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2-vinyloxymethylbicyclo[2.2.1]heptane

中文名称
——
中文别名
——
英文名称
2-vinyloxymethylbicyclo[2.2.1]heptane
英文别名
2-norbornanemethylvinyl ether;2-(Ethenoxymethyl)bicyclo[2.2.1]heptane
2-vinyloxymethylbicyclo[2.2.1]heptane化学式
CAS
——
化学式
C10H16O
mdl
——
分子量
152.236
InChiKey
BBYDMZZAXMLPJY-UHFFFAOYSA-N
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

计算性质

  • 辛醇/水分配系数(LogP):
    3.1
  • 重原子数:
    11
  • 可旋转键数:
    3
  • 环数:
    2.0
  • sp3杂化的碳原子比例:
    0.8
  • 拓扑面积:
    9.2
  • 氢给体数:
    0
  • 氢受体数:
    1

上下游信息

  • 上游原料
    中文名称 英文名称 CAS号 化学式 分子量
    2-降莰烷甲醇 exo-hydroxymethylnorbornane 5240-72-2 C8H14O 126.199

反应信息

  • 作为产物:
    描述:
    2-降莰烷甲醇乙烯基乙醚mercury(II) diacetate 作用下, 反应 48.0h, 以53%的产率得到2-vinyloxymethylbicyclo[2.2.1]heptane
    参考文献:
    名称:
    由四氟乙烯和大体积乙烯基酯或乙烯基醚组成的无定形含氟聚合物
    摘要:
    通过在有机溶剂中进行自由基聚合,可以高收率制备四氟乙烯(TFE)与乙烯基酯和具有金刚烷基或降冰片基侧链的乙烯基醚的共聚物。该聚合物是热稳定的,可溶于标准有机溶剂中,玻璃化转变温度比具有线性脂族侧链的相应共聚物要高出100℃以上。
    DOI:
    10.1016/s0022-1139(02)00205-1
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文献信息

