₈H₁₆
• mdl: MFCD00060947
• 分子量: 112.215
• InChiKey: FQYUGAXHZSQHMU-UHFFFAOYSA-N

物化性质

• 熔点：
  -103.01°C (estimate)
• 沸点：
  120.2°C (estimate)
• 密度：
  0.7350
• 保留指数：
  791.8;778

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  8
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 海关编码：
  2901299090

反应信息

• 作为反应物：
  描述：

  3-乙基-2-甲基-1-戊烯 在 Cl₂ radical anion 作用下， 以 水 、 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Radiolytic reductions and oxidations in dimethyl sulfoxide solutions: solvent effects on reactivity of halogen atom complexes

  摘要：

  Radiolysis of dimethyl sulfoxide (DMSO) solutions containing various additives was used to achieve clean one-electron reduction of oxidation of solutes. Pulse radiolysis of benzoquinone in DMSO solutions containing acetone and triethylamine permitted conversion of all primary radicals into reducing species. The total yield of reduction in the gamma-radiolysis of methyl viologen solutions was found to be 0.37-mu-mol/J. In the pulse radiolysis of TMPD and triphenylamine in aerated DMSO containing LiCl and/or CCl4, all the primary radicals were converted into oxidizing species and gave a maximum yield of 0.39-mu-mol/J. In the latter systems, oxidation was partly by halogen atom complexes. The reactivity of complexes of DMSO (DMSO.Cl, DMSO.Br) and of halide ions (Br2.-,I2.-) was examined for several organic compounds. DMSO.Cl oxidizes chlorpromazine, triphenylamine, and zinc porphyrin with rate constants of the order of 10(7)-10(8) M-1 s-1, and the rates increase upon addition of CH2Cl2 as well as upon addition of water and formamide. DMSO.Cl also reacts with olefins by addition of Cl to the double bond; the rate constants increase upon increasing the electron-donating properties of the substituents on the double bond. The rate constants for oxidation of chlorpromazine by Br2.- and I2.- increase by more than 2 orders of magnitude upon changing the solvent from DMSO gradually to water. The change was less with acetonitrile/water mixtures, and the difference is probably due to differences in ion solvation.

  DOI：

  10.1021/j100187a032
• 作为产物：
  描述：

  3-ethyl-3-chloro-2-methyl-pentane 在 potassium carbonate 作用下， 生成 3-乙基-2-甲基-1-戊烯
  参考文献：
  名称：

  Grigorowitsch; Pawlow, Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, 1891, vol. 23, p. 169

  摘要：

  DOI：

文献信息

• Stetter,H.; Tresper,E., Chemische Berichte, 1971, vol. 104, p. 71 - 74
  作者：Stetter,H.、Tresper,E.

  DOI：——

  日期：——
• Buck et al., Journal of the Institute of Petroleum, 1949, vol. 35, p. 648
  作者：Buck et al.

  DOI：——

  日期：——
• Halomethyl-metal compounds. XIII. Preparation of gem-difluorocyclopropanes by iodide ion-induced CF2 transfer from trimethyl(trifluoromethyl)tin
  作者：Dietmar Seyferth、Hadwig Dertouzos、Reiichi Suzuki、Jeffrey Y. P. Mui

  DOI：10.1021/jo01285a011

  日期：1967.10
• Localization of excitation energy in chemically activated systems. 3-Ethyl-2-methyl-2-pentyl radicals
  作者：M. C. Flowers、B. S. Rabinovitch

  DOI：10.1021/j100250a003

  日期：1985.2
• Olefin synthesis by vanadium(V)-induced oxidative decarboxylation-deoxygenation of 3-hydroxy carboxylic acids
  作者：Ingrid K. Meier、Jeffrey Schwartz

  DOI：10.1021/jo00308a021

  日期：1990.10

表征谱图