Tricyclodecanedimethanol | 68398-16-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: Tricyclodecanedimethanol
• 英文别名: [8-(hydroxymethyl)-3-tricyclo[5.2.1.02,6]decanyl]methanol
• CAS: 68398-16-3
• 化学式: C₁₂H₂₀O₂
• 分子量: 196.29
• InChiKey: OTLDLKLSNZMTTA-UHFFFAOYSA-N

物化性质

• LogP：
  1.617 (est)

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Tricyclodecanedimethanol 、 己二酸 生成 6-[[8-(5-carboxypentanoyloxymethyl)-3-tricyclo[5.2.1.02,6]decanyl]methoxy]-6-oxohexanoic acid
  参考文献：
  名称：

  ORLOWSKI, J. A.;BUTLER, D. V.;KIDD, P. D.

  摘要：

  DOI：

文献信息

• ALKALI-DEVELOPABLE PHOTOSENSITIVE RESIN COMPOSITION AND BETA-DIKETONE COMPOUND
  申请人：Yamada Takashi

  公开号：US20100129753A1

  公开（公告）日：2010-05-27

  An alkali developable photosensitive resin composition contains (J) a photopolymerizable unsaturated compound having a structure resulting from the addition reaction of (B) a compound having a β-diketone moiety or a compound having a β-ketoester group to the (meth)acryloyl group of (A) a compound having at least two (meth)acryloyl groups and a hydroxyl group and subsequent esterification of the hydroxyl group of the resulting addition product with (C) a polybasic acid anhydride. The compound having a β-diketone moiety is preferably a novel β-diketone compound represented by general formula (I): wherein R 1 is a C1-C20 alkyl group; R 2 represents R 11 , OR 11 , COR 11 , SR 11 , CONR 12 R 13 , or CN; R 11 , R 12 , and R 13 are each hydrogen, a C1-C20 alkyl group, etc.; a is 0 to 3; and b is 0 to 4.

  一种可由碱显影的光敏树脂组合物，含有（J）一种光聚合不饱和化合物，该化合物的结构是由（B）含β-二酮基团或含β-酮酯基团的化合物与（A）含至少两个(甲基)丙烯酰基团和一个羟基的化合物中的(甲基)丙烯酰基团发生加成反应，并随后将所得加成产物的羟基与（C）多元酸酐进行酯化反应得到的。含β-二酮基团的化合物最好是表示为通用公式（I）的一种新型β-二酮化合物：其中R1是C1-C20烷基团；R2代表R11、OR11、COR11、SR11、CONR12R13或CN；R11、R12和R13分别是氢、C1-C20烷基团等；a是0到3；b是0到4。
• Fluoropolymer coating compositions with olefinic silanes for anti-reflective polymer films
  申请人：Jing Naiyong

  公开号：US20060147177A1

  公开（公告）日：2006-07-06

  An economic, optically transmissive, stain and ink repellent, durable low refractive index fluoropolymer composition for use in an antireflection film or coupled to an optical display. In one aspect of the invention, the composition is formed from the reaction product of a fluoropolymer, a C═C double bond group containing silane ester agent, and an optional multi-olefinic crosslinker. In another aspect of the invention, the composition further includes surface modified inorganic nanoparticles. In another aspect, the multi-olefinic crosslinker is an alkoxysilyl-containing multi-olefinic crosslinker.

  一种经济、光学透明、防污染和抗墨水的耐用低折射率氟聚合物组合物，用于制造防反射膜或与光学显示器耦合。在发明的一个方面，该组合物由氟聚合物、含有C═C双键基团的硅烷酯剂和可选的多烯交联剂的反应产物形成。在发明的另一个方面，该组合物进一步包括表面改性的无机纳米颗粒。在另一个方面，多烯交联剂是含有烷氧基基团的多烯交联剂。
• Low refractive index fluoropolymer coating compositions for use in antireflective polymer films
  申请人：Jing Naiyong

  公开号：US20060147723A1

  公开（公告）日：2006-07-06

  An economic, optically transmissive, stain and ink repellent, durable low refractive index fluoropolymer composition for use in an antireflection film or coupled to an optical display. In one aspect of the invention, the composition is formed from the reaction product of a fluoropolymer or reactive fluoropolymer, an amino silane ester coupling agent or ester equivalent, a multi-olefinic crosslinker, and optional surface modified inorganic particles or sol gel precursors.