  • Process for producing vinyl ether compounds
    申请人:——
    公开号:US20030083529A1
    公开(公告)日:2003-05-01
    A process produces vinyl ether compounds and includes allowing a vinyl ester compound represented by following Formula (1): 1 wherein R 1 , R 2 , R 3 and R 4 are the same or different and are each a hydrogen atom or an organic group, to react with a hydroxy compound represented by following Formula (2): R 5 OH  (2) wherein R 5 is an organic group, in the presence of at least one transition element compound to thereby yield a vinyl ether compound represented by following Formula (3): 2 wherein R 2 , R 3 , R 4 and R 5 have the same meanings as defined above. Such transition element compounds include iridium compounds and other compounds containing Group VIII elements.
    该过程生产乙烯醚化合物,包括使得由以下化学式(1)表示的乙烯酯化合物发生反应:其中R1、R2、R3和R4相同或不同,每个都是氢原子或有机基团,与由以下化学式(2)表示的羟基化合物反应:其中R5是有机基团,在至少一种过渡元素化合物存在下,从而产生由以下化学式(3)表示的乙烯醚化合物:其中R2、R3、R4和R5的含义与上述定义相同。这样的过渡元素化合物包括铱化合物和其他含有第VIII族元素的化合物。
  • CALIXARENE AND PHOTORESIST COMPOSITION COMPRISING SAME
    申请人:Rohm and Haas Electronic Materials LLC
    公开号:US20130078569A1
    公开(公告)日:2013-03-28
    A molecular glass compound comprises a vinyl ether adduct of an aromatic vinyl ether of formula C(R 1 ) 2 ═C(R 2 )—O-(L) n -Ar 1 , and a calix[4]arene, wherein R 1 and R 2 are each independently a single bond, H, C 1-20 alkyl, C 1-20 haloalkyl, C 6-20 aryl, C 6-20 haloaryl, C 7-20 aralkyl, or C 7-20 haloaralkyl, L is a C 1-20 linking group, n is 0 or 1, and Ar 1 is a halo-containing monocyclic, or substituted or unsubstituted polycyclic or fused polycyclic C 6-20 aromatic-containing moiety, wherein R 1 and R 2 are connected to Ar 1 when either or both of R 1 and R 2 is a single bond and n is 0. A photoresist, comprising the molecular glass compound, a solvent, and a photoacid generator, a coated substrate, comprising (a) a substrate having one or more layers to be patterned on a surface thereof; and (b) a layer of a photoresist composition over the one or more layers to be patterned, and a method of forming the molecular glass compound, are also disclosed.
    一种分子玻璃化合物包括芳香基乙烯醚的乙烯醚加合物,化学式为C(R1)2═C(R2)—O-(L)n-Ar1,以及一种杯芳烃[4],其中R1和R2分别独立为单键,H,C1-20烷基,C1-20卤代烷基,C6-20芳基,C6-20卤代芳基,C7-20芳基烷基,或C7-20卤代芳基烷基,L是C1-20连接基,n为0或1,Ar1是含卤素的单环芳基,或取代或未取代的多环或融合多环C6-20芳基结构,当R1和R2中的一个或两个为单键且n为0时,R1和R2与Ar1相连。此外,还公开了包括该分子玻璃化合物、溶剂和光酸发生剂的光阻剂,包括(a)具有一个或多个要在其表面上进行图案化的层的基板;和(b)覆盖在要进行图案化的一个或多个层上的光阻剂组合物层,以及形成该分子玻璃化合物的方法。
  • Polymerizable monomer polymeric compound resin compositions for photoresist and method for producing semiconductor
    申请人:Koyama Hiroshi
    公开号:US20060058480A1
    公开(公告)日:2006-03-16
    A polymerizable monomer of the present invention is represented by the following formula (1); R 1 , R 2 and R 3 are each a hydrogen atom, a fluorine atom, an alkyl group or a fluoroalkyl group, W is a single bond or a linkage group and n is 0 or 1, where at least one of R 1 , R 2 and R 3 is a fluorine atom or a fluoroalkyl group when n= 1; and the ring in the formula may have a substituent. The polymerizable monomer of the present invention can provide an appropriate hydrophilicity or hydrophilicity and transparency to a photoresist polymer.
    本发明的可聚合单体由以下公式(1)表示;其中,R1、R2和R3分别为氢原子、氟原子、烷基或氟烷基,W为单键或连接基,n为0或1,当n=1时,R1、R2和R3中至少有一个为氟原子或氟烷基;公式中的环可能具有取代基。本发明的可聚合单体能够为光刻胶聚合物提供适当的亲水性或亲疏水性和透明度。
  • Vinyl ether compounds and preparation process thereof
    申请人:Daicel Chemical Industries, Ltd.
    公开号:EP1288186A2
    公开(公告)日:2003-03-05
