methyl sarcophytoate | 129239-13-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: methyl sarcophytoate
• 英文别名: methyl (1S,2R,3R,8R,10E,14E,21R,22R,23E,27R)-2,3-dihydroxy-2,6,11,15,24,28-hexamethyl-9,16,19-trioxo-18-propan-2-yl-31-oxatetracyclo[25.3.1.05,22.08,21]hentriaconta-5,10,14,23,28-pentaene-21-carboxylate
• CAS: 129239-13-0
• 化学式: C₄₁H₅₈O₈
• 分子量: 678.907
• InChiKey: UNAARPYXKDMZJO-ZEFPOTGJSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  49
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.66
• 拓扑面积：
  127
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  methyl sarcophytoate 在 sodium tetrahydroborate 作用下， 以 甲醇 为溶剂， 反应 1.0h， 以1.8 mg的产率得到
  参考文献：
  名称：

  A novel chlorinated biscembranoid from the marine soft coral Sarcophyton glaucum

  摘要：

  Novel tetraterpenes 1 and 3 have been isolated from an Okinawan soft coral Sarcophyton glaucum and their structures have been deduced by means of spectroscopy and chemical transformation. Their carbon framework, presumably formed by Diels-Alder reaction of two cembranoids, has been found to be the same as that of methyl sartortuoate and methyl isosartortuoate.

  DOI：

  10.1021/jo00313a014

文献信息

• A novel chlorinated biscembranoid from the marine soft coral Sarcophyton glaucum
  作者：Takenori Kusumi、Morihiro Igari、Midori O. Ishitsuka、Akio Ichikawa、Yoshiko Itezono、Noboru Nakayama、Hiroshi Kakisawa

  DOI：10.1021/jo00313a014

  日期：1990.12

  Novel tetraterpenes 1 and 3 have been isolated from an Okinawan soft coral Sarcophyton glaucum and their structures have been deduced by means of spectroscopy and chemical transformation. Their carbon framework, presumably formed by Diels-Alder reaction of two cembranoids, has been found to be the same as that of methyl sartortuoate and methyl isosartortuoate.