2,6,6-trimethyl-2-heptene | 132462-53-4

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 2,6,6-trimethyl-2-heptene
• 英文别名: 2,6,6-Trimethylhept-2-ene
• CAS: 132462-53-4
• 化学式: C₁₀H₂₀
• 分子量: 140.269
• InChiKey: PJDUNKKHPCBOPA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  10
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  2,6,6-trimethyl-7-iodo-2-heptene 在 lithium aluminium tetrahydride 作用下， 以 四氢呋喃 为溶剂， 反应 48.0h， 生成 1-isopropyl-3,3-dimethylcyclopentane 、 2,6,6-trimethyl-2-heptene
  参考文献：
  名称：

  Concerning the mechanism of reaction of lithium aluminum hydride with alkyl halides

  摘要：

  A detailed study of the mechanism of reaction of LiAlH4 with alkyl halides has been carried out with special emphasis on the use of radical probes. The data presented strongly support the validity of using radical probes in this reaction as an indication of an electron-transfer process. These studies also suggest a radical chain process (hydrogen atom transfer) in addition to the halogen atom transfer process on which we reported earlier. Studies to determine the influence of impurities as well as a potential metal-halogen exchange process are also reported.

  DOI：

  10.1021/jo00004a047

文献信息

• Concerning the mechanism of reaction of lithium aluminum hydride with alkyl halides
  作者：E. C. Ashby、T. N. Pham、A. Amrollah-Madjdabadi

  DOI：10.1021/jo00004a047

  日期：1991.2

  A detailed study of the mechanism of reaction of LiAlH4 with alkyl halides has been carried out with special emphasis on the use of radical probes. The data presented strongly support the validity of using radical probes in this reaction as an indication of an electron-transfer process. These studies also suggest a radical chain process (hydrogen atom transfer) in addition to the halogen atom transfer process on which we reported earlier. Studies to determine the influence of impurities as well as a potential metal-halogen exchange process are also reported.