    A process produces vinyl ether compounds and includes allowing a vinyl ester compound represented by following Formula (1): wherein R1, R2, R3 and R4 are the same or different and are each a hydrogen atom or an organic group, to react with a hydroxy compound represented by following Formula (2):         R5OH     (2) wherein R5 is an organic group, in the presence of at least one transition element compound to thereby yield a vinyl ether compound represented by following Formula (3): wherein R2, R3, R4 and R5 have the same meanings as defined above. Such transition element compounds include iridium compounds and other compounds containing Group VIII elements. A vinyl ether compound represented by following Formula (4): wherein W is a divalent hydrocarbon; n is 0 or 1; m is an integer from 1 to 8; ring Z is any one of cyclic groups represented by following Formulae (5) through (12):
    一种生产乙烯基醚化合物的工艺,包括让下式(1)代表的乙烯基酯化合物与下式(2)代表的羟基化合物反应: 其中 R1、R2、R3 和 R4 相同或不同,且各自为氢原子或有机基团,与下式(2)所代表的羟基化合物反应: R5OH (2) 其中 R5 为有机基团,在至少一种过渡元素化合物存在的情况下,生成下式 (3) 所代表的乙烯基醚化合物: 其中 R2、R3、R4 和 R5 的含义与上述定义相同。此类过渡元素化合物包括铱化合物和其他含有第八族元素的化合物。 由下式(4)表示的乙烯基醚化合物: 其中 W 为二价烃;n 为 0 或 1;m 为 1 至 8 的整数;环 Z 为下式(5)至(12)所代表的任一环状基团:
  • Vinyl ether compounds
    申请人:DAICEL CHEMICAL INDUSTRIES, LTD.
    公开号:EP1826196A2
    公开(公告)日:2007-08-29
    A vinyl ether compound represent by following Formula (4): wherein ring Z is any one of cyclic groups represented by following Formulae (5) through (12): wherein X1, X2, X3, X4, X5, X6, X7, and X8 are each a substituent combined with an atom constituting each ring and are each a halogen atom, an alkyl group, a haloalkyl group, an aryl group, a hydroxyl group which may be protected by a protecting group, a hydroxymethyl group which may be protected by a protecting group, an amino group which may be protected by a protecting group, a carboxyl group which may be protected by a protecting group, a sulfo group which may be protected by a protecting group, an oxo group, a nitro group, a cyano group, or an acyl group which may be protected by a protecting group, wherein, when there are two or more substituents X1s, these X1s may be combined to form a ring containing four or more members with a carbon atom constituting the cyclohexane ring in Formula (5); a, b, c, d, e, f, g, and h are each an integer of 0 or more, wherein when a, b, c, d, 3, f, g or h is 2 or more, the substituents in the parentheses may be the same or different; and p, q, and r are each an integer of from 0 to 3; W is a divalent hydrocarbon group; R2, R3, and R4 are the same or different and are each a hydrogen atom or an organic group; n is 0 or 1; and m is an integer of from 1 to 8, wherein groups in the parentheses may be the same or different when m is 2 or more; wherein a in Formula (5) is 1 or more and b in Formula (6) is 1 or more when n is 0 and m is 1; and wherein c is 1 or more when p is 0 or 1, and X3 is a group other than hydroxyl group when p is 0 and c is 1 in Formula (7).
    乙烯基醚化合物,由下式(4)表示: 其中 环 Z 是下式(5)至(12)所代表的任何一个环状基团: 其中 X1、X2、X3、X4、X5、X6、X7 和 X8 各自是与构成各环的原子结合的取代基,并且各自是卤素原子、烷基、卤代烷基、芳基、可受保护基保护的羟基、可受保护基保护的羟甲基、可受保护基保护的氨基、可被保护基团保护的羧基、可被保护基团保护的磺基、氧代基团、硝基、氰基或可被保护基团保护的酰基,其中,当有两个或两个以上取代基 X1s 时,这些 X1s 可组合成一个包含四个或四个以上成员的环,其中一个碳原子构成式(5)中的环己烷环; a、b、c、d、e、f、g 和 h 各为 0 或 0 以上的整数,其中当 a、b、c、d、3、f、g 或 h 为 2 或 2 以上时,括号中的取代基可以相同或不同;以及 p、q 和 r 分别为 0 至 3 的整数; W 是二价烃基; R2、R3 和 R4 可以相同或不同,并且各自是氢原子或有机基团; n 是 0 或 1;以及 m 是 1 至 8 的整数、 当 m 为 2 或 2 以上时,括号中的基团可以相同或不同; 当 n 为 0 和 m 为 1 时,式(5)中的 a 为 1 或 1 以上,式(6)中的 b 为 1 或 1 以上;以及 其中当 p 为 0 或 1 时,式(7)中的 c 为 1 或 1 以上;当 p 为 0 和 c 为 1 时,式(7)中的 X3 为羟基以外的基团。
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