3-(octyloxy)thiophene | 132643-20-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-(octyloxy)thiophene
• 英文别名: 3-Octyloxythiophene；3-octoxythiophene
• CAS: 132643-20-0
• 化学式: C₁₂H₂₀OS
• 分子量: 212.356
• InChiKey: AUVZKIJQGLYISA-UHFFFAOYSA-N

物化性质

• 沸点：
  285.8±13.0 °C(Predicted)
• 密度：
  0.972±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  14
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  37.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-(octyloxy)thiophene 在 N-溴代丁二酰亚胺(NBS) 作用下， 生成 2,5-dibromo-3-octyloxythiophene
  参考文献：
  名称：

  Stability of a Conductive State of Poly(3-alkoxythiophene)s

  摘要：

  将碘掺杂聚（3-辛氧基噻吩）（P3OOT）与聚（3-辛基噻吩）（P3OT）的导电状态的稳定性进行了比较。掺杂后 P3OOT 电导率的时间衰减比 P3OT 慢得多。P3OOT 的阳离子很稳定，没有观察到自旋浓度的增加。这些结果支持作者提出的聚(3-烷基噻吩)的掺杂机理[J. Phys. Chem. B2005, 109, 15288]：掺杂是通过阳离子的去质子化进行的，从而形成稳定的聚烯基。P3OOT 的阳离子很难发生去质子化，因为去质子化会产生不稳定的自由基。因此，P3OOT 的导电状态是稳定的。

  DOI：

  10.1246/bcsj.82.202
• 作为产物：
  描述：

  3-甲氧基噻吩 、 辛醇 在 sodium hydrogen sulfate 作用下， 生成 3-(octyloxy)thiophene
  参考文献：
  名称：

  Stability of a Conductive State of Poly(3-alkoxythiophene)s

  摘要：

  将碘掺杂聚（3-辛氧基噻吩）（P3OOT）与聚（3-辛基噻吩）（P3OT）的导电状态的稳定性进行了比较。掺杂后 P3OOT 电导率的时间衰减比 P3OT 慢得多。P3OOT 的阳离子很稳定，没有观察到自旋浓度的增加。这些结果支持作者提出的聚(3-烷基噻吩)的掺杂机理[J. Phys. Chem. B2005, 109, 15288]：掺杂是通过阳离子的去质子化进行的，从而形成稳定的聚烯基。P3OOT 的阳离子很难发生去质子化，因为去质子化会产生不稳定的自由基。因此，P3OOT 的导电状态是稳定的。

  DOI：

  10.1246/bcsj.82.202

文献信息

• Organometallic Complex, and Light-Emitting Element, Light-Emitting Device, and Electronic Device Using the Organometallic Complex
  申请人：Inoue Hideko

  公开号：US20080312437A1

  公开（公告）日：2008-12-18

  According to the present invention, a wider variation of organometallic complexes that can emit phosphorescence can be provided by applying, as a ligand, an organic compound from which a variety of derivatives can be easily synthesized. In particular, an organometallic complex having a sharp emission spectrum is provided. Further, an organometallic complex having high emission efficiency is provided. An organometallic complex represented by the general formula (G1) is provided. In the formula, Ar represents an aryl group, R represents an alkoxy group having 1 to 4 carbon atoms, and R 1 and R 2 individually represent either hydrogen or an alkyl group having 1 to 4 carbon atoms.

  根据本发明，通过应用一种作为配体的有机化合物，可以提供更广泛的能够发射磷光的有机金属配合物变体，从而可以轻松合成各种衍生物。特别地，提供了具有尖锐发射光谱的有机金属配合物。此外，提供了具有高发射效率的有机金属配合物。提供了由通式（G1）表示的有机金属配合物。在该式中，Ar代表芳基，R代表具有1至4个碳原子的烷氧基，R1和R2分别表示氢或具有1至4个碳原子的烷基。
• [EN] NARROW ABSORPTION POLYMER NANOPARTICLES AND RELATED METHODS<br/>[FR] NANOPARTICULES DE POLYMÈRES À ABSORPTION ÉTROITE ET PROCÉDÉS ASSOCIÉS
  申请人：UNIV WASHINGTON

  公开号：WO2020060937A1

  公开（公告）日：2020-03-26

  Polymers, monomers, narrow-band absorbing polymers, narrow-band absorbing monomers, absorbing units, polymer dots, and related methods are provided. Bright, luminescent polymer nanoparticles with narrow-band absorptions are provided. Methods for synthesizing absorbing monomers, methods for synthesizing the polymers, preparation methods for forming the polymer nanoparticles, and applications for using the polymer nanoparticles are also provided.

