(E)-ethyl 3-(4-isobutylphenyl)acrylate

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 肉桂酸及其衍生物
• 英文名称: (E)-ethyl 3-(4-isobutylphenyl)acrylate
• 英文别名: Ethyl 3-(4-Isobutylphenyl)acrylate；ethyl (E)-3-[4-(2-methylpropyl)phenyl]prop-2-enoate
• 化学式: C₁₅H₂₀O₂
• 分子量: 232.323
• InChiKey: AVKJHNLUCYTIQE-MDZDMXLPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  17
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (E)-ethyl 3-(4-isobutylphenyl)acrylate 在 RuCl₂(2-(diphenylphosphino)-N-(2-(n-butylthio)ethyl)ethanamine)PPh₃ 、 potassium methanolate 、 氢气 作用下， 以 四氢呋喃 为溶剂， 105.0 ℃ 、5.0 MPa 条件下， 反应 16.0h， 以91%的产率得到3-(4-异丁基苯基)-1-丙醇
  参考文献：
  名称：

  IMPROVEMENTS IN OR RELATING TO ORGANIC COMPOUNDS

  摘要：

  在存在包含氮、硫和磷原子的三齿或双齿配体的过渡金属配合物的情况下，对含有碳杂原子双键的底物进行氢化的过程，其中至少N和P原子，以及可选地也包括S原子与过渡金属配体形成配位键。

  公开号：

  US20160326199A1

文献信息

• [EN] IMPROVEMENTS IN OR RELATING TO ORGANIC COMPOUNDS<br/>[FR] PERFECTIONNEMENTS APPORTÉS À DES COMPOSÉS ORGANIQUES OU EN RELATION AVEC CEUX-CI
  申请人：GIVAUDAN SA

  公开号：WO2015110515A1

  公开（公告）日：2015-07-30

  A process for the hydrogenation of a substrate comprising a carbon heteroatom double bond in the presence of a transition metal complex comprising a tridentate or bisdentate- ligand containing a nitrogen, sulphur and phosphorus atom, of which at least the N- and P- and optionally also the S-atom coordinates with the transition metal.

  在存在包含氮、硫和磷原子的三齿或双齿配体的过渡金属配合物的情况下，对含有碳杂原子双键的底物进行氢化的方法，其中至少N和P原子以及可选的S原子与过渡金属配位。
• ORGANIC COMPOUNDS
  申请人：GIVAUDAN SA

  公开号：US20180066003A1

  公开（公告）日：2018-03-08

  A process for the hydrogenation of a substrate comprising a carbon heteroatom double bond in the presence of a transition metal complex comprising a tridentate or bisdentate-ligand containing a nitrogen, sulphur and phosphorus atom, of which at least the N- and P- and optionally also the S-atom coordinates with the transition metal.
• LIQUID CRYSTAL POLYMERIZED FILMS USING ALIGNMENT FILM AND POLYMERIZABLE LIQUID CRYSTAL COMPOSTION
  申请人：JNC CORPORATION

  公开号：US20180163135A1

  公开（公告）日：2018-06-14

  Liquid crystal polymerization films, prepared by applying a polymerizable liquid crystal composition containing a polymerizable liquid crystal compound represented by formula (2) on an alignment film prepared by calcinating a composition containing a polymer represented by a repeating unit of formula (1), and subsequently polymerizing the polymerizable liquid crystal composition. In formula (1), R 1 is independently a tetravalent group, R 2 is independently a divalent functional group and R 3 is independently a hydrogen atom or a monovalent functional group. PG 1 -Sp 1 -R 4 -Sp 2 -PG 2 (2) In formula (2), R 4 represents a divalent group formed by combining five or more and nine or less of alicycles and/or aromatic rings, SP 1 and SP 2 represent a spacer group, and PG 1 and PG 2 represents an alkyl group, an alkoxyl group, a cyano group, fluorine or a polymerizable functional group, in which either group is the polymerizable functional group.
• IMPROVEMENTS IN OR RELATING TO ORGANIC COMPOUNDS
  申请人：GIVAUDAN SA

  公开号：US20160326199A1

  公开（公告）日：2016-11-10

  A process for the hydrogenation of a substrate comprising a carbon heteroatom double bond in the presence of a transition metal complex comprising a tridentate or bisdentate-ligand containing a nitrogen, sulphur and phosphorus atom, of which at least the N- and P- and optionally also the S-atom coordinates with the transition metal.

  在存在包含氮、硫和磷原子的三齿或双齿配体的过渡金属配合物的情况下，对含有碳杂原子双键的底物进行氢化的过程，其中至少N和P原子，以及可选地也包括S原子与过渡金属配体形成配位键。