  一种经济、光学透明、防污染、耐用的低折射率氟聚合物组合物，用于用于抗反射膜或耦合到光学显示器中。在发明的一个方面，该组合物是由氟聚合物或反应性氟聚合物、氨基硅烷酯偶联剂或酯等效物、多烯交联剂以及可选的表面改性的无机颗粒或溶胶凝胶前体的反应产物形成的。
• Compound having silsesquioxane skeleton and its polymer
  申请人：Inagaki Jyun-ichi

  公开号：US20050009982A1

  公开（公告）日：2005-01-13

  The present invention relates to a compound represented by Formula (1) and a polymer obtained using the compound: wherein R 1 is phenyl which may have substituents, Q 1 is hydrogen, halogen, alkyl having 1 to 10 carbon atoms, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl or phenyl in which optional hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms, and Q 2 is a group represented by Formula (2) wherein the code < represents a bonding point with silicon, l, m, n and p are independently 0, 1, 2 or 3, A 1 to A 4 are independently a single bond, 1,4-cyclohexylene, 1,4-cyclohexenylene, a condensed ring group having 6 to 10 carbon atoms which is a divalent group, or 1,4-phenylene, Z 0 to Z 3 are independently a single bond, —CH═CR—, —C≡C—, —COO—, —OCO—, or alkylene having 1 to 20 carbon atoms, and Z 4 is a single bond, —CH═CH—, —C≡C—, —COO—, —OCO—, or alkylene having 1 to 20 carbon atoms. And Y 1 in Formula (1) is the group defined in Claim 1.

  本发明涉及一种由式（1）表示的化合物和使用该化合物获得的聚合物：其中R1是苯基，可能具有取代基；Q1是氢、卤素、具有1至10个碳原子的烷基、环丙基、环丁基、环戊基、环己基、环己烯基或苯基，其中可选的氢原子可被卤素或具有1至5个碳原子的烷基取代；Q2是由式（2）表示的基团，其中代码<表示与硅的连接点，l、m、n和p独立地为0、1、2或3，A1至A4独立地为单键、1,4-环己亚基、1,4-环己烯亚基、具有6至10个碳原子的缩合环基团，为二价基团，或1,4-苯亚基，Z0至Z3独立地为单键、—CH═CR—、—C≡C—、—COO—、—OCO—或具有1至20个碳原子的烷基，Z4为单键、—CH═CH—、—C≡C—、—COO—、—OCO—或具有1至20个碳原子的烷基。式（1）中的Y1是权利要求1中定义的基团。
• ACTIVE-ENERGY-RAY-POLYMERIZABLE INITIATOR, ACTIVE-ENERGY-RAY-POLYMERIZABLE COMPOSITION, ACTIVE-ENERGY-RAY-POLYMERIZABLE INK, INK STORAGE CONTAINER, IMAGE FORMING METHOD, AND IMAGE FORMING APPARATUS
  申请人：HARADA Shigeyuki

  公开号：US20200270469A1

  公开（公告）日：2020-08-27

  An active-energy-ray-polymerizable initiator having a structure represented by the following general formula (1) is provided. In general formula (1), L 1 represents —C(═O)—O— (binding to L 2 side) or —O—, L 2 represents —O(CH 2 ) p -(binding to L 1 side), —(OC 2 H 4 ) n -(binding to L 1 side), or —(OC 3 H 6 ) m -(binding to L 1 side), where p represents an integer of 2 to 16, n represents an integer of 2 to 12, and m represents 2 or 3, L 3 represents a direct binding or —NH—, L 4 represents —OC 2 H 4 -(binding to L 3 side) or —(OC 2 H 4 ) 2 -(binding to L 3 side), and R represents —H or —CH 3 .

  提供具有以下一般式（1）所代表的结构的活性能量射线可聚合引发剂。 在一般式（1）中，L1代表—C(═O)—O—（与L2侧结合）或—O—，L2代表—O(CH2)p-(与L1侧结合)，—(OC2H4)n-(与L1侧结合)，或—(OC3H6)m-(与L1侧结合)，其中p表示2到16的整数，n表示2到12的整数，m表示2或3，L3代表直接结合或—NH—，L4代表—OC2H4-(与L3侧结合)或—(OC2H4)2-(与L3侧结合)，R代表—H或—CH3。

表征谱图