1,3,5-triphenyl-2-chloropentane-1,5-dione | 136285-74-0

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物
• 英文名称: 1,3,5-triphenyl-2-chloropentane-1,5-dione
• 英文别名: 1,3,5-triphenyl-2-chloro-1,5-pentanedione；2-Chloro-1,3,5-triphenyl-1,5-pentanedione；2-chloro-1,3,5-triphenylpentane-1,5-dione
• CAS: 136285-74-0
• 化学式: C₂₃H₁₉ClO₂
• 分子量: 362.856
• InChiKey: QGFVUWCSRRBBHR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  26
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,3,5-triphenyl-2-chloropentane-1,5-dione 以 乙醇 、 溶剂黄146 为溶剂， 反应 15.0h， 生成 2,4,6-triphenyl-3-benzoyl-2,3,4,5-tetrahydropyridazine
  参考文献：
  名称：

  Transformations of stereoisomeric 2-chloro-3-R-pentane-1,5-diones in reaction with phenylhydrazine

  摘要：

  Monophenylhydrazones were prepared from three monochloro derivatives of arylaliphatic 1,5-diketones, and some their transformations were investigated. The monophenyihydrazones formed regiospecifically, and the direction of the reaction was governed by the substituent attached to C-3 atom in the initial chlorodiketones. C Formerly unknown products of transformations suffered by monophenylhydrazones obtained were described: 2-amino-1,3-diphenyl-3-(2-phenylindolyl-3)-propan-1-one, 3-benzoyl-2,4,6-triphenl-2,3,4,5-tetrahydropyridazine, and 3-methyl-1,5-diphenyl-5-phenylazopent-4-en-1-one.

  DOI：

  10.1134/s1070428007020108
• 作为产物：
  描述：

  1,3,5-三苯基-1,5-戊二酮 在 (二氯碘)-苯 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 以70%的产率得到1,3,5-triphenyl-2-chloropentane-1,5-dione
  参考文献：
  名称：

  Moskovkina, T. V.; Vysotskii, V. I., Journal of Organic Chemistry USSR (English Translation), 1991, vol. 27, # 4, p. 717 - 719

  摘要：

  DOI：

文献信息

• Moskovkina, T. V.; Vysotskii, V. I., Journal of Organic Chemistry USSR (English Translation), 1991, vol. 27, # 4, p. 717 - 719
  作者：Moskovkina, T. V.、Vysotskii, V. I.

  DOI：——

  日期：——
• XARCHENKO, V. G.;CHALAYA, S. N.;LITVINOVA, O. V.;PCHELINTSEVA, N. V., SINTEZ HOB. POLITSIKLICH. I GETEROTSIKLICH. SOED., KUJBYSHEV,(1989) S. 85+
  作者：XARCHENKO, V. G.、CHALAYA, S. N.、LITVINOVA, O. V.、PCHELINTSEVA, N. V.

  DOI：——

  日期：——
• MOSKOVKINA, T. V.;VYSOTSKIJ, V. I., ZH. ORGAN. XIMII, 27,(1991) N, S. 833-836
  作者：MOSKOVKINA, T. V.、VYSOTSKIJ, V. I.

  DOI：——

  日期：——
• Moskovkina, T. V.; Vysotskii, V. I., Russian Journal of Organic Chemistry, 1994, vol. 30, # 7.1, p. 1052 - 1054
  作者：Moskovkina, T. V.、Vysotskii, V. I.

  DOI：——

  日期：——
• Transformations of stereoisomeric 2-chloro-3-R-pentane-1,5-diones in reaction with phenylhydrazine
  作者：T. V. Moskovkina、A. I. Kalinovskii

  DOI：10.1134/s1070428007020108

  日期：2007.2

  Monophenylhydrazones were prepared from three monochloro derivatives of arylaliphatic 1,5-diketones, and some their transformations were investigated. The monophenyihydrazones formed regiospecifically, and the direction of the reaction was governed by the substituent attached to C-3 atom in the initial chlorodiketones. C Formerly unknown products of transformations suffered by monophenylhydrazones obtained were described: 2-amino-1,3-diphenyl-3-(2-phenylindolyl-3)-propan-1-one, 3-benzoyl-2,4,6-triphenl-2,3,4,5-tetrahydropyridazine, and 3-methyl-1,5-diphenyl-5-phenylazopent-4-en-1-one.