  提供了聚合物、单体、窄带吸收聚合物、窄带吸收单体、吸收单元、聚合物点以及相关方法。提供了具有窄带吸收的明亮、发光的聚合物纳米颗粒。还提供了合成吸收单体的方法、合成聚合物的方法、形成聚合物纳米颗粒的制备方法，以及使用聚合物纳米颗粒的应用。
• Acenaphthopyridine Derivative, Material of Light-Emitting Element, Light-Emitting Element, Light-Emitting Device, and Electronic Appliance
  申请人：Takasu Takako

  公开号：US20090247753A1

  公开（公告）日：2009-10-01

  It is an object to provide a new compound which is suitable for a material of an electron-transporting layer of a light-emitting element. In particular, it is an object to provide a compound which can be used for forming a light-emitting element capable of emitting light at a low drive voltage. An acenaphthopyridine derivative represented by the following general formula (G1) is provided. In the formula, Het represents a pyridyl group or a quinolyl group.

  提供一种适用于发光元件电子传输层材料的新化合物是一个目标。特别是，提供一种可用于形成能够以低驱动电压发光的发光元件的化合物是一个目标。提供了以下一般式（G1）所代表的一种蒽醌吡啶衍生物。在该式中，Het代表吡啶基团或喹啉基团。
• WATER-SOLUBLE COMPOSITION, PRODUCTION METHOD FOR CURED PRODUCT THEREOF, AND CURED PRODUCT THEREOF, AND ACYL PHOSPHINATE
  申请人：ADEKA CORPORATION

  公开号：US20200032021A1

  公开（公告）日：2020-01-30

  Provided are: a water-soluble composition which has excellent storage stability and is adaptable to a wide range of light sources and capable of forming a highly fine pattern; a method of producing a cured product of the same; a cured product of the same; and an acylphosphinate. The water-soluble composition contains: an acylphosphinate (A) represented by Formula (I) below, wherein X 1 represents an aryl group having 6 to 15 carbon atoms; X 2 represents a linear alkyl group having 1 to 8 carbon atoms or the like; A m+ represents an alkali metal ion or the like; and m represents a number of 1 to 3; and a compound (B) having a group represented by Formula (II) below, wherein R 1 represents a hydrogen atom or the like; Z 1 represents an oxygen atom or the like; R 2 represents a hydrogen atom or the like; Z 2 represents an alkylene group having 1 to 6 carbon atoms; n represents a number of 0 to 30; * means a bond; and, when the compound (B) has plural groups represented by Formula (II), plural R 1′ s, Z 1′ s, Z 2′ s and n's are each optionally the same or different.

  提供了以下内容：一种水溶性组合物，具有优异的储存稳定性，适用于广泛的光源，并能形成高度精细的图案；一种制备该固化产品的方法；一种该固化产品；以及一种酰基膦酸酯。水溶性组合物包含：由下式（I）表示的酰基膦酸酯（A），其中X1表示具有6到15个碳原子的芳基基团；X2表示具有1到8个碳原子的线性烷基基团或类似物；Am+表示碱金属离子或类似物；m表示1到3的数字；以及具有下式（II）表示的基团的化合物（B），其中R1表示氢原子或类似物；Z1表示氧原子或类似物；R2表示氢原子或类似物；Z2表示具有1到6个碳原子的烷基基团；n表示0到30的数字；*表示一个键；当化合物（B）具有由式（II）表示的多个基团时，多个R1'、Z1'、Z2'和n'可以是任意相同或不同。
• Organometallic Complex, and Light-Emitting Material, Light-Emitting Element, Light-Emitting Device and Electronic Device
  申请人：Inoue Hideko

  公开号：US20080305361A1

  公开（公告）日：2008-12-11

  The present invention provides a novel organometallic complex which emits green phosphorescence so as to enrich variations of phosphorescent materials for green color which is one of three primary colors. An organometallic complex comprising a structure represented by a general formula (G1) is provided. In the formula, R 1 represents an alkyl group having 1 to 4 carbon atoms, and R 2 and R 3 individually represent hydrogen or an alkyl group having 1 to 4 carbon atoms. In addition, R 4 to R 7 individually represent an electron-withdrawing group, hydrogen or an alkyl group having 1 to 4 carbon atoms. Note that at least one of R 4 to R 7 represents an electron-withdrawing group. In addition, M is a central metal and represents either an element belonging to Group 9 in the periodic table or an element belonging to Group 10 in the periodic table.

  本发明提供了一种新型的有机金属配合物，其发出绿色荧光，以丰富绿色荧光材料的变化，这是三原色之一。提供一种由通式（G1）所表示的结构的有机金属配合物。在该式中，R1表示1至4个碳原子的烷基基团，而R2和R3各自表示氢或具有1至4个碳原子的烷基基团。此外，R4至R7各自表示带电子吸引基团、氢或具有1至4个碳原子的烷基基团。注意，至少有一个R4至R7表示带电子吸引基团。此外，M是中心金属，表示周期表中属于第9族或第10族元素。