1,3-bis(norborn-2-ene-5-methoxy)propane

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,3-bis(norborn-2-ene-5-methoxy)propane
• 英文别名: 5-[3-(2-Bicyclo[2.2.1]hept-5-enylmethoxy)propoxymethyl]bicyclo[2.2.1]hept-2-ene
• 化学式: C₁₉H₂₈O₂
• 分子量: 288.43
• InChiKey: BEECMFIGOSZCLQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  21
• 可旋转键数：
  8
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1,3-二溴丙烷 、 5-降冰片烯-2-甲醇 在 四甲基氢氧化铵 作用下， 反应 10.0h， 以14%的产率得到1,3-bis(norborn-2-ene-5-methoxy)propane
  参考文献：
  名称：

  悬浮开环复分解聚合：降冰片烯基树脂的制备及其在有机合成中的应用

  摘要：

  通过水悬浮液开环复分解聚合（ROMP）获得了一系列的降冰片烯基树脂珠，并用作有机合成的聚合物载体。这些树脂由降冰片烯，降冰片烯-2-烯-5-甲醇和交联剂如双（降冰片烯-2-烯-5-甲氧基）烷烃，二（降冰片烯-2-烯-5-甲基）醚制备和1,3-二（降冰片-2-烯-5-甲氧基）苯。使用氢化，氢氟化，氯化和溴化反应对所得的包含烯烃重复单元的不饱和ROMP（U-ROMP）树脂进行化学改性，以生产具有不同化学和物理性质的饱和ROMP树脂。发现氢化的ROMP（H-ROMP）树脂对酸性，碱性，路易斯酸具有很高的抵抗力，和桦木还原条件，并被评估为一系列固相合成应用中的聚合物载体。发现H-ROMP树脂在芳族硝化和酰化反应中比聚苯乙烯-二乙烯基苯（PS-DVB）共聚物具有更好的性能。在乙内酰脲的常规五步固相合成中，对于H-ROMP和PS-DVB树脂都获得了相似的结果。还显示出U-ROMP树脂在苯并咪唑和苯并咪唑酮的固相合成中有效。

  DOI：

  10.1021/jo049827s

文献信息

• Optical waveguides and methods thereof
  申请人：Choki Koji

  公开号：US20070148566A1

  公开（公告）日：2007-06-28

  Embodiments in accordance with the present invention provide waveguide structures and methods of forming such structures where core and laterally adjacent cladding regions are defined. Some embodiments of the present invention provide waveguide structures where core regions are collectively surrounded by laterally adjacent cladding regions and cladding layers and methods of forming such structures.

  本发明实施例提供了波导结构和形成这种结构的方法，其中定义了核心和横向相邻的包层区域。本发明的某些实施例提供波导结构，其中核心区域被横向相邻的包层区域和包层层所包围，并提供形成这种结构的方法。
• OPTICAL WAVEGUIDES AND METHODS THEREOF
  申请人：Choki Koji

  公开号：US20100061688A1

  公开（公告）日：2010-03-11

  Embodiments in accordance with the present invention provide waveguide structures and methods of forming such structures where core and laterally adjacent cladding regions are defined. Some embodiments of the present invention provide waveguide structures where core regions are collectively surrounded by laterally adjacent cladding regions and cladding layers and methods of forming such structures.

  本发明实施例提供了波导结构和形成这种结构的方法，其中定义了核心和横向相邻的包层区域。本发明的一些实施例提供了波导结构，其中核心区域被横向相邻的包层区域和包层层共同包围，并提供了形成这种结构的方法。
• Negative tone photosensitive compositions
  申请人：PROMERUS, LLC

  公开号：US10712661B2

  公开（公告）日：2020-07-14

  Various compositions encompassing polymers containing acidic pendent groups in combination with one or more reactive olefinic compounds and a photoacid generators form self-imagable negative tone films. Examples of such polymers include polymers and copolymers containing norbornene-type repeating units having acidic pendent groups, ring opened maleic anhydride polymers, polyacrylic acid, polyhydroxystyrene polymers, and the like. The films formed from such compositions provide self imagable, low-k, thermally stable layers for use in microelectronic and optoelectronic devices, among other applications.

  含有酸性悬垂基团的聚合物与一种或多种活性烯烃化合物和光酸发生器的各种组合物可形成自显影负色调薄膜。此类聚合物的例子包括含有酸性悬垂基团的降冰片烯类重复单元的聚合物和共聚物、开环马来酸酐聚合物、聚丙烯酸、聚羟基苯乙烯聚合物等。由此类组合物形成的薄膜具有自显影性、低 K 值、热稳定性，可用于微电子和光电设备及其他应用中。
• High impact strength 3D printing materials derived from polycycloolefin monomers and crosslinkers
  申请人：PROMERUS, LLC

  公开号：US11142662B2

  公开（公告）日：2021-10-12

  Embodiments in accordance with the present invention encompass a composition containing a latent catalyst and a compound capable of generating a Bronsted acid with a counterion capable of coordinating and activating the latent catalyst along with one or more monomers which undergo ring open metathesis polymerization (ROMP) and one or more multi-functional crosslinkable molecules when said composition is exposed to a suitable radiation forms a three-dimensional (3D) object. The catalyst system employed therein can be sensitive to oxygen and thus inhibits polymerization in ambient atmospheric conditions. The three-dimensional objects made by this process exhibits improved mechanical properties, particularly, high distortion temperature, impact strength, elongation to break, among others. Accordingly, compositions of this invention are useful as 3D inkjet materials for forming high impact strength objects of various sizes with microscale features lower than 100 microns, among various other uses.

  本发明的实施方案包括一种组合物，该组合物含有一种潜伏催化剂和一种能够生成具有反离子的勃朗斯特德酸的化合物，该反离子能够配位和活化潜伏催化剂以及一种或多种进行开环偏聚（ROMP）的单体和一种或多种多功能可交联分子，当所述组合物暴露在适当的辐射下时，就会形成三维（3D）物体。其中采用的催化剂系统可能对氧气敏感，因此在环境大气条件下会抑制聚合。通过这种工艺制作的三维物体具有更好的机械性能，特别是高变形温度、冲击强度和断裂伸长率等。因此，本发明的组合物可用作三维喷墨材料，用于形成具有低于 100 微米的微观特征的各种尺寸的高冲击强度物体，以及其他各种用途。
• LIGHT GUIDE AND LIGHT GUIDE STRUCTURE
  申请人：Choki Koji

  公开号：US20100067861A1

  公开（公告）日：2010-03-18

  An optical waveguide structure has excellent heat resistance and a low water absorbing property and can be manufactured with a low material cost. Such an optical waveguide structure includes: an optical waveguide having two surfaces, a core layer including core portions and cladding portions each having a refractive index lower than that of each of the core portions, the core layer having two surfaces, and cladding layers provided so as to make contact with the two surfaces of the core layer and having a refractive index lower than that of each of the core portions; and conductor layers provided on the two surfaces of the optical waveguide. In the optical waveguide structure, each of the cladding layers is formed of a norbornene-based polymer as a major component thereof. Further, it is preferred that the norbornene-based polymer is composed of molecules each represented by the following formula 1 as a major component thereof: wherein R is an alkyl group having a carbon number of 1 to 10, “a” is an integer of 0 to 3, “b” is an integer of 1 to 3, and “p”/“q” is 20 or less.