2-(2,6-diisopropylphenylthio)benzenamine | 872513-59-2

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 2-(2,6-diisopropylphenylthio)benzenamine
• 英文别名: 2-{[2,6-Di(propan-2-yl)phenyl]sulfanyl}aniline；2-[2,6-di(propan-2-yl)phenyl]sulfanylaniline
• CAS: 872513-59-2
• 化学式: C₁₈H₂₃NS
• 分子量: 285.453
• InChiKey: AUGQKFWNTJGTLJ-UHFFFAOYSA-N

物化性质

• 沸点：
  347.7±42.0 °C(Predicted)
• 密度：
  1.07±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  20
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  51.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-(2,6-diisopropylphenylthio)benzenamine 在 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 以48%的产率得到2-((2,6-diisopropylphenyl)sulfinyl)aniline
  参考文献：
  名称：

  Synthesis and characterization of titanium complexes bearing sulfoxide groups and their catalytic behaviors in ethylene homo- and copolymerization

  摘要：

  设计并合成了源自 2,4- 二叔丁基-6-((2-(芳基亚磺酰基)苯基亚氨基)甲基)苯酚的钛配合物。X 射线衍射研究显示，这些配合物采用扭曲的八面体几何结构，O（苯酚）、N（亚胺）和 O（亚砜）与钛配位。这些配合物与改性甲基铝氧烷（MMAO）结合在一起，显示出中等到较高的活性，即使在 120 ℃、1 个大气压的乙烯压力下也能生成聚乙烯。这些配合物在乙烯与 1-己烯或降冰片烯的共聚中也表现出卓越的能力。结果表明，亚砜基团的引入可以打开中心金属周围的空间，有利于大体积共聚物的插入。

  DOI：

  10.1007/s11426-014-5137-4
• 作为产物：
  描述：

  丙泊酚 在 lithium aluminium tetrahydride 、 sodium hydride 、 potassium hydroxide 、 锌 作用下， 以 乙二醇二甲醚 、 乙醇 、 溶剂黄146 、 二甲基亚砜 、 N,N-二甲基甲酰胺 为溶剂， 生成 2-(2,6-diisopropylphenylthio)benzenamine
  参考文献：
  名称：

  Synthesis and characterization of titanium complexes bearing sulfoxide groups and their catalytic behaviors in ethylene homo- and copolymerization

  摘要：

  设计并合成了源自 2,4- 二叔丁基-6-((2-(芳基亚磺酰基)苯基亚氨基)甲基)苯酚的钛配合物。X 射线衍射研究显示，这些配合物采用扭曲的八面体几何结构，O（苯酚）、N（亚胺）和 O（亚砜）与钛配位。这些配合物与改性甲基铝氧烷（MMAO）结合在一起，显示出中等到较高的活性，即使在 120 ℃、1 个大气压的乙烯压力下也能生成聚乙烯。这些配合物在乙烯与 1-己烯或降冰片烯的共聚中也表现出卓越的能力。结果表明，亚砜基团的引入可以打开中心金属周围的空间，有利于大体积共聚物的插入。

  DOI：

  10.1007/s11426-014-5137-4

文献信息

• ORGANIC COMPOUNDS CONTAINING HETEROATOMS AND THEIR USE IN ZIEGLER-NATTA CATALYST WITH SINGLE ACTIVATION CENTER
  申请人：SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY, CHINESE ACADEMY OF SCIENCES

  公开号：EP2039677A1

  公开（公告）日：2009-03-25

  Organic compounds containing heteroatoms and their use in preparing Ziegler-Natta (Z-N) catalyst with single activation center. The Z-N olefin polymerization catalyst is prepared by adding organic or inorganic solid carrier or compound of them which is pre-activated by heating or pre-treated chemically, organic compound containing heteroatoms and metallic compound into magnesium compound/tetrahydrofuran solution. The Z-N olefin polymerization catalyst prepared in the present invention is fluidizable powder and can prepare ethene homopolymer and copolymer of controllable construction with high catalytic activity, during homo-polymerization and combined polymerization with alpha-olefin of C3-C8 under action of catalyst promoter such as alkyl aluminium, alkyl aluminoxane, and so on.

