11-dotriacontyne

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 11-dotriacontyne
• 英文别名: Dotriacont-11-yne
• 化学式: C₃₂H₆₂
• 分子量: 446.844
• InChiKey: ABOXFZWIAOAKSF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.4
• 重原子数：
  32
• 可旋转键数：
  26
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  11-dotriacontyne 在 Pd-BaSO₄ 喹啉 、 氢气 作用下， 以 Petroleum ether 为溶剂， 生成 (Z)-Dotriacont-11-ene
  参考文献：
  名称：

  The Synthesis of Long Chain Dialkylalkynes, Dialkyldiynes and Their Hydrogenation to Monoenes and Dienes

  摘要：

  Long methylenic chain dialkylalkynes have been synthesised in high yield by an improved procedure. The methodology has been extended to nonconjugated diynes. Catalytic hydrogenation with a poisoned palladium catalyst affords cis-monoenes and cis,cis-dienes respectively. An improved synthesis of cis-9-tricosene is described.

  DOI：

  10.1080/00397919808006830
• 作为产物：
  描述：

  1-十二炔 、 溴代二十烷 在 正丁基锂 作用下， 生成 11-dotriacontyne
  参考文献：
  名称：

  The Synthesis of Long Chain Dialkylalkynes, Dialkyldiynes and Their Hydrogenation to Monoenes and Dienes

  摘要：

  Long methylenic chain dialkylalkynes have been synthesised in high yield by an improved procedure. The methodology has been extended to nonconjugated diynes. Catalytic hydrogenation with a poisoned palladium catalyst affords cis-monoenes and cis,cis-dienes respectively. An improved synthesis of cis-9-tricosene is described.

  DOI：

  10.1080/00397919808006830

文献信息

• The Synthesis of Long Chain Dialkylalkynes, Dialkyldiynes and Their Hydrogenation to Monoenes and Dienes
  作者：I. G. Fisher、J. H. P. Tyman

  DOI：10.1080/00397919808006830

  日期：1998.4

  Long methylenic chain dialkylalkynes have been synthesised in high yield by an improved procedure. The methodology has been extended to nonconjugated diynes. Catalytic hydrogenation with a poisoned palladium catalyst affords cis-monoenes and cis,cis-dienes respectively. An improved synthesis of cis-9-tricosene is described.