| 1159426-92-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物
• CAS: 1159426-92-2；141216-32-2
• 化学式: C₁₂H₂₄N₄O₁₂P₄*Ce
• 分子量: 680.357
• InChiKey: JTPIDGWHKHXMSB-UHFFFAOYSA-F

计算性质

• 辛醇/水分配系数(LogP)：
  -7.31
• 重原子数：
  33.0
• 可旋转键数：
  8.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  265.72
• 氢给体数：
  0.0
• 氢受体数：
  16.0

反应信息

• 作为反应物：
  描述：

  以 高氯酸 为溶剂， 生成 氢化铈 (CeH3)
  参考文献：
  名称：

  Dissociation kinetics study of Ce(III) complexes with H8dotp (H8dotp = 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetrakis (methylphosphonic acid))

  摘要：

  The dissociation kinetics of cerium(III) complexes with H(8)dotp (I = 3.0 mol dm(-3) (Na,H)ClO4, t = 25-60 degrees C) was studied by means of molecular absorption spectroscopy in the UV region. The mechanism of the proton-assisted reaction was proposed, and the activation parameters (E-a = 111 +/- 20kJ mol(-1), Delta H-not equal = 108 +/- 20kJ mol(-1), Delta S-not equal = 32 +/- 62J K-1 mol(-1)) for the rate-determining step were calculated. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jallcom.2007.04.052
• 作为产物：
  描述：

  cerium(III) oxide 、 1,4,7,10-四氮杂环十二烷-1,4,7,10-四(甲基膦酸) 在 sodium hydroxide 作用下， 以 水 为溶剂， 生成
  参考文献：
  名称：

  Dissociation kinetics study of Ce(III) complexes with H8dotp (H8dotp = 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetrakis (methylphosphonic acid))

  摘要：

  The dissociation kinetics of cerium(III) complexes with H(8)dotp (I = 3.0 mol dm(-3) (Na,H)ClO4, t = 25-60 degrees C) was studied by means of molecular absorption spectroscopy in the UV region. The mechanism of the proton-assisted reaction was proposed, and the activation parameters (E-a = 111 +/- 20kJ mol(-1), Delta H-not equal = 108 +/- 20kJ mol(-1), Delta S-not equal = 32 +/- 62J K-1 mol(-1)) for the rate-determining step were calculated. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jallcom.2007.04.052

文献信息

• 31P and 23Na NMR lanthanide induced shifts in axially symmetric macrocyclic phosphonate complexes
  作者：A. Dean Sherry、C.F.G.C. Geraldes、W.P. Cacheris

  DOI：10.1016/s0020-1693(00)84059-1

  日期：1987.12