  含有杂原子的有机化合物及其在制备具有单活化中心的齐格勒-纳塔（Z-N）催化剂中的应用。Z-N 烯烃聚合催化剂的制备方法是在镁化合物/四氢呋喃溶液中加入经加热预活化或化学预处理的有机或无机固体载体或它们的化合物、含杂原子的有机化合物和金属化合物。本发明制备的 Z-N 烯烃聚合催化剂为可流动粉末，在烷基铝、烷基铝氧烷等催化剂促进剂的作用下，与 C3-C8 α-烯烃进行均聚和联合聚合时，可制备结构可控、催化活性高的乙烯均聚物和共聚物。
• Organic compounds containing heteroatoms and their use in ziegler-natta catalyst with single activation center
  申请人：SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY, CHINESE ACADEMY OF SCIENCES

  公开号：EP2039677B1

  公开（公告）日：2014-04-23
• CLASS OF ORGANIC COMPOUNDS CONTAINING HETEROATOM AND ITS APPLICATIONS IN PREPARING SINGLE-SITE ZIEGLER-NATTA CATALYST
  申请人：TANG Yong

  公开号：US20090137383A1

  公开（公告）日：2009-05-28

  Organic compounds containing heteroatoms and their use in preparing Ziegler-Natta (Ziegler-Natta) catalyst with single activation center. The Ziegler-Natta olefin polymerization catalyst is preparing by adding organic or inorganic solid carrier or compound of them which is pre-activated by heating or pre-treated chemically, organic compound containing heteroatoms and metallic compound into magnesium compound/tetrahydrofuran solution. The Ziegler-Natta olefin polymerization catalyst prepared in the present invention is fluidizable powder and can prepare ethene homopolymer and copolymer of controllable construction with high catalytic activity, during homo-polymerization and combined polymerization with alpha-olefin of C 3 ˜C 18 under action of catalyst promoter such as alkyl aluminum, alkyl aluminoxane, and so on.
• Synthesis and characterization of titanium complexes bearing sulfoxide groups and their catalytic behaviors in ethylene homo- and copolymerization
  作者：Zheng Wang、Ai-Qing Peng、Xiu-Li Sun、Yong Tang

  DOI：10.1007/s11426-014-5137-4

  日期：2014.8

  Titanium complexes derived from 2,4-di-tert-butyl-6-((2-(arylsulfinyl)phenylimino)methyl)phenol are designed and synthesized. X-ray diffraction studies reveal that the complexes adopt distorted octahedral geometry with O(phenol), N(imine), and O(sulfoxide) coordinated with titanium. Combined with modified methylaluminoxane(MMAO), the complexes exhibit moderate to high activity to afford polyethylene even at 120 °C under 1 atm ethylene pressure. The complexes also show excellent capability in copolymerization of ethylene with either 1-hexene or norbornene. Results indicate that the introduction of sulfoxide groups could open the space around central metal and favors the insertion of bulky comonomers.

  设计并合成了源自 2,4- 二叔丁基-6-((2-(芳基亚磺酰基)苯基亚氨基)甲基)苯酚的钛配合物。X 射线衍射研究显示，这些配合物采用扭曲的八面体几何结构，O（苯酚）、N（亚胺）和 O（亚砜）与钛配位。这些配合物与改性甲基铝氧烷（MMAO）结合在一起，显示出中等到较高的活性，即使在 120 ℃、1 个大气压的乙烯压力下也能生成聚乙烯。这些配合物在乙烯与 1-己烯或降冰片烯的共聚中也表现出卓越的能力。结果表明，亚砜基团的引入可以打开中心金属周围的空间，有利于大体积共聚物的插入。