(-)-bornyl acetate

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (-)-bornyl acetate
• 英文别名: Isobomyl acetate；[(1R,2R,4S)-1,7,7-trimethyl-2-bicyclo[2.2.1]heptanyl] acetate
• 化学式: C₁₂H₂₀O₂
• 分子量: 196.29
• InChiKey: KGEKLUUHTZCSIP-UMNHJUIQSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (-)-bornyl acetate 在 tetrakis(tetrabutylammonium)decatungstate(VI) 、 碳酸氢钠 、 N-氟代双苯磺酰胺 作用下， 以 乙腈 为溶剂， 反应 17.0h， 以56%的产率得到(5S)-5-fluorobornyl acetate
  参考文献：
  名称：

  一种方便的未活化C ？的光催化氟化反应 H债券

  摘要：

  氟化反应是现代药物化学必不可少的，因此提供了一种手段来阻止药物的定点代谢降解，并为正电子发射断层扫描成像提供放射性示踪剂的访问。尽管目前在氟化试剂和方法中已经很复杂，但是未活化的CH键的氟化仍然是一个巨大的挑战。本文报道的为未活化的C直接氟化的便利和经济的方法可以利用该夺氢一decatungstate光催化剂的能力结合温和的氟原子转移试剂H键Ñ-氟苯磺酰亚胺。这种操作简单的反应可直接进入各种氟化有机分子，包括结构复杂的天然产物，酰基氟和氟化氨基酸衍生物。

  DOI：

  10.1002/anie.201400420

文献信息

• Encapsulates
  申请人：Procter & Gamble International Operations SA

  公开号：US10947483B2

  公开（公告）日：2021-03-16

  The present application relates processes that can be used to produce encapsulated benefit agents comprising a core and a shell that encapsulates said core, encapsulated benefit agents produced by such process and products comprising such encapsulated benefit agents as well as methods of making and using such products. Such process can be used to produce particles that offer the desired protection and release benefits when used in a varity of products.

  本申请涉及可用于生产由核心和封装所述核心的外壳组成的胶囊化益处剂的工艺、由此类工艺生产的胶囊化益处剂和包含此类胶囊化益处剂的产品以及制造和使用此类产品的方法。这种工艺可用于生产在各种产品中使用时能提供所需的保护和释放益处的颗粒。
• COMPOSITION COMPRISING MULTIPLE POPULATIONS OF MICROCAPSULES COMPRISING PERFUME
  申请人：The Procter & Gamble Company

  公开号：EP3316854B1

  公开（公告）日：2019-07-31
• PARTICLES COMPRISING VOLATILE MATERIALS AND PARTICLE GAS SATURATED SOLUTION PROCESSES FOR MAKING SAME
  申请人：Rauckhorst Holly Balasubramanian

  公开号：US20120258150A1

  公开（公告）日：2012-10-11

  Particles containing a polymer and a volatile material, such as a perfume, and particle gas saturated solution (PGSS) processes for making such particles are provided.
• Compositions Containing Multiple Populations of Microcapsules
  申请人：The Procter & Gamble Company

  公开号：US20170002293A1

  公开（公告）日：2017-01-05

  A consumer product including a personal care composition providing multiple blooms of fragrance, the multiple blooms being provided for by different populations of microcapsules.
• Dispensers For Dispensing Microcapsules
  申请人：The Procter & Gamble Company

  公开号：US20170065995A1

  公开（公告）日：2017-03-09

  A dispenser for applying at least two compositions, the dispenser including at least two reservoirs for storing the at least two compositions separately, at least two pumps for pumping the at least two compositions, an optional premix chamber for mixing the two compositions before dispensing, at least two channels for delivering the compositions from the reservoirs to the premix chamber or swirl chamber, an exit orifice, an actuator, and a lever assembly for reducing the actuation force required to activate the two pumps; wherein the first composition includes microcapsules and the second composition includes a volatile